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Hydrogen bonding framework in imidazole derivatives: Crystal structure and Hirshfeld surface analysis
Praveen Singh (1)
, Ranjeet Kumar (2) , Ashish Kumar Tewari (3,*) (1) Department of Chemistry, Centre of Advance Studies, Institute of Science, Banaras Hindu University, Varanasi 221005, India
(2) Department of Chemistry, Chaudhary Mahadeo Prasad Degree College, Allahabad, 211002, India
(3) Department of Chemistry, Centre of Advance Studies, Institute of Science, Banaras Hindu University, Varanasi 221005, India
(*) Corresponding Author
Received: 12 Dec 2019 | Revised: 19 Jan 2020 | Accepted: 28 Jan 2020 | Published: 31 Mar 2020 | Issue Date: March 2020
Abstract
A series of imidazole derivatives (1-3) were synthesized with three component reaction among benzil, ammonium acetate and formaldehyde/aromatic aldehyde at 110 °C without a catalyst and solvent. These synthesized imidazole derivatives have shown intermolecular hydrogen bonding such as N-H···N and O-H···N. The imidazole 1 and 2 exhibited N-H···N intermolecular hydrogen bonding while imidazole 3 exhibited O-H···N intermolecular hydrogen bonding. The hydrogen bonds in imidazoles were studied by X-ray crystallography and Hirshfeld Surface Analysis at dnorm surface which show the visible red spots, indicated for hydrogen bonds. Further, Hirshfeld surface analysis also shows the percentage of all intermolecular interactions.
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DOI: 10.5155/eurjchem.11.1.50-59.1945
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Funding information
University Grant Commission (Grant Sanction No. 37-54/2009), India; Department of Chemistry, Banaras Hindu University, Varanasi, India.
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DOI Link: https://doi.org/10.5155/eurjchem.11.1.50-59.1945
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European Journal of Chemistry 2020, 11(1), 50-59 | doi: https://doi.org/10.5155/eurjchem.11.1.50-59.1945 | Get rights and content
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