Synthesis and electrochemistry of dimanganese(II) complexes of phenol-based dinucleating ligands with four methoxyethyl chelating arms | European Journal of Chemistry

Default Image

PDF

Published: Jun 30, 2011

DOI: https://doi.org/10.5155/eurjchem.2.2.266-268.227

Keywords:

Dimanganese(II) complex, Dinucleating ligand, Electrochemistry, p-Substituent, DFT, Redox potential

Section

Short Communication

Issue

Vol. 2 No. 2 (2011): June 2011

Dates

Received 2010-08-03
Accepted 2010-10-27
Published 2011-06-30

Yuuki Nakayama

eMail

Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan

Kei Unoura

eMail

Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan

Yasuhiro Igarashi

eMail

Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan

Md. Jamil Hossain

eMail

Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan

Hiroshi Sakiyama

eMail

Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan

Abstract

Dimanganese(II) complexes [Mn₂(bonp)(PhCO₂)₂]PF₆ (1) and [Mn₂(bocp)(PhCO₂)₂]PF₆ (2) were synthesized with p-nitro- and p-chloro-substituted phenol-based dinucleating ligands bonp^- [2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-nitrophenolate anion] and bocp^- [4-chloro-2,6-bis[bis(2-methoxyethyl)aminomethyl]phenolate anion], respectively, with the aim of controlling the redox potentials of the dimanganese center by changing the p-substituents in the dinucleating ligands. Cyclic voltammograms of 1 and 2 showed quasi-reversible oxidation processes, assigned to Mn^IIMn^II/Mn^IIMn^III, at 1.17 and 1.00 V vs. Ag/AgCl, respectively. Compared to the previous p-methyl complex [Mn₂(bomp)(PhCO₂)₂]PF₆ (3) [bomp^–: 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-methylphenolate anion] (0.96 V vs. Ag/AgCl), the order of the potentials was 1(-NO₂) > 2(-Cl) > 3(-CH₃). Thus, the redox potentials of the dimanganese centers were controlled by the p-substituents in the dinucleating ligands. 2_2_266_268_800

2_2_266_268_800

This Abstract was viewed 3532 times |

Article PDF downloaded 949 times

How to Cite

(1)

Nakayama, Y.; Unoura, K.; Igarashi, Y.; Hossain, M. J.; Sakiyama, H. Synthesis and Electrochemistry of dimanganese(II) Complexes of Phenol-Based Dinucleating Ligands With Four Methoxyethyl Chelating Arms. Eur. J. Chem. 2011, 2, 266-268.

Share

Links for Article

Crossref - Scopus - Google - European PMC

Crossref

Scopus

Google Scholar

Europe PMC

References

[1]. Kono, Y.; Fridovich, I. J. Biol. Chem. 1983, 258, 6015-6019.

[2]. Kono, Y.; Fridovich, I. J. Biol. Chem. 1983, 258, 13646-13658.

[3]. Allgood, G. S.; Perry, J. J. J. Bacteriol. 1986, 168, 563-567.

[4]. Barynin, V. V.; Grebenko, A. I. Dokl. Akad. Nauk SSSR 1986, 286, 461-464.

[5]. Khangulov, S. V.; Goldfeld, M. G.; Gerasimenko, V. V.; Andreeva, N. E.; Barynin, V. V.; Grebenko, A. I. J. Inorg. Biochem. 1990, 40, 279-292.
doi:10.1016/0162-0134(90)80062-3

[6]. Kagawa, M.; Murakoshi, N.; Nishikawa, Y.; Matsumoto, G.; Kurata, Y.; Mizobata, T.; Kawata, Y.; Nagai, J. Arch. Biochem. Biophys. 1990, 40, 279-292.

[7]. Willing, A.; Follmann, H.; Auling, G. Eur. J. Biochem. 1988, 170, 603-611.
doi:10.1111/j.1432-1033.1988.tb13740.x
PMid:2828045

[8]. Reczkowski, R. S.; Ash, D. E. J. Am. Chem. Soc. 1992, 114, 10992-10994.
doi:10.1021/ja00053a064

[9]. Cammack, R.; Chapmann, A.; Lu, W.-P.; Karagouni, A. A.; Kelly, D. P. FEBS Lett. 1989, 252, 239-243.
doi:10.1016/0014-5793(89)80967-6

[10]. Carrel, H. L.; Glusker, J. P.; Burger, V.; Manfre, F.; Tritsch, D.; Biellmann, J. F. Proc. Natl. Acad. Sci. U.S.A. 1989, 86, 4440-4444.
doi:10.1073/pnas.86.12.4440

[11]. Whitlow, M.; Howard, A. J.; Finzel, B. C.; Poulos, T. L.; Winborne, E.; Gilliland, G. L. Proteins 1991, 9, 153-173.
doi:10.1002/prot.340090302
PMid:2006134

[12]. Collyer, C. A.; Henrick, K.; Blow, D. M. J. Mol. Biol. 1990, 212, 211-235.
doi:10.1016/0022-2836(90)90316-E

[13]. Davies, J. F.; Hostomka, Z. II.; Hostomsky, Z.; Jordan, S. R.; Matthews, D. A. Science 1991, 252, 88-95.
doi:10.1126/science.1707186
PMid:1707186

[14]. Wilce, M. C.; Bond, C. S.; Dixon, N. E.; Freeman, H. C.; Guss, J. M.; Lilley, P. E.; Wilce, J. A. Proc. Natl. Acad. Sci. U.S.A. 1998, 95, 3472-3477.
doi:10.1073/pnas.95.7.3472

[15]. Pecoraro, V. L. Manganese Redox Enzymes, VCH Publishers, Inc, 1992.

[16]. Kurz, P.; Anderlund, M. F.; Shaikh, N.; Styring, S.; Huang, P. Eur. J. Inorg. Chem. 2008, 5, 762-770.
doi:10.1002/ejic.200700888

[17]. Gultneh, Y.; Tesema, Y. T.; Ahvazi, Bijan; Yisgedu, T. B.; Butcher, R. J.; Tuchagues, J. P. Inorg. Chim. Acta 2006, 359, 4463-4469.
doi:10.1016/j.ica.2006.05.040

[18]. Dubois, L.; Caspar, R.; Jacquamet, L.; Petit, P. E.; Charlot, M. F. Baffert, C.; Collomb, M. N.; Deronzier, A.; Latour, J. M. Inorg. Chem. 2006, 42, 4817-4827.
doi:10.1021/ic020646n
PMid:12895103

[19]. Sakiyama, H.; Sugawara, A.; Sakamoto, M.; Unoura, K.; Inoue, K.; Yamasaki, M. Inorg. Chim. Acta 2000, 310, 163-168.
doi:10.1016/S0020-1693(00)00277-2

[20]. Sakiyama, H.; Igarashi, Y.; Nakayama, Y.; Hossain, M. J.; Unoura, K.; Nishida, Y. Inorg. Chim. Acta 2003, 351, 256-260.
doi:10.1016/S0020-1693(03)00119-1

[21]. Sakiyama, H.; Mochizuki, R.; Sugawara, A.; Sakamoto, M.; Nishida, Y.; Yamasaki, M. J. Chem. Soc., Dalton Trans. 1999, 6, 997-1000.

[22]. Head-Gordon, M.; Pople, J. A.; Frisch, M. J. Chem. Phys. Lett. 1988, 153, 503-506.
doi:10.1016/0009-2614(88)85250-3

[23]. Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 275-280.
doi:10.1016/0009-2614(90)80029-D

[24]. Frisch, M. J.; Head-Gordon, M.; Pople, J. A. Chem. Phys. Lett. 1990, 166, 281-289.
doi:10.1016/0009-2614(90)80030-H

[25]. Head-Gordon, M.; Head-Gordon, T. Chem. Phys. Lett. 1994, 220, 122-128.
doi:10.1016/0009-2614(94)00116-2

[26]. Saebo, S.; Almlof, J. Chem. Phys. Lett. 1989, 154, 83-89.

[27]. Kohn, W.; Becke, A. D.; Parr, R. G. J. Phys. Chem. 1996, 100, 12974-12980.
doi:10.1021/jp960669l

[28]. Becke, A. D. J. Chem. Soc. 1993, 98, 5648-5652.

[29]. Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100.
doi:10.1103/PhysRevA.38.3098
PMid:9900728

[30]. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270-283.

[31]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
doi:10.1016/S0010-8545(00)80455-5

[32]. Unoura, K.; Ooi, T.; Tanaka, K.; Iwase, A. J. Electroanal. Chem. 1988, 252, 335-343.
doi:10.1016/0022-0728(88)80220-1

[33]. Jaffé, H. H. Chem. Revs. 1953, 53, 191-261.
doi:10.1021/cr60165a003

[34]. Hansch, C.; Leo, A.; Taft, R. W. Chem. Rev. 1991, 91, 165-195.
doi:10.1021/cr00002a004

Supporting Agencies

Most read articles by the same author(s)

Most read articles by the same author(s)

Hiroshi Sakiyama, Hidetatsu Inoue, Md.Kudrat-E-Zahan Md.Kudrat-E-Zahan, Shoichi Hueki, Naohisa Tachiya, Yuzo Nishida, Stabilization of 5-aminolevulinic acid by the zinc(II) ion in an aqueous solution , European Journal of Chemistry: Vol. 1 No. 4 (2010): December 2010

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).