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Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct
Evrim Arslan (1)
, Ivan Bernal (2) , Roger Lalancette (3,*) (1) Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA
(2) Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, 2050 Johannesburg, ZA, South Africa
(3) Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA
(*) Corresponding Author
Received: 22 Mar 2022 | Revised: 07 May 2022 | Accepted: 08 May 2022 | Published: 30 Jun 2022 | Issue Date: June 2022
Abstract
A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca21, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K.
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DOI: 10.5155/eurjchem.13.2.168-171.2278
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Funding information
The National Science Foundation for NSF-CRIF Grant No. 0443538 and Rutgers University, 73 Warren St., Newark, NJ, 07102, USA.
References
[1]. Bernal, I.; Rieger, P. H. Solvent effects on the optical and electron spin resonance spectra of vanadyl acetylacetonate. Inorg. Chem. 1963, 2, 256-260.
https://doi.org/10.1021/ic50006a004
[2]. Ishida, T.; Mitsubori, S.-I.; Nogami, T.; Takeda, N.; Ishikawa, M.; Iwamura, H. Ferromagnetic exchange coupling of vanadium(IV) dπ spins across pyrimidine rings: Dinuclear complexes of oxovanadium(IV) bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionate) bridged by pyrimidine derivatives. Inorg. Chem. 2001, 40, 7059-7064.
https://doi.org/10.1021/ic010730n
[3]. Bryant, B. E.; Fernelius, W. C.; Busch, D. H.; Stoufer, R. C.; Stratton, W.; Rowe, R. A.; Jones, M. M. Vanadium(IV) Oxy(acetylacetonate). In Inorganic Syntheses; John Wiley & Sons, Inc.: Hoboken, NJ, USA, 2007; pp. 113-116.
https://doi.org/10.1002/9780470132364.ch30
[4]. Groom, C. R.; Bruno, I. J.; Lightfoot, M. P.; Ward, S. C. The Cambridge Structural Database. Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 2016, 72, 171-179.
https://doi.org/10.1107/S2052520616003954
[5]. Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Shields, G. P.; Taylor, R.; Towler, M.; van de Streek, J. Mercury: visualization and analysis of crystal structures. J. Appl. Crystallogr. 2006, 39, 453-457.
https://doi.org/10.1107/S002188980600731X
[6]. Brandenburg, K.; Putz, H. DIAMOND. Crystal Impact GbR, Bonn, Germany, 1999.
[7]. Bruker SAINT, SADABS, 2009 Bruker AXS Inc., Madison, Wisconsin, USA.
[8]. Bruker APEX 2, Version 2.0-2. 2009 Bruker AXS Inc., Madison, Wisconsin, USA.
[9]. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930
[10]. Sheldrick, G. M. SHELXT - integrated space-group and crystal-structure determination. Acta Crystallogr. A Found. Adv. 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370
[11]. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. C Struct. Chem. 2015, 71, 3-8.
https://doi.org/10.1107/S2053229614024218
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DOI Link: https://doi.org/10.5155/eurjchem.13.2.168-171.2278
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European Journal of Chemistry 2022, 13(2), 168-171 | doi: https://doi.org/10.5155/eurjchem.13.2.168-171.2278 | Get rights and content
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