European Journal of Chemistry

Modeling of cation diffusion in bifunctional polymers based on cis-tetraphenylcalix[4]resorcinarene

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Published: Mar 28, 2011
DOI: https://doi.org/10.5155/eurjchem.2.1.14-17.297
Keywords:
Cis-tetraphenylcalix[4]resorcinarene, Bifunctional polymers, Ion exchange kinetics, Cation diffusion, Mathematical model, Nanoreactor effect
Section
Research Article
Issue
Vol. 2 No. 1 (2011): March 2011
Dates
Received 2010-10-18
Accepted 2010-11-08
Published 2011-03-28


Main Article Content

Heinrich Naumovich Altshuler
Kemerovo Division of Institute of Solid State Chemistry and Mechanochemistry Siberian Branch of Russian Academy of Sciences, Kemerovo, RU-650099, Russia
Olga Heinrichovna Altshuler
Kemerovo State University, Kemerovo, RU-650043, Russia

Abstract

In this study, we report that interaction of the network functional polymers based on cis-tetraphenylcalix[4]resorcinarene with aqueous solutions of electrolytes is controlled by diffusion of ions in a polymeric phase. The nanoreactor effect consisting in sufficiently high rate increase of a cation diffusion flux in bifunctional polymers containing sulfonic acid and phenol ionogenic groups has been found. For steady and non-steady states the solutions of the fundamental differential equation of cation diffusion in bifunctional polymers by means of the spherical layer model are obtained for a variety of initial and boundary conditions with constant diffusion coefficient. The proposed mathematical model explains the nanoreactor effect in bifunctional polymers.

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How to Cite
(1)
Altshuler, H. N.; Altshuler, O. H. Modeling of Cation Diffusion in Bifunctional Polymers Based on Cis-tetraphenylcalix[4]resorcinarene. Eur. J. Chem. 2011, 2, 14-17.

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Author Biography

Heinrich Naumovich Altshuler, Kemerovo Division of Institute of Solid State Chemistry and Mechanochemistry Siberian Branch of Russian Academy of Sciences, Kemerovo, RU-650099, Russia


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Supporting Agencies

This work was supported by the Russian Foundation for Basic Research (Project No, 07-03-96030).
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