Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
SHORT COMMUNICATION
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Synthesis and electrochemistry of dimanganese(II) complexes of phenol-based dinucleating ligands with four methoxyethyl chelating arms
Yuuki Nakayama (1)
, Kei Unoura (2) , Yasuhiro Igarashi (3) , Md. Jamil Hossain (4) , Hiroshi Sakiyama (5,*) (1) Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan
(2) Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan
(3) Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan
(4) Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan
(5) Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan
(*) Corresponding Author
Received: 03 Aug 2010 | Revised: 04 Apr 2011 | Accepted: 27 Oct 2010 | Published: 30 Jun 2011 | Issue Date: June 2011
Abstract
Dimanganese(II) complexes [Mn2(bonp)(PhCO2)2]PF6 (1) and [Mn2(bocp)(PhCO2)2]PF6 (2) were synthesized with p-nitro- and p-chloro-substituted phenol-based dinucleating ligands bonp- [2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-nitrophenolate anion] and bocp- [4-chloro-2,6-bis[bis(2-methoxyethyl)aminomethyl]phenolate anion], respectively, with the aim of controlling the redox potentials of the dimanganese center by changing the p-substituents in the dinucleating ligands. Cyclic voltammograms of 1 and 2 showed quasi-reversible oxidation processes, assigned to MnIIMnII/MnIIMnIII, at 1.17 and 1.00 V vs. Ag/AgCl, respectively. Compared to the previous p-methyl complex [Mn2(bomp)(PhCO2)2]PF6 (3) [bomp–: 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-methylphenolate anion] (0.96 V vs. Ag/AgCl), the order of the potentials was 1(-NO2) > 2(-Cl) > 3(-CH3). Thus, the redox potentials of the dimanganese centers were controlled by the p-substituents in the dinucleating ligands.
Announcements
Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.
1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization between November 15, 2022 and December 28, 2022 (Voucher code: SINGLE2022).
2. Young writers will not be charged for the article processing fee between November 15, 2022 and December 28, 2022 (Voucher code: YOUNG2022).
3. The article processing fee will not be charged from the articles containing a part of the PhD thesis between November 15, 2022 and December 28, 2022 (Voucher code: PhD2022).
4. The article processing fee will not be charged from authors who have at least one publication in the European Journal of Chemistry between November 15, 2022 and December 28, 2022 (Voucher code: (Voucher code: AUTHOR2022).
Editor-in-Chief
European Journal of Chemistry
Keywords
Dimanganese(II) complex; Dinucleating ligand; Electrochemistry; p-Substituent; DFT; Redox potential
Full Text:
PDF
DOI: 10.5155/eurjchem.2.2.266-268.227
Links for Article
| | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 3029 times |
PDF Article downloaded 581 times
References
[1]. Kono, Y.; Fridovich, I. J. Biol. Chem. 1983, 258, 6015-6019.
[2]. Kono, Y.; Fridovich, I. J. Biol. Chem. 1983, 258, 13646-13658.
[3]. Allgood, G. S.; Perry, J. J. J. Bacteriol. 1986, 168, 563-567.
[4]. Barynin, V. V.; Grebenko, A. I. Dokl. Akad. Nauk SSSR 1986, 286, 461-464.
[5]. Khangulov, S. V.; Goldfeld, M. G.; Gerasimenko, V. V.; Andreeva, N. E.; Barynin, V. V.; Grebenko, A. I. J. Inorg. Biochem. 1990, 40, 279-292.
doi:10.1016/0162-0134(90)80062-3
[6]. Kagawa, M.; Murakoshi, N.; Nishikawa, Y.; Matsumoto, G.; Kurata, Y.; Mizobata, T.; Kawata, Y.; Nagai, J. Arch. Biochem. Biophys. 1990, 40, 279-292.
[7]. Willing, A.; Follmann, H.; Auling, G. Eur. J. Biochem. 1988, 170, 603-611.
doi:10.1111/j.1432-1033.1988.tb13740.x
PMid:2828045
[8]. Reczkowski, R. S.; Ash, D. E. J. Am. Chem. Soc. 1992, 114, 10992-10994.
doi:10.1021/ja00053a064
[9]. Cammack, R.; Chapmann, A.; Lu, W.-P.; Karagouni, A. A.; Kelly, D. P. FEBS Lett. 1989, 252, 239-243.
doi:10.1016/0014-5793(89)80967-6
[10]. Carrel, H. L.; Glusker, J. P.; Burger, V.; Manfre, F.; Tritsch, D.; Biellmann, J. F. Proc. Natl. Acad. Sci. U.S.A. 1989, 86, 4440-4444.
doi:10.1073/pnas.86.12.4440
[11]. Whitlow, M.; Howard, A. J.; Finzel, B. C.; Poulos, T. L.; Winborne, E.; Gilliland, G. L. Proteins 1991, 9, 153-173.
doi:10.1002/prot.340090302
PMid:2006134
[12]. Collyer, C. A.; Henrick, K.; Blow, D. M. J. Mol. Biol. 1990, 212, 211-235.
doi:10.1016/0022-2836(90)90316-E
[13]. Davies, J. F.; Hostomka, Z. II.; Hostomsky, Z.; Jordan, S. R.; Matthews, D. A. Science 1991, 252, 88-95.
doi:10.1126/science.1707186
PMid:1707186
[14]. Wilce, M. C.; Bond, C. S.; Dixon, N. E.; Freeman, H. C.; Guss, J. M.; Lilley, P. E.; Wilce, J. A. Proc. Natl. Acad. Sci. U.S.A. 1998, 95, 3472-3477.
doi:10.1073/pnas.95.7.3472
[15]. Pecoraro, V. L. Manganese Redox Enzymes, VCH Publishers, Inc, 1992.
[16]. Kurz, P.; Anderlund, M. F.; Shaikh, N.; Styring, S.; Huang, P. Eur. J. Inorg. Chem. 2008, 5, 762-770.
doi:10.1002/ejic.200700888
[17]. Gultneh, Y.; Tesema, Y. T.; Ahvazi, Bijan; Yisgedu, T. B.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chim. Acta 2006, 359, 4463-4469.
doi:10.1016/j.ica.2006.05.040
[18]. Dubois, L.; Caspar, R.; Jacquamet, L.; Petit, P. E.; Charlot, M. F. Baffert, C.; Collomb, M. N.; Deronzier, A.; Latour, J. M. Inorg. Chem. 2006, 42, 4817-4827.
doi:10.1021/ic020646n
PMid:12895103
[19]. Sakiyama, H.; Sugawara, A.; Sakamoto, M.; Unoura, K.; Inoue, K.; Yamasaki, M. Inorg. Chim. Acta 2000, 310, 163-168.
doi:10.1016/S0020-1693(00)00277-2
[20]. Sakiyama, H.; Igarashi, Y.; Nakayama, Y.; Hossain, M. J.; Unoura, K.; Nishida, Y. Inorg. Chim. Acta 2003, 351, 256-260.
doi:10.1016/S0020-1693(03)00119-1
[21]. Sakiyama, H.; Mochizuki, R.; Sugawara, A.; Sakamoto, M.; Nishida, Y.; Yamasaki, M. J. Chem. Soc., Dalton Trans. 1999, 6, 997-1000.
[22]. Head-Gordon, M.; Pople, J. A.; Frisch, M. J. Chem. Phys. Lett. 1988, 153, 503-506.
doi:10.1016/0009-2614(88)85250-3
[23]. Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 275-280.
doi:10.1016/0009-2614(90)80029-D
[24]. Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 281-289.
doi:10.1016/0009-2614(90)80030-H
[25]. Head-Gordon, M.; Head-Gordon, T. Chem. Phys. Lett. 1994, 220, 122-128.
doi:10.1016/0009-2614(94)00116-2
[26]. Saebo, S.; Almlof, J. Chem. Phys. Lett. 1989, 154, 83-89.
[27]. Kohn, W.; Becke, A. D.; Parr, R. G. J. Phys. Chem. 1996, 100, 12974-12980.
doi:10.1021/jp960669l
[28]. Becke, A. D. J. Chem. Soc. 1993, 98, 5648-5652.
[29]. Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100.
doi:10.1103/PhysRevA.38.3098
PMid:9900728
[30]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270-283.
[31]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
doi:10.1016/S0010-8545(00)80455-5
[32]. Unoura, K.; Ooi, T.; Tanaka, K.; Iwase, A. J. Electroanal. Chem. 1988, 252, 335-343.
doi:10.1016/0022-0728(88)80220-1
[33]. Jaffé, H. H. Chem. Revs. 1953, 53, 191-261.
doi:10.1021/cr60165a003
[34]. Hansch, C.; Leo, A.; Taft, R. W. Chem. Rev. 1991, 91, 165-195.
doi:10.1021/cr00002a004
[2]. Kono, Y.; Fridovich, I. J. Biol. Chem. 1983, 258, 13646-13658.
[3]. Allgood, G. S.; Perry, J. J. J. Bacteriol. 1986, 168, 563-567.
[4]. Barynin, V. V.; Grebenko, A. I. Dokl. Akad. Nauk SSSR 1986, 286, 461-464.
[5]. Khangulov, S. V.; Goldfeld, M. G.; Gerasimenko, V. V.; Andreeva, N. E.; Barynin, V. V.; Grebenko, A. I. J. Inorg. Biochem. 1990, 40, 279-292.
doi:10.1016/0162-0134(90)80062-3
[6]. Kagawa, M.; Murakoshi, N.; Nishikawa, Y.; Matsumoto, G.; Kurata, Y.; Mizobata, T.; Kawata, Y.; Nagai, J. Arch. Biochem. Biophys. 1990, 40, 279-292.
[7]. Willing, A.; Follmann, H.; Auling, G. Eur. J. Biochem. 1988, 170, 603-611.
doi:10.1111/j.1432-1033.1988.tb13740.x
PMid:2828045
[8]. Reczkowski, R. S.; Ash, D. E. J. Am. Chem. Soc. 1992, 114, 10992-10994.
doi:10.1021/ja00053a064
[9]. Cammack, R.; Chapmann, A.; Lu, W.-P.; Karagouni, A. A.; Kelly, D. P. FEBS Lett. 1989, 252, 239-243.
doi:10.1016/0014-5793(89)80967-6
[10]. Carrel, H. L.; Glusker, J. P.; Burger, V.; Manfre, F.; Tritsch, D.; Biellmann, J. F. Proc. Natl. Acad. Sci. U.S.A. 1989, 86, 4440-4444.
doi:10.1073/pnas.86.12.4440
[11]. Whitlow, M.; Howard, A. J.; Finzel, B. C.; Poulos, T. L.; Winborne, E.; Gilliland, G. L. Proteins 1991, 9, 153-173.
doi:10.1002/prot.340090302
PMid:2006134
[12]. Collyer, C. A.; Henrick, K.; Blow, D. M. J. Mol. Biol. 1990, 212, 211-235.
doi:10.1016/0022-2836(90)90316-E
[13]. Davies, J. F.; Hostomka, Z. II.; Hostomsky, Z.; Jordan, S. R.; Matthews, D. A. Science 1991, 252, 88-95.
doi:10.1126/science.1707186
PMid:1707186
[14]. Wilce, M. C.; Bond, C. S.; Dixon, N. E.; Freeman, H. C.; Guss, J. M.; Lilley, P. E.; Wilce, J. A. Proc. Natl. Acad. Sci. U.S.A. 1998, 95, 3472-3477.
doi:10.1073/pnas.95.7.3472
[15]. Pecoraro, V. L. Manganese Redox Enzymes, VCH Publishers, Inc, 1992.
[16]. Kurz, P.; Anderlund, M. F.; Shaikh, N.; Styring, S.; Huang, P. Eur. J. Inorg. Chem. 2008, 5, 762-770.
doi:10.1002/ejic.200700888
[17]. Gultneh, Y.; Tesema, Y. T.; Ahvazi, Bijan; Yisgedu, T. B.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chim. Acta 2006, 359, 4463-4469.
doi:10.1016/j.ica.2006.05.040
[18]. Dubois, L.; Caspar, R.; Jacquamet, L.; Petit, P. E.; Charlot, M. F. Baffert, C.; Collomb, M. N.; Deronzier, A.; Latour, J. M. Inorg. Chem. 2006, 42, 4817-4827.
doi:10.1021/ic020646n
PMid:12895103
[19]. Sakiyama, H.; Sugawara, A.; Sakamoto, M.; Unoura, K.; Inoue, K.; Yamasaki, M. Inorg. Chim. Acta 2000, 310, 163-168.
doi:10.1016/S0020-1693(00)00277-2
[20]. Sakiyama, H.; Igarashi, Y.; Nakayama, Y.; Hossain, M. J.; Unoura, K.; Nishida, Y. Inorg. Chim. Acta 2003, 351, 256-260.
doi:10.1016/S0020-1693(03)00119-1
[21]. Sakiyama, H.; Mochizuki, R.; Sugawara, A.; Sakamoto, M.; Nishida, Y.; Yamasaki, M. J. Chem. Soc., Dalton Trans. 1999, 6, 997-1000.
[22]. Head-Gordon, M.; Pople, J. A.; Frisch, M. J. Chem. Phys. Lett. 1988, 153, 503-506.
doi:10.1016/0009-2614(88)85250-3
[23]. Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 275-280.
doi:10.1016/0009-2614(90)80029-D
[24]. Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 281-289.
doi:10.1016/0009-2614(90)80030-H
[25]. Head-Gordon, M.; Head-Gordon, T. Chem. Phys. Lett. 1994, 220, 122-128.
doi:10.1016/0009-2614(94)00116-2
[26]. Saebo, S.; Almlof, J. Chem. Phys. Lett. 1989, 154, 83-89.
[27]. Kohn, W.; Becke, A. D.; Parr, R. G. J. Phys. Chem. 1996, 100, 12974-12980.
doi:10.1021/jp960669l
[28]. Becke, A. D. J. Chem. Soc. 1993, 98, 5648-5652.
[29]. Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100.
doi:10.1103/PhysRevA.38.3098
PMid:9900728
[30]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270-283.
[31]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
doi:10.1016/S0010-8545(00)80455-5
[32]. Unoura, K.; Ooi, T.; Tanaka, K.; Iwase, A. J. Electroanal. Chem. 1988, 252, 335-343.
doi:10.1016/0022-0728(88)80220-1
[33]. Jaffé, H. H. Chem. Revs. 1953, 53, 191-261.
doi:10.1021/cr60165a003
[34]. Hansch, C.; Leo, A.; Taft, R. W. Chem. Rev. 1991, 91, 165-195.
doi:10.1021/cr00002a004
How to cite
Nakayama, Y.; Unoura, K.; Igarashi, Y.; Hossain, M.; Sakiyama, H.
Eur. J. Chem.
2011,
2(2), 266-268.
doi:10.5155/eurjchem.2.2.266-268.227
Nakayama, Y.; Unoura, K.; Igarashi, Y.; Hossain, M.; Sakiyama, H. Synthesis and electrochemistry of dimanganese(II) complexes of phenol-based dinucleating ligands with four methoxyethyl chelating arms.
Eur. J. Chem.
2011,
2(2), 266-268.
doi:10.5155/eurjchem.2.2.266-268.227
Nakayama, Y., Unoura, K., Igarashi, Y., Hossain, M., & Sakiyama, H.
(2011).
Synthesis and electrochemistry of dimanganese(II) complexes of phenol-based dinucleating ligands with four methoxyethyl chelating arms.
European Journal of Chemistry, 2(2), 266-268.
doi:10.5155/eurjchem.2.2.266-268.227
Nakayama, Yuuki, Kei Unoura, Yasuhiro Igarashi, Md. Jamil Hossain, & Hiroshi Sakiyama.
"Synthesis and electrochemistry of dimanganese(II) complexes of phenol-based dinucleating ligands with four methoxyethyl chelating arms." European Journal of Chemistry [Online], 2.2 (2011): 266-268. Web. 28 Nov. 2022
Nakayama, Yuuki, Unoura, Kei, Igarashi, Yasuhiro, Hossain, Md., AND Sakiyama, Hiroshi.
"Synthesis and electrochemistry of dimanganese(II) complexes of phenol-based dinucleating ligands with four methoxyethyl chelating arms" European Journal of Chemistry [Online], Volume 2 Number 2 (30 June 2011)
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.2.2.266-268.227
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2011, 2(2), 266-268 | doi: https://doi.org/10.5155/eurjchem.2.2.266-268.227 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2022 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2022 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.