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MgO nanoparticles: Synthesis, characterization, and applications as a catalyst for organic transformations
Harshal Dabhane (1)
, Suresh Ghotekar (2) , Pawan Tambade (3,*) , Shreyas Pansambal (4) , Rajeshwari Oza (5) , Vijay Medhane (6) (1) Department of Chemistry, Guruvarya Mamasaheb Dandekar Arts, Bhagwantrao Waje Commerce and Science College, Sinnar, Nashik, Affiliated to Savitribai Phule Pune University, Pune, Maharashtra, 422 103, India
(2) Department of Chemistry, Sangamner Nagarpalika Arts, Damodar Jagannath Malpani Commerce and Bastiram Narayandas Sarda Science College, Sangamner, Affiliated to Savitribai Phule Pune University, Maharashtra, 422 605 India
(3) Department of Chemistry, Karmaveer Kakasaheb Wagh Arts, Science and Commerce College, Pimpalgaon (B), Nashik, Affiliated to Savitribai Phule Pune University, Maharashtra, 422 209 India
(4) Department of Chemistry, Sangamner Nagarpalika Arts, Damodar Jagannath Malpani Commerce and Bastiram Narayandas Sarda Science College, Sangamner, Affiliated to Savitribai Phule Pune University, Maharashtra, 422 605 India
(5) Department of Chemistry, Sangamner Nagarpalika Arts, Damodar Jagannath Malpani Commerce and Bastiram Narayandas Sarda Science College, Sangamner, Affiliated to Savitribai Phule Pune University, Maharashtra, 422 605 India
(6) Department of Chemistry, Karmaveer Raosaheb Thorat Arts, Bhausaheb Hiray Commerce & Annasaheb Murkute Science College (KTHM College), Nashik, Affiliated to Savitribai Phule Pune University, Pune Maharashtra, 422002 India
(*) Corresponding Author
Received: 06 Jan 2021 | Revised: 19 Feb 2021 | Accepted: 20 Feb 2021 | Published: 31 Mar 2021 | Issue Date: March 2021
Abstract
Currently, the size and shape selective synthesis of nanoparticles (NPs) and their varied catalytic applications are gaining significant enthusiasm in the field of nanochemistry. Homogeneous catalysis is crucial due to its inherent benefits like high selectivity and mild reaction conditions. Nevertheless, it endures with serious disadvantages of catalysts and/or product separation/recycles compared to their heterogeneous counterparts restricting their catalytic applications. The utilization of catalysts in the form of nano-size is an elective methodology for the combination of merits of homogeneous and heterogeneous catalysis. Magnesium oxide (MgO) NPs are important as they find applications for catalysis, organic transformation, and synthesis of fine chemicals and organic intermediates. The applications of MgO NPs in diverse organic transformations including oxidation, reduction, epoxidation, condensation, and C-C, C-N, C-O, C-S bond formation in a variety of notable heterocyclic reactions are also discussed. The use of MgO NPs in organic transformation is advantageous as it mitigates the use of ligands; the procurable separation of catalyst for recyclability makes the protocol heterogeneous and monetary. MgO NPs gave efficacious catalytic performance towards the desired products due to high surface area. By considering these efficient merits, scientists have focused their attentions towards stupendous applications of MgO NPs in selective organic transformation. In the current review article, we summarized the synthesis of MgO NPs and numerous characterization techniques, whereas the application section illustrates their utility as a catalyst in several organic transformations. We believe this decisive appraisal will provide imperative details to further advance the application of MgO NPs in selective catalysis.
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European Journal of Chemistry
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DOI: 10.5155/eurjchem.12.1.86-108.2060
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