Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct

Evrim Arslan; Ivan Bernal; Roger Lalancette

doi:10.5155/eurjchem.13.2.168-171.2278

PDF CIF FILE SUPPLEMENTARY FILE

Published: Jun 30, 2022

DOI: https://doi.org/10.5155/eurjchem.13.2.168-171.2278

Keywords:

Triazines, Formamide, X-ray diffraction, Metal basic adduct, Magnetic properties, Vanadyl acetylacetonates

Section

Research Article

Issue

Vol. 13 No. 2 (2022): June 2022

Dates

Received 2022-03-22
Accepted 2022-05-08
Published 2022-06-30

Evrim Arslan

Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA

https://orcid.org/0000-0001-9712-3573

Ivan Bernal

Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, 2050 Johannesburg, ZA, South Africa

https://orcid.org/0000-0002-8168-5907

Roger Lalancette

Carl A. Olson Memorial Laboratories, Department of Chemistry, Rutgers University, 73 Warren St., Newark, NJ, 07102, USA

https://orcid.org/0000-0002-3470-532X

Abstract

A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca2₁, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K.

This Abstract was viewed 625 times |

Article PDF downloaded 393 times

Article CIF FILE downloaded 0 times

Article SUPPLEMENTARY FILE downloaded 0 times

How to Cite

(1)

Arslan, E.; Bernal, I.; Lalancette, R. Vanadyl(acetylacetonate)2 Mediated Hydrolytic Splitting of 1,3,5-Triazine in a Solution of Toluene at 130 °C: The Crystal Structure of Its Axial Formamide Adduct. Eur. J. Chem. 2022, 13, 168-171.

Links for Article

Crossref - Scopus - Google - European PMC

References

[1]. Bernal, I.; Rieger, P. H. Solvent effects on the optical and electron spin resonance spectra of vanadyl acetylacetonate. Inorg. Chem. 1963, 2, 256-260.
https://doi.org/10.1021/ic50006a004

[2]. Ishida, T.; Mitsubori, S.-I.; Nogami, T.; Takeda, N.; Ishikawa, M.; Iwamura, H. Ferromagnetic exchange coupling of vanadium(IV) dπ spins across pyrimidine rings: Dinuclear complexes of oxovanadium(IV) bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionate) bridged by pyrimidine derivatives. Inorg. Chem. 2001, 40, 7059-7064.
https://doi.org/10.1021/ic010730n

[3]. Bryant, B. E.; Fernelius, W. C.; Busch, D. H.; Stoufer, R. C.; Stratton, W.; Rowe, R. A.; Jones, M. M. Vanadium(IV) Oxy(acetylacetonate). In Inorganic Syntheses; John Wiley & Sons, Inc.: Hoboken, NJ, USA, 2007; pp. 113-116.
https://doi.org/10.1002/9780470132364.ch30

[4]. Groom, C. R.; Bruno, I. J.; Lightfoot, M. P.; Ward, S. C. The Cambridge Structural Database. Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 2016, 72, 171-179.
https://doi.org/10.1107/S2052520616003954

[5]. Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Shields, G. P.; Taylor, R.; Towler, M.; van de Streek, J. Mercury: visualization and analysis of crystal structures. J. Appl. Crystallogr. 2006, 39, 453-457.
https://doi.org/10.1107/S002188980600731X

[6]. Brandenburg, K.; Putz, H. DIAMOND. Crystal Impact GbR, Bonn, Germany, 1999.

[7]. Bruker SAINT, SADABS, 2009 Bruker AXS Inc., Madison, Wisconsin, USA.

[8]. Bruker APEX 2, Version 2.0-2. 2009 Bruker AXS Inc., Madison, Wisconsin, USA.

[9]. Sheldrick, G. M. A short history of SHELX. Acta Crystallogr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[10]. Sheldrick, G. M. SHELXT - integrated space-group and crystal-structure determination. Acta Crystallogr. A Found. Adv. 2015, 71, 3-8.
https://doi.org/10.1107/S2053273314026370

[11]. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. C Struct. Chem. 2015, 71, 3-8.
https://doi.org/10.1107/S2053229614024218

Supporting Agencies

The National Science Foundation for NSF-CRIF Grant No. 0443538 and Rutgers University, 73 Warren St., Newark, NJ, 07102, USA.

Most read articles by the same author(s)

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).

Article Sidebar

Main Article Content

Abstract

Article Details

Most read articles by the same author(s)

Downloads

Metrics