European Journal of Chemistry 2010, 1(4), 319-321. doi:10.5155/eurjchem.1.4.319-321.224

Determination of enantiomeric excess of leucine and valine by X-ray powder diffraction


Elżbieta Tadeusiak (1) , Rafal Kruszynski (2,*) , Agata Trzesowska-Kruszynska (3) , Tomasz Sieranski (4) , Bartlomiej Lewinski (5)

(1) Department of Structural Studies, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, Łódź, PL-90-363, Poland
(2) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(3) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(4) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(5) Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Łódź, Żeromskiego 116, Łódź, PL-90-924, Poland
(*) Corresponding Author

Received: 26 Jul 2010, Accepted: 06 Aug 2010, Published: 22 Dec 2010

Abstract


Two amino acids, leucine and valine, were studied by X-ray powder diffraction (XRPD). The linear correlations between intensity of racemate (decrease) or enantiomer (increase) and enantiomeric excesses were observed in each case.

1_4_319_321_800


Keywords


Leucine; Valine; Enantiomeric excess; X-ray powder diffraction

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DOI: 10.5155/eurjchem.1.4.319-321.224

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[1]. María Mar Quesada-Moreno, Albert Virgili, Eva Monteagudo, Rosa M. Claramunt, Juan Ramón Avilés-Moreno, Juan Jesús López-González, Ibon Alkorta, José Elguero
A vibrational circular dichroism (VCD) methodology for the measurement of enantiomeric excess in chiral compounds in the solid phase and for the complementary use of NMR and VCD techniques in solution: the camphor case
The Analyst  143(6), 1406, 2018
DOI: 10.1039/C7AN01855J
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How to cite


Tadeusiak, E.; Kruszynski, R.; Trzesowska-Kruszynska, A.; Sieranski, T.; Lewinski, B. Eur. J. Chem. 2010, 1(4), 319-321. doi:10.5155/eurjchem.1.4.319-321.224
Tadeusiak, E.; Kruszynski, R.; Trzesowska-Kruszynska, A.; Sieranski, T.; Lewinski, B. Determination of enantiomeric excess of leucine and valine by X-ray powder diffraction. Eur. J. Chem. 2010, 1(4), 319-321. doi:10.5155/eurjchem.1.4.319-321.224
Tadeusiak, E., Kruszynski, R., Trzesowska-Kruszynska, A., Sieranski, T., & Lewinski, B. (2010). Determination of enantiomeric excess of leucine and valine by X-ray powder diffraction. European Journal of Chemistry, 1(4), 319-321. doi:10.5155/eurjchem.1.4.319-321.224
Tadeusiak, Elżbieta, Rafal Kruszynski, Agata Trzesowska-Kruszynska, Tomasz Sieranski, & Bartlomiej Lewinski. "Determination of enantiomeric excess of leucine and valine by X-ray powder diffraction." European Journal of Chemistry [Online], 1.4 (2010): 319-321. Web. 19 Sep. 2019
Tadeusiak, Elżbieta, Kruszynski, Rafal, Trzesowska-Kruszynska, Agata, Sieranski, Tomasz, AND Lewinski, Bartlomiej. "Determination of enantiomeric excess of leucine and valine by X-ray powder diffraction" European Journal of Chemistry [Online], Volume 1 Number 4 (22 December 2010)

DOI Link: https://doi.org/10.5155/eurjchem.1.4.319-321.224

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