European Journal of Chemistry 2022, 13(2), 230-233 | doi: https://doi.org/10.5155/eurjchem.13.2.230-233.2256 | Get rights and content

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Phenazine and 10H-phenothiazine cocrystal stabilized by N-H···N and C-H···S hydrogen bonds


Tahir Mehmood (1) orcid , Bhumiben Chandubhai Patel (2) orcid , Jayarama Prakasha Reddy (3,*) orcid

(1) Department of Chemistry, School of Sciences, Indrashil University, Rajpur, Gujarat 382740, India
(2) Department of Chemistry, School of Sciences, Indrashil University, Rajpur, Gujarat 382740, India
(3) Department of Chemistry, School of Sciences, Indrashil University, Rajpur, Gujarat 382740, India
(*) Corresponding Author

Received: 09 Mar 2022 | Revised: 23 Apr 2022 | Accepted: 27 Apr 2022 | Published: 30 Jun 2022 | Issue Date: June 2022

Abstract


A 1:1 co-crystal of phenazine and phenothiazine was prepared. The crystal structure was determined by using a single crystal X-ray crystallography technique. Analysis of the crystal revealed that the molecular complex crystallizes in monoclinic P21/n space group, C12H8N2·C12H9NS, a = 9.068(2) Å, b = 8.872(2) Å, c = 23.935(4) Å, β = 92.16(4)°, = 1924.1(6) Å3, Z = 4, T = 293(2) K, μ(MoKα) = 0.182 mm-1, Dcalc = 1.310 g/cm3, 8057 reflections measured (3.4° ≤ 2Θ ≤ 46.54°), 2751 unique (Rint = 0.0559, Rsigma = 0.0618) which were used in all calculations. The final R1 was 0.0548 (>2sigma(I)) and wR2 was 0.1029 (all data). The molecules recognize each other through N-H···N and C-H···N hydrogen bonds, thus producing a tetramer unit. These units further interact with one another via C-H···S hydrogen bonds.


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Editor-in-Chief
European Journal of Chemistry

Keywords


Co-crystal; Phenazine; Phenothiazine; Hydrogen bonding; X-ray crystallography; Supramolecular assembly

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DOI: 10.5155/eurjchem.13.2.230-233.2256

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Funding information


Scheme of Developing High Quality Research (SHODH), Government of Gujarat, India.

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The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Mehmood, T.; Patel, B.; Reddy, J. Eur. J. Chem. 2022, 13(2), 230-233. doi:10.5155/eurjchem.13.2.230-233.2256
Mehmood, T.; Patel, B.; Reddy, J. Phenazine and 10H-phenothiazine cocrystal stabilized by N-H···N and C-H···S hydrogen bonds. Eur. J. Chem. 2022, 13(2), 230-233. doi:10.5155/eurjchem.13.2.230-233.2256
Mehmood, T., Patel, B., & Reddy, J. (2022). Phenazine and 10H-phenothiazine cocrystal stabilized by N-H···N and C-H···S hydrogen bonds. European Journal of Chemistry, 13(2), 230-233. doi:10.5155/eurjchem.13.2.230-233.2256
Mehmood, Tahir, Bhumiben Chandubhai Patel, & Jayarama Prakasha Reddy. "Phenazine and 10H-phenothiazine cocrystal stabilized by N-H···N and C-H···S hydrogen bonds." European Journal of Chemistry [Online], 13.2 (2022): 230-233. Web. 8 Dec. 2023
Mehmood, Tahir, Patel, Bhumiben, AND Reddy, Jayarama. "Phenazine and 10H-phenothiazine cocrystal stabilized by N-H···N and C-H···S hydrogen bonds" European Journal of Chemistry [Online], Volume 13 Number 2 (30 June 2022)

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DOI Link: https://doi.org/10.5155/eurjchem.13.2.230-233.2256


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