

Modeling of cation diffusion in bifunctional polymers based on cis-tetraphenylcalix[4]resorcinarene
Heinrich Naumovich Altshuler (1,*)


(1) Kemerovo Division of Institute of Solid State Chemistry and Mechanochemistry Siberian Branch of Russian Academy of Sciences, Kemerovo, RU-650099, Russia
(2) Kemerovo State University, Kemerovo, RU-650043, Russia
(*) Corresponding Author
Received: 18 Oct 2010 | Accepted: 08 Nov 2010 | Published: 28 Mar 2011 | Issue Date: March 2011
Abstract
In this study, we report that interaction of the network functional polymers based on cis-tetraphenylcalix[4]resorcinarene with aqueous solutions of electrolytes is controlled by diffusion of ions in a polymeric phase. The nanoreactor effect consisting in sufficiently high rate increase of a cation diffusion flux in bifunctional polymers containing sulfonic acid and phenol ionogenic groups has been found. For steady and non-steady states the solutions of the fundamental differential equation of cation diffusion in bifunctional polymers by means of the spherical layer model are obtained for a variety of initial and boundary conditions with constant diffusion coefficient. The proposed mathematical model explains the nanoreactor effect in bifunctional polymers.
Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF

DOI: 10.5155/eurjchem.2.1.14-17.297
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics


Funding information
This work was supported by the Russian Foundation for Basic Research (Project No: 07-03-96030).
Citations
[1]. O. G. Al’tshuler, G. Yu. Shkurenko, A. A. Gorlov, G. N. Al’tshuler
Diffusion kinetics of the ion exchange of benzocaine on sulfocationites
Russian Journal of Physical Chemistry A 90(6), 1238, 2016
DOI: 10.1134/S0036024416060029

[2]. T. N. Pashirova, E. P. Zhil´tsova, S. S. Lukashenko, E. M. Gibadullina, A. R. Burilov, L. Ya. Zakharova, A. I. Konovalov
Supramolecular systems based on polyethyleneimines and octa-2-hydroxyethylated calix[4]resorcinarenes. Aggregation and catalytic activity
Russian Chemical Bulletin 65(5), 1272, 2016
DOI: 10.1007/s11172-016-1447-3

[3]. O. H. Altshuler, G. Yu. Shkurenko, H. N. Altshuler
Weak Base Diffusion in Strong Acid Cation Exchangers
Solvent Extraction and Ion Exchange 34(5), 502, 2016
DOI: 10.1080/07366299.2016.1207392

[4]. G. N. Al’tshuler, G. Yu. Shkurenko, A. A. Gorlov
Kinetics of the reduction of p-nitrobenzoic acid esters in nanoreactors on the basis of sulfonated polymers
Russian Journal of Physical Chemistry A 89(3), 372, 2015
DOI: 10.1134/S0036024415030024

References
[1]. Hogberg, A. G. S. J. Am. Chem. Soc. 1980, 102, 6046-6050.
doi:10.1021/ja00539a012
[2]. Buchachenko, A. L. Usp. Khim. 1999, 2, 99-118.
[3]. Alexandratos, S. D.; Natesan, S. Macromolecules 2001, 34, 206-210.
doi:10.1021/ma0012550
[4]. Altshuler, H.; Ostapova, E.; Fedyaeva, O.; Sapozhnikova, L.; Altshuler, O. Macromol. Symp. 2002, 181, 1-5.
doi:10.1002/1521-3900(200205)181:1<1::AID-MASY1>3.0.CO;2-U
[5]. Altshuler, H.; Sapozhnikova, L.; Ostapova, E.; Fedyaeva, O.; Altshuler, O. Solvent Extr. Ion Exch. 2002, 20, 263-271.
doi:10.1081/SEI-120003026
[6]. Altshuler, O.; Sapozhnikova, L.; Altshuler, H. Polymer Science. Ser. A 2007, 49, 1198-1206.
doi:10.1134/S0965545X07110077
[7]. Altshuler, H.; Abramova, L.; Altshuler, O. Russian Federation patent, Pat No: 2291171, January 2007.
[8]. Sapozhnikova, L.; Altshuler, O.; Malyshenko, N.; Shkurenko, G.; Ostapova, E.; Tryasunov, B.; Altshuler, H. Int. J. Hydrogen Energ. 2011, 36, 1259-1263.
doi:10.1016/j.ijhydene.2010.06.124
[9]. Altshuler, H. N.; Ostapova, E. V.; Evdoshenko, A. A. Russ. J. Appl. Chem. 2006, 79, 82-84.
doi:10.1134/S1070427206010174
[10]. Altshuler, H. N.; Fedyaeva, O. N.; Sapozhnikova, L. A.; Ostapova, E. V. Vysokomol. Soedin. Ser. B 2001, 43, 755-759.
[11]. Ostapova, E. V.; Altshuler, O. H.; Sapozhnikova, L. A.; Altshuler, H. N. Russ. J. Phys. Chem. A 2003, 77, 909-913.
[12]. Altshuler, G. N.; Sapozhnikova, L. A.; Abramova, L. P. Russ. Chem. Bull. 1998, 47, 2146-2148.
doi:10.1007/BF02494269
[13]. Altshuler, H. N.; Fedyaeva, O. N.; Ostapova, E. V. Russ. Chem. Bull. 2000, 49, 1468-1470.
doi:10.1007/BF02495099
[14]. Altshuler, H.; Sapozhnikova, L.; Ostapova, E.; Altshuler, O. Russ. J. Phys. Chem. A 2007, 81, 1159-1164.
[15]. Altshuler, H. N; Ostapova, E. V.; Sapoznikova, L. A.; Altshuler, O. H. J. Therm. Anal. Calorim. 2008, 92, 665-669.
doi:10.1007/s10973-008-9011-5
[16]. Fedoseeva, O. N.; Cherneva, E. P.; Tunitskii, N. N. Zh. Fiz Khim. 1959, 33, 936-938.
[17]. Altshuler, H.; Malyshenko, N.; Shkurenko, G. Russ. J. Appl. Chem. 2007, 80, 1737-1740.
doi:10.1134/S107042720710028X
[18]. Altshuler, O. H.; Malyshenko, N. V.; Shkurenko, G. J.; Altshuler, H. N. Theor. Found. Chem. Eng. 2009, 43, 43-49.
doi:10.1134/S0040579509010060
[19]. Helfferich F., Ionenaustauscher, Verlag Chemie, 1959.
[20]. Helfferich, F. J. Phys. Chem. 1965, 69, 1178-1187.
doi:10.1021/j100888a015
[21]. Crank J. The Matematics of Diffusion, 2nd edition, Clarendon Press, 1975.
[22]. Boyd, G.; Adamson, A.; Myers, L. J. Am. Chem. Soc. 1947, 69, 2836-2848.
doi:10.1021/ja01203a066
PMid:20270838
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.2.1.14-17.297

















European Journal of Chemistry 2011, 2(1), 14-17 | doi: https://doi.org/10.5155/eurjchem.2.1.14-17.297 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.