European Journal of Chemistry 2020, 11(1), 15-20 | doi: https://doi.org/10.5155/eurjchem.11.1.15-20.1941 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, characterization and biological activity of a Schiff base derived from o-amino benzoic acid and its Co(II), Cd(II) and Ni(II) complexes


Tasneem Ibrahim Hussein (1) orcid , Musa Abduelrahman Ahmed (2) orcid , Ismail Adam Arbab (3,*) orcid , Awad Salim Ibrahim (4) orcid , Mohamed Al-Bratty (5) orcid , Hassan Ahmed Alhazmi (6) orcid , Asim Najmi (7) orcid

(1) Department of Chemistry and Biology, Faculty of Education, University of Albutana, Gezira State, Rufaa, 22216, Sudan
(2) Department of Chemistry and Biology, Faculty of Education, University of Gezira, Gezira State, Wad Madani, 21111, Sudan
(3) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Jazan University, Jazan, 45142, Saudi Arabia
(4) Department of Chemistry, Faculty of Education, West Kordufan University, West Kordufan State, El-Nuhud, 55511, Sudan
(5) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Jazan University, Jazan, 45142, Saudi Arabia
(6) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Jazan University, Jazan, 45142, Saudi Arabia
(7) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Jazan University, Jazan, 45142, Saudi Arabia
(*) Corresponding Author

Received: 18 Nov 2019 | Revised: 24 Dec 2019 | Accepted: 27 Dec 2019 | Published: 31 Mar 2020 | Issue Date: March 2020

Abstract


Equimolar amounts of imidazoleacetophenone and 2-aminobenzoic acid were combined together and the Schiff base 4(1H-imidazole-yl)acetophenoneanthranilic acid was prepared as a new bidentate complexing agent. The synthesized ligand was reacted with cobalt(II), cadmium(II), and nickel(II) ions yielding air stable complexes. For quantification and characterization purposes, elemental analysis, infrared spectra, electronic spectra, proton nuclear magnetic resonance spectra and mass spectra studies were carried out on the obtained complexes and ligand. Thermogravimetric analysis and magnetic susceptibility measurements were also used for characterization. The ligand IR spectrum showed that the ligand acts as a bidentate coordinates to the metal ions through the nitrogen and oxygen atoms.Measurements of magnetic susceptibility for Ni(II) and Co(II) complexes were found to be 3.4 and 3.8 B.M., respectively, in the range normal for the octahedral geometry. The conductivity measurements revealed that the chelates are non-electrolytes. An in vitro antimicrobial investigation was also carried out for the free ligand and its metal complexes against a number of bacterial and fungal strains, to assess their antimicrobial properties by diffusion technique. Antimicrobial activity of the prepared complexes showed higher activity than the free ligand.


Announcements


One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).

Editor-in-Chief
European Journal of Chemistry

Keywords


Complex; Schiff base; Antifungal activity; Antibacterial activity; Bidentate complexing agent; 4(1H-Imidazole-yl)acetophenoneanthranilic acid

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.11.1.15-20.1941

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 2191 times | icon graph PDF Article downloaded 512 times

Funding information


Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Jazan University, Jazan, 45142, Saudi Arabia.

Citations

/


[1]. Ifeyinwa Stella Ozochukwu, Obinna Chibueze Okpareke, David Chukwuma Izuogu, Akachukwu Ibezim, Oguejiofo Theophilus Ujam, Jonnie Niyi Asegbeloyin
N'-(Pyridin-3-ylmethylene)benzenesulfonohydrazide: Crystal structure, DFT, Hirshfeld surface and in silico anticancer studies
European Journal of Chemistry  12(3), 256, 2021
DOI: 10.5155/eurjchem.12.3.256-264.2102
/


References


[1]. Turan, N.; Buldurun, K. Eur. J. Chem. 2018, 9(1), 22-29.
https://doi.org/10.5155/eurjchem.9.1.22-29.1671

[2]. Prakash, A.; Adhikari, D. Int. J. Chem. Tech. Res. 2011, 3, 1891-1896.

[3]. Demirelli, H.; Koseoglu, F. J. Solution Chem. 2005, 34, 561-577.
https://doi.org/10.1007/s10953-005-5592-9

[4]. Golcu, A.; Tumer, M.; Demirelli, H.; Wheatley, R. A. Inorg. Chim. Acta 2005, 358, 1785-1797.
https://doi.org/10.1016/j.ica.2004.11.026

[5]. Al-Salami, B. K.; Gata, R. A.; Asker, K. A. Adv. Appl. Sci. Res. 2017, 8, 4-12.

[6]. Vadivel, R.; Jayakumar, R.; Ananthi, N. Org. Med. Chem. IJ. 2018, 5(3), 555662, 1-6.

[7]. Ashraf, M. A.; Mahmood, K.; Wajid, A.; Maah, M. J.; Yusoff, I. Int. Conf. Chem. Chem. Proc. IPCBEE 2011, 10, 1-7.

[8]. Jesmin, M.; Ali, M.; Khanam, J. Turk. J. Pharm. Sci. 2010, 34, 20-31.

[9]. Al-Shaheen, J.; Amira, A. M. Res. J. Chem. Sci. 2014, 4, 25-32.

[10]. Joseyphus, R. S.; Shiju, C.; Joseph, J.; Dhanaraj, C. J.; Bright, K. Der Pharma Chem. 2015, 7, 265-270.

[11]. Kumar, S.; Dhar, D. N.; Saxena, P. J. Sci. Ind. Res. India 2009, 68, 181-187.

[12]. Tanaka, K.; Shimoura, R.; Caira, M. R. Tetrahedron Lett. 2010, 51, 449-452.
https://doi.org/10.1016/j.tetlet.2009.11.062

[13]. Abdalla, T. I. H. Ph.D. Thesis, Synthesis, characterization and biological activity of some schiff bases derived from o-aminobenzoic acid and thiosemicarbazone ligands and their complexes with some metal ions, University of Gezira, Sudan, 2016.

[14]. Yernale, N. G.; Udayagiri, M. D.; Mruthyunjayaswam, B. H. M. Eur. J. Chem. 2016, 7(1), 56-65.
https://doi.org/10.5155/eurjchem.7.1.56-65.1372

[15]. Chandra, J. N. S.; Sadashiva, C.; Kavitha, C.; Rangappa, K. Bioorgan. Med. Chem. 2006, 14, 6621-6627.
https://doi.org/10.1016/j.bmc.2006.05.064

[16]. Yahyazadeh, M.; Omidbaigi, R.; Zare, R.; Taheri, H. World J. Microb. Biot. 2008, 24, 1445-1450.
https://doi.org/10.1007/s11274-007-9636-8

[17]. Bouchra, C.; Achouri, M.; Hassani, L. I.; Hmamouchi, M. J. Ethnopharm. 2003, 89, 165-169.
https://doi.org/10.1016/S0378-8741(03)00275-7

[18]. Ahmed, M. A.; Suliman, M. R.; Babiker, M. O. J. Sci. Technol. 2013, 14(2), 88-100.

[19]. Singh, R.; Chaudhary, P.; Poonia, K.; Chauhan, S. Spectrochim. Acta A 2008, 70, 587-594.
https://doi.org/10.1016/j.saa.2007.08.002

[20]. Chandra, S.; Gupta, L. K. Spectrochim Acta A. 2005, 62, 1102-1106.
https://doi.org/10.1016/j.saa.2005.04.007

[21]. Chandra, S.; Gupta, L. K. Spectrochim Acta A. 2004, 60, 1563-1571.
https://doi.org/10.1016/j.saa.2003.08.023

[22]. Al-Fregi, A. A.; Al-Fadhly, A. L.; Al-Salami, B. K. Eur. J. Chem. 2017, 8(2), 155-161.
https://doi.org/10.5155/eurjchem.8.2.155-161.1564

[23]. Kataria, R.; Khatkar, A. BMC Chemistry 2019, 13, 41, 1-17.
https://doi.org/10.1186/s13065-019-0556-0

[24]. Carmona, M.; Rodriguez, R.; Lahoz, F. J.; Garcia-Orduna, P.; Osante, I.; Cativiela, C.; Lopez, J. A.; Carmona, D. Dalton Trans. 2016, 45, 14203-14215.
https://doi.org/10.1039/C6DT02411D

[25]. Suresh, M. S.; Prakash, V. Int. J. Phys. Sci. 2010, 5(9), 1443-1449.

[26]. Neelakantan, M.; Rusalraj, F.; Dharmaraja, J.; Johnsonraja, S.; Jeyakumar, T.; Pillai, M. S. Spectrochim. Acta A 2008, 71, 1599-1609.
https://doi.org/10.1016/j.saa.2008.06.008

[27]. Mohamed, G. G.; Ibrahim, N. A.; Attia, H. A. Spectrochim. Acta A 2009, 72, 610-615.
https://doi.org/10.1016/j.saa.2008.10.051

[28]. Siraj, I. T.; Ado, H. B. Dutse J. Pure Appl. Sci. 2018, 4(1), 426-435.

[29]. Padmaja, M.; Pragathi, J.; Kumari, C. G. J. Chem. Pharm. 2011, 3, 602-613.

[30]. Refat, M. S.; Killa, H. M.; Mansour, A. F.; Fetooh, H. Inorg Nano-Met Chem. 2011, 41, 295-308.

[31]. Bayoumi, H. A.; Alaghaz, A. M. A.; Aljahdali, M. S. Int. J. Electrochem. Sci. 2013, 8, 9399-9413.

[32]. Stein, A.; Wilson, B. E.; Rudisill, S. G. Chem. Soc. Rev. 2013, 42, 2763-2803.
https://doi.org/10.1039/C2CS35317B

[33]. Farooqi, S. A. Green Metal Nanoparticles: Synthesis, Characterization and their Application, 1st edition, John Wiley & Sons, 2018.

[34]. Daglia, M. Curr. Opin. Biotech. 2012, 23, 174-181.
https://doi.org/10.1016/j.copbio.2011.08.007

[35]. Mohamed, G. G.; Omar, M.; Hindy, A. M. Spectrochim. Acta A 2005, 62, 1140-1150.
https://doi.org/10.1016/j.saa.2005.03.031


How to cite


Hussein, T.; Ahmed, M.; Arbab, I.; Ibrahim, A.; Al-Bratty, M.; Alhazmi, H.; Najmi, A. Eur. J. Chem. 2020, 11(1), 15-20. doi:10.5155/eurjchem.11.1.15-20.1941
Hussein, T.; Ahmed, M.; Arbab, I.; Ibrahim, A.; Al-Bratty, M.; Alhazmi, H.; Najmi, A. Synthesis, characterization and biological activity of a Schiff base derived from o-amino benzoic acid and its Co(II), Cd(II) and Ni(II) complexes. Eur. J. Chem. 2020, 11(1), 15-20. doi:10.5155/eurjchem.11.1.15-20.1941
Hussein, T., Ahmed, M., Arbab, I., Ibrahim, A., Al-Bratty, M., Alhazmi, H., & Najmi, A. (2020). Synthesis, characterization and biological activity of a Schiff base derived from o-amino benzoic acid and its Co(II), Cd(II) and Ni(II) complexes. European Journal of Chemistry, 11(1), 15-20. doi:10.5155/eurjchem.11.1.15-20.1941
Hussein, Tasneem, Musa Abduelrahman Ahmed, Ismail Adam Arbab, Awad Salim Ibrahim, Mohamed Al-Bratty, Hassan Ahmed Alhazmi, & Asim Najmi. "Synthesis, characterization and biological activity of a Schiff base derived from o-amino benzoic acid and its Co(II), Cd(II) and Ni(II) complexes." European Journal of Chemistry [Online], 11.1 (2020): 15-20. Web. 3 Jun. 2023
Hussein, Tasneem, Ahmed, Musa, Arbab, Ismail, Ibrahim, Awad, Al-Bratty, Mohamed, Alhazmi, Hassan, AND Najmi, Asim. "Synthesis, characterization and biological activity of a Schiff base derived from o-amino benzoic acid and its Co(II), Cd(II) and Ni(II) complexes" European Journal of Chemistry [Online], Volume 11 Number 1 (31 March 2020)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.11.1.15-20.1941


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2020, 11(1), 15-20 | doi: https://doi.org/10.5155/eurjchem.11.1.15-20.1941 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c) 2020 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).



© Copyright 2010 - 2023  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.