European Journal of Chemistry

Modeling of cation diffusion in bifunctional polymers based on cis-tetraphenylcalix[4]resorcinarene

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Published: Mar 28, 2011
DOI: https://doi.org/10.5155/eurjchem.2.1.14-17.297
Keywords:
Cis-tetraphenylcalix[4]resorcinarene, Bifunctional polymers, Ion exchange kinetics, Cation diffusion, Mathematical model, Nanoreactor effect
Section
Research Article
Issue
Vol. 2 No. 1 (2011): March 2011
Dates
Received 2010-10-18
Accepted 2010-11-08
Published 2011-03-28


Main Article Content

Heinrich Naumovich Altshuler
Kemerovo Division of Institute of Solid State Chemistry and Mechanochemistry Siberian Branch of Russian Academy of Sciences, Kemerovo, RU-650099, Russia
Olga Heinrichovna Altshuler
Kemerovo State University, Kemerovo, RU-650043, Russia

Abstract

In this study, we report that interaction of the network functional polymers based on cis-tetraphenylcalix[4]resorcinarene with aqueous solutions of electrolytes is controlled by diffusion of ions in a polymeric phase. The nanoreactor effect consisting in sufficiently high rate increase of a cation diffusion flux in bifunctional polymers containing sulfonic acid and phenol ionogenic groups has been found. For steady and non-steady states the solutions of the fundamental differential equation of cation diffusion in bifunctional polymers by means of the spherical layer model are obtained for a variety of initial and boundary conditions with constant diffusion coefficient. The proposed mathematical model explains the nanoreactor effect in bifunctional polymers.

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How to Cite
(1)
Altshuler, H. N.; Altshuler, O. H. Modeling of Cation Diffusion in Bifunctional Polymers Based on Cis-tetraphenylcalix[4]resorcinarene. Eur. J. Chem. 2011, 2, 14-17.

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Author Biography

Heinrich Naumovich Altshuler, Kemerovo Division of Institute of Solid State Chemistry and Mechanochemistry Siberian Branch of Russian Academy of Sciences, Kemerovo, RU-650099, Russia


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References

[1]. Hogberg, A. G. S. J. Am. Chem. Soc. 1980, 102, 6046-6050.
doi:10.1021/ja00539a012

[2]. Buchachenko, A. L. Usp. Khim. 1999, 2, 99-118.

[3]. Alexandratos, S. D.; Natesan, S. Macromolecules 2001, 34, 206-210.
doi:10.1021/ma0012550

[4]. Altshuler, H.; Ostapova, E.; Fedyaeva, O.; Sapozhnikova, L.; Altshuler, O. Macromol. Symp. 2002, 181, 1-5.
doi:10.1002/1521-3900(200205)181:1<1::AID-MASY1>3.0.CO;2-U

[5]. Altshuler, H.; Sapozhnikova, L.; Ostapova, E.; Fedyaeva, O.; Altshuler, O. Solvent Extr. Ion Exch. 2002, 20, 263-271.
doi:10.1081/SEI-120003026

[6]. Altshuler, O.; Sapozhnikova, L.; Altshuler, H. Polymer Science. Ser. A 2007, 49, 1198-1206.
doi:10.1134/S0965545X07110077

[7]. Altshuler, H.; Abramova, L.; Altshuler, O. Russian Federation patent, Pat No: 2291171, January 2007.

[8]. Sapozhnikova, L.; Altshuler, O.; Malyshenko, N.; Shkurenko, G.; Ostapova, E.; Tryasunov, B.; Altshuler, H. Int. J. Hydrogen Energ. 2011, 36, 1259-1263.
doi:10.1016/j.ijhydene.2010.06.124

[9]. Altshuler, H. N.; Ostapova, E. V.; Evdoshenko, A. A. Russ. J. Appl. Chem. 2006, 79, 82-84.
doi:10.1134/S1070427206010174

[10]. Altshuler, H. N.; Fedyaeva, O. N.; Sapozhnikova, L. A.; Ostapova, E. V. Vysokomol. Soedin. Ser. B 2001, 43, 755-759.

[11]. Ostapova, E. V.; Altshuler, O. H.; Sapozhnikova, L. A.; Altshuler, H. N. Russ. J. Phys. Chem. A 2003, 77, 909-913.

[12]. Altshuler, G. N.; Sapozhnikova, L. A.; Abramova, L. P. Russ. Chem. Bull. 1998, 47, 2146-2148.
doi:10.1007/BF02494269

[13]. Altshuler, H. N.; Fedyaeva, O. N.; Ostapova, E. V. Russ. Chem. Bull. 2000, 49, 1468-1470.
doi:10.1007/BF02495099

[14]. Altshuler, H.; Sapozhnikova, L.; Ostapova, E.; Altshuler, O. Russ. J. Phys. Chem. A 2007, 81, 1159-1164.

[15]. Altshuler, H. N; Ostapova, E. V.; Sapoznikova, L. A.; Altshuler, O. H. J. Therm. Anal. Calorim. 2008, 92, 665-669.
doi:10.1007/s10973-008-9011-5

[16]. Fedoseeva, O. N.; Cherneva, E. P.; Tunitskii, N. N. Zh. Fiz Khim. 1959, 33, 936-938.

[17]. Altshuler, H.; Malyshenko, N.; Shkurenko, G. Russ. J. Appl. Chem. 2007, 80, 1737-1740.
doi:10.1134/S107042720710028X

[18]. Altshuler, O. H.; Malyshenko, N. V.; Shkurenko, G. J.; Altshuler, H. N. Theor. Found. Chem. Eng. 2009, 43, 43-49.
doi:10.1134/S0040579509010060

[19]. Helfferich F., Ionenaustauscher, Verlag Chemie, 1959.

[20]. Helfferich, F. J. Phys. Chem. 1965, 69, 1178-1187.
doi:10.1021/j100888a015

[21]. Crank J. The Matematics of Diffusion, 2nd edition, Clarendon Press, 1975.

[22]. Boyd, G.; Adamson, A.; Myers, L. J. Am. Chem. Soc. 1947, 69, 2836-2848.
doi:10.1021/ja01203a066
PMid:20270838

Supporting Agencies

This work was supported by the Russian Foundation for Basic Research (Project No, 07-03-96030).
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