Synthesis, characterization and crystal structure of  2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole

Mohamed Ziaulla; Maralavadi Nagaraju Manjunatha; Kuderu Rajendraswamy Nagasundara; Noor Shahina Begum

doi:10.5155/eurjchem.2.1.58-60.350

European Journal of Chemistry 2011, 2(1), 58-60 | doi: https://doi.org/10.5155/eurjchem.2.1.58-60.350 | Get rights and content

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Synthesis, characterization and crystal structure of 2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole

Mohamed Ziaulla ^(1,*)

, Maralavadi Nagaraju Manjunatha ⁽²⁾

, Kuderu Rajendraswamy Nagasundara ⁽³⁾

, Noor Shahina Begum ⁽⁴⁾

⁽¹⁾ Department of Chemistry, Bangalore University, Bangalore, IN-560001, India
⁽²⁾ Department of Chemistry, Bangalore University, Bangalore, IN-560001, India
⁽³⁾ Department of Chemistry, Bangalore University, Bangalore, IN-560001, India
⁽⁴⁾ Department of Chemistry, Bangalore University, Bangalore, IN-560001, India
^(*) Corresponding Author

Received: 25 Nov 2010 | Revised: 04 Dec 2010 | Accepted: 05 Dec 2010 | Published: 28 Mar 2011 | Issue Date: March 2011

Abstract

An efficient synthesis of the title compound, 2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole, was carried out by the condensation reaction of o-phenylenediamine and p-thiomethyl benzaldehyde in benzene. The structure was confirmed by spectroscopic data and elemental analyses. The molecular structure was determined from single crystal X‐ray diffraction data. The compound crystallizes in the orthorhombic space group Pbca with a = 8.544(2) Å, b = 9.700(3) Å, c = 29.684(8) Å, V = 2460.0(11) Å³, Z = 8. The crystal structure is stabilized by intermolecular C-H…N, N-H…N and π-π interactions.

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Keywords

2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole; Benzimidazole; Crystal structure; Hydrogen bond; pi-pi Interactions; Spectroscopy

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DOI: 10.5155/eurjchem.2.1.58-60.350

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Funding information

University Grants Commission (UGC), India for the financial assistance and Department of Science and Technology (DST), India for data collection.

Citations

[1]. Abbas Washeel Salman, Rosenani A. Haque, Srinivasa Budagumpi, H. Zetty Zulikha
Coordination diversity of Ag(I) and Hg(II) towards symmetrically and non-symmetrically substituted imidazol-2-ylidenes: Synthesis, crystal structures, nitrile reactivity, and Hofmann-type elimination studies
Polyhedron 49(1), 200, 2013
DOI: 10.1016/j.poly.2012.09.020

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Supporting information

The Supplementary Material for this article can be found online at: Supplementary files

How to cite

Ziaulla, M.; Manjunatha, M.; Nagasundara, K.; Begum, N. Eur. J. Chem. 2011, 2(1), 58-60. doi:10.5155/eurjchem.2.1.58-60.350

Ziaulla, M.; Manjunatha, M.; Nagasundara, K.; Begum, N. Synthesis, characterization and crystal structure of 2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole. Eur. J. Chem. 2011, 2(1), 58-60. doi:10.5155/eurjchem.2.1.58-60.350

Ziaulla, M., Manjunatha, M., Nagasundara, K., & Begum, N. (2011). Synthesis, characterization and crystal structure of 2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole. European Journal of Chemistry, 2(1), 58-60. doi:10.5155/eurjchem.2.1.58-60.350

Ziaulla, Mohamed, Maralavadi Nagaraju Manjunatha, Kuderu Rajendraswamy Nagasundara, & Noor Shahina Begum. "Synthesis, characterization and crystal structure of 2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole." European Journal of Chemistry [Online], 2.1 (2011): 58-60. Web. 3 Jun. 2023

Ziaulla, Mohamed, Manjunatha, Maralavadi, Nagasundara, Kuderu, AND Begum, Noor. "Synthesis, characterization and crystal structure of 2-(4-(methylthio)phenyl)-1H-benzo[d]imidazole" European Journal of Chemistry [Online], Volume 2 Number 1 (28 March 2011)

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