European Journal of Chemistry 2011, 2(3), 324-330 | doi: https://doi.org/10.5155/eurjchem.2.3.324-330.272 | Get rights and content

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Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent


Ardeshir Shokrollahi (1,*) , Mehrourang Ghaedi (2) , Sara Alipour (3) , Ali Hossein Kianfar (4)

(1) Department of Chemistry, Faculty of Sciences, Yasouj University, Yasouj, 75918-74831, Iran
(2) Department of Chemistry, Faculty of Sciences, Yasouj University, Yasouj, 75918-74831, Iran
(3) University of Applied Science and Technology, Pasargad Branch, Saadatshahr, 73741-173, Iran
(4) Department of Chemistry, Faculty of Sciences, Yasouj University, Yasouj, 75918-74831, Iran
(*) Corresponding Author

Received: 04 Sep 2010 | Revised: 12 Nov 2010 | Accepted: 08 Dec 2010 | Published: 30 Sep 2011 | Issue Date: September 2011

Abstract


The complexation behaviour of some salophen,s derivatives with few transition and heavy metal cations in N,N'-dimethyl formamid as nonaqueous solvent at 25 oC and 0.05 M tetra ethylammonium perchlorate to investigate the effect of structure were studied by spectrophotometric method. The formation of complexes between ligands and metal ions of the types ML, ML2 or M2L was observed. The overall stability constants of such complexes were evaluated by computer refinement of absorption-mole ratio data using the KINFIT program.

2_3_324_330_800


Keywords


Complexation; Salophen’s derivatives; DMF; Spectrophotometric study; KINFIT program; Metal ions

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DOI: 10.5155/eurjchem.2.3.324-330.272

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Yasouj University

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How to cite


Shokrollahi, A.; Ghaedi, M.; Alipour, S.; Kianfar, A. Eur. J. Chem. 2011, 2(3), 324-330. doi:10.5155/eurjchem.2.3.324-330.272
Shokrollahi, A.; Ghaedi, M.; Alipour, S.; Kianfar, A. Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent. Eur. J. Chem. 2011, 2(3), 324-330. doi:10.5155/eurjchem.2.3.324-330.272
Shokrollahi, A., Ghaedi, M., Alipour, S., & Kianfar, A. (2011). Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent. European Journal of Chemistry, 2(3), 324-330. doi:10.5155/eurjchem.2.3.324-330.272
Shokrollahi, Ardeshir, Mehrourang Ghaedi, Sara Alipour, & Ali Hossein Kianfar. "Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent." European Journal of Chemistry [Online], 2.3 (2011): 324-330. Web. 24 Jan. 2022
Shokrollahi, Ardeshir, Ghaedi, Mehrourang, Alipour, Sara, AND Kianfar, Ali. "Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent" European Journal of Chemistry [Online], Volume 2 Number 3 (30 September 2011)

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