OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS
Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct
Evrim Arslan (1) , Ivan Bernal (2) , Roger Lalancette (3,*)
(1) Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA
(2) Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, 2050 Johannesburg, ZA, South Africa
(3) Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA
(*) Corresponding Author
Received: 22 Mar 2022 | Revised: 07 May 2022 | Accepted: 08 May 2022 | Published: 30 Jun 2022 | Issue Date: June 2022
A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca21, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K.
Links for Article
| | | | | | |
| | | | | | |
| | | |
Article MetricsThis Abstract was viewed 207 times | PDF Article downloaded 70 times
The National Science Foundation for NSF-CRIF Grant No. 0443538 and Rutgers University, 73 Warren St., Newark, NJ, 07102, USA.
. Bernal, I.; Rieger, P. H. Solvent effects on the optical and electron spin resonance spectra of vanadyl acetylacetonate. Inorg. Chem. 1963, 2, 256-260.
. Ishida, T.; Mitsubori, S.-I.; Nogami, T.; Takeda, N.; Ishikawa, M.; Iwamura, H. Ferromagnetic exchange coupling of vanadium(IV) dπ spins across pyrimidine rings: Dinuclear complexes of oxovanadium(IV) bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionate) bridged by pyrimidine derivatives. Inorg. Chem. 2001, 40, 7059-7064.
. Bryant, B. E.; Fernelius, W. C.; Busch, D. H.; Stoufer, R. C.; Stratton, W.; Rowe, R. A.; Jones, M. M. Vanadium(IV) Oxy(acetylacetonate). In Inorganic Syntheses; John Wiley & Sons, Inc.: Hoboken, NJ, USA, 2007; pp. 113-116.
. Groom, C. R.; Bruno, I. J.; Lightfoot, M. P.; Ward, S. C. The Cambridge Structural Database. Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 2016, 72, 171-179.
. Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Shields, G. P.; Taylor, R.; Towler, M.; van de Streek, J. Mercury: visualization and analysis of crystal structures. J. Appl. Crystallogr. 2006, 39, 453-457.
. Brandenburg, K.; Putz, H. DIAMOND. Crystal Impact GbR, Bonn, Germany, 1999.
. Bruker SAINT, SADABS, 2009 Bruker AXS Inc., Madison, Wisconsin, USA.
. Bruker APEX 2, Version 2.0-2. 2009 Bruker AXS Inc., Madison, Wisconsin, USA.
. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. A 2008, 64, 112-122.
. Sheldrick, G. M. SHELXT - integrated space-group and crystal-structure determination. Acta Crystallogr. A Found. Adv. 2015, 71, 3-8.
. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. C Struct. Chem. 2015, 71, 3-8.
The Supplementary Material for this article can be found online at: Supplementary files
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.13.2.168-171.2278
| | | | | | | |
| | | | | | |
Save to Zotero Save to Mendeley
European Journal of Chemistry 2022, 13(2), 168-171 | doi: https://doi.org/10.5155/eurjchem.13.2.168-171.2278 | Get rights and content
- There are currently no refbacks.
Copyright (c) 2022 Authors
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.