European Journal of Chemistry 2021, 12(4), 389-393 | doi: https://doi.org/10.5155/eurjchem.12.4.389-393.2151 | Get rights and content

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Synthesis and structural analysis of cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-trifluoromethanesulfonate 0.28-hexafluoridophosphate


Tsugiko Takase (1) orcid , Dai Oyama (2,*) orcid

(1) Department of Natural Sciences and Informatics, Fukushima University, 1 Kanayagawa, Fukushima, 960-1296, Japan
(2) Department of Natural Sciences and Informatics, Fukushima University, 1 Kanayagawa, Fukushima, 960-1296, Japan
(*) Corresponding Author

Received: 15 Jul 2021 | Revised: 20 Aug 2021 | Accepted: 28 Aug 2021 | Published: 31 Dec 2021 | Issue Date: December 2021

Abstract


Ruthenium(II) complexes containing both 1,10-phenanthroline (Phen) and carbonyl (CO) ligands are important molecules for various applications including catalysis. In this work, the molecular structure of [Ru(Phen)2(CO)2]2+ was determined via X-ray diffraction analysis for the first time. The complex exhibits substitutional disorder of one of counter-anions in the asymmetric unit, with different occupancies for CF3SO3- (0.72) and PF6- (0.28). The ruthenium atom is coordinated in a distorted octahedral environment by two carbonyl carbon atoms and four nitrogen atoms from bis-Phen ligands. The cation displays a cis configuration of the carbonyl ligands. Several hydrogen bonds and π-π interactions are present in the crystal. In addition to structural characterization, IR spectral data for the complex is compared with calculated values. These results provide fundamental data for understanding various properties of related ruthenium complexes.


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European Journal of Chemistry

Keywords


Carbonyl; IR spectra; Crystal structure; Ruthenium complex; 1,10-Phenanthroline; Computational chemistry

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DOI: 10.5155/eurjchem.12.4.389-393.2151

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Funding information


Japan Society for the Promotion of Science, Japan.

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Takase, T.; Oyama, D. Eur. J. Chem. 2021, 12(4), 389-393. doi:10.5155/eurjchem.12.4.389-393.2151
Takase, T.; Oyama, D. Synthesis and structural analysis of cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-trifluoromethanesulfonate 0.28-hexafluoridophosphate. Eur. J. Chem. 2021, 12(4), 389-393. doi:10.5155/eurjchem.12.4.389-393.2151
Takase, T., & Oyama, D. (2021). Synthesis and structural analysis of cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-trifluoromethanesulfonate 0.28-hexafluoridophosphate. European Journal of Chemistry, 12(4), 389-393. doi:10.5155/eurjchem.12.4.389-393.2151
Takase, Tsugiko, & Dai Oyama. "Synthesis and structural analysis of cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-trifluoromethanesulfonate 0.28-hexafluoridophosphate." European Journal of Chemistry [Online], 12.4 (2021): 389-393. Web. 4 Jul. 2022
Takase, Tsugiko, AND Oyama, Dai. "Synthesis and structural analysis of cis-bis(1,10-phenanthroline)dicarbonyl ruthenium(II) 1.72-trifluoromethanesulfonate 0.28-hexafluoridophosphate" European Journal of Chemistry [Online], Volume 12 Number 4 (31 December 2021)

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