European Journal of Chemistry

Electrochemical study of the metal extractant 4-chloro-N-8-quinolinylbenzenesulfonamide

Article Sidebar

PDF
Published: Dec 31, 2011
DOI: https://doi.org/10.5155/eurjchem.2.4.441-447.417
Keywords:
Voltamperometry, LIX 34, Copper, Reduction Metal extractant, Sulfonamidoquinoline
Section
Research Article
Issue
Vol. 2 No. 4 (2011): December 2011
Dates
Received 2011-03-16
Accepted 2011-05-13
Published 2011-12-31


Main Article Content

Marta Huebra
Department of Applied Physics I, Universidad del País Vasco/Euskal Herriko Unibersitatea, La Casilla 3, 48012 Bilbao, Spain
Maria Puy Elizalde
Department of Analytical Chemistry, Universidad del País Vasco/Euskal Herriko Unibersitatea, Apdo. 644, 48080 Bilbao, Spain

Abstract

The electrochemical behaviour of the reagent 4-chloro-N-8-quinolinylbenzenesulfonamide has been studied by sampled direct current and differential pulse polarography as well as by cyclic voltamperometry techniques. Three reduction waves are obtained and the reversibility and nature of the electrodic processes are discussed. The first and third reduction waves have been explained through chemical reactions and adsorption processes involving the interaction with mercury as electrodic material, whereas the second wave is attributed to the reduction process of the reagent itself. Acidity constant values of the compound in 0.1 M KCl / 25 % methanol medium through polarographic measurements are also given. The influence of the addition of copper to the hydroalcoholic solution in the electrochemical reduction of the reagent is also described.

2_4_441_447_800


icon graph This Abstract was viewed 1244 times | icon graph Article PDF downloaded 738 times

How to Cite
(1)
Huebra, M.; Elizalde, M. P. Electrochemical Study of the Metal Extractant 4-Chloro-N-8-Quinolinylbenzenesulfonamide. Eur. J. Chem. 2011, 2, 441-447.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Yu, W.; Freiser, H. Talanta 1989, 36, 347-349.
http://dx.doi.org/10.1016/0039-9140(89)80119-5

[2]. Yu, W.; Freiser, H. Anal. Sci. 1987, 3, 401-403.
http://dx.doi.org/10.2116/analsci.3.401

[3]. Doe, H.; Freiser, H. Anal. Sci. 1991, 7, 303-311.
http://dx.doi.org/10.2116/analsci.7.303

[4]. Mickler, W.; Mönner, A.; Uhleman, E.; Wilke, S.; Müller, H. J. Electroanal. Chem. 1999, 469, 91-96.
http://dx.doi.org/10.1016/S0022-0728(99)00175-8

[5]. Uehara, A.; Kasuno, M.; Okugaki, T.; Kitatsuji, Y.; Shirai, O.; Yoshida, Z.; Kihara, S.; J. Electroanal. Chem. 2007, 604, 115-124.
http://dx.doi.org/10.1016/j.jelechem.2007.03.017

[6]. Kordosky, G. A.; Mackay K. D.; Virnig, M. J. Transactions of the Society of Mining Engineers of AIME 1977, 262, 36-42.

[7]. Sandström, G.; Hummelstedt, L. Proc. Int. Solvent Extraction 1980, 80-81.

[8]. Germain, G.; Declercq, J. P.; Castresana, J. M.; Elizalde, M. P.; Arrieta, J. M. Acta Cryst. 1983, 39, 230-232.

[9]. Elizalde, M. P.; Castresana, J. M.; Aguilar, M.; Cox, M. Chemica Scripta 1985, 25, 300-304.

[10]. Castresana, J. M.; Aparicio, J. L.; Elizalde, M. P.; Aguilar, M.; Cox, M. Hydrometallurgy 1986, 15, 363-379.
http://dx.doi.org/10.1016/0304-386X(86)90067-8

[11]. Castresana, J. M.; Elizalde, M. P.; Aguilar, M.; Cox, M. Chemica Scripta 1987, 27, 273-276.

[12]. Castresana, J. M.; Elizalde, M. P.; Aguilar, M.; Cox, M. Chemica Scripta 1986, 26, 325-329.

[13]. Huebra, M. M.; Elizalde, M. P.; Castresana, J. M. Electroanalysis 1994, 6, 785-790.
http://dx.doi.org/10.1002/elan.1140060913

[14]. Almela, A.; Huebra, M. M.; Elizalde, M. P.; Menoyo, B. J. Chem. Technol. Biotechnol. 2004, 79, 299-305.
http://dx.doi.org/10.1002/jctb.988

[15]. Perrin, D. D.; Dempsey, B.; Serjeant, E. P. pKa prediction for organic acids and bases, Chapman and Hall, London and New York, 1981.

[16]. Cottrell, P. T.; Mann, C. K. J. Amer. Chem. Soc. 1971, 93, 3579-3583.
http://dx.doi.org/10.1021/ja00744a006

[17]. Nicholson, R. S.; Shain, I. Anal. Chem. 1964, 36, 706-723.
http://dx.doi.org/10.1021/ac60210a007

[18]. Muller, C.; Claret, J.; Sarret, M. Electrochim. Acta 1987, 32, 283-287.
http://dx.doi.org/10.1016/0013-4686(87)85036-3

[19]. Gupta, S. L.; Raghavan, P. S. Electrochim. Acta 1971, 16, 1613-1618.
http://dx.doi.org/10.1016/0013-4686(71)85071-5

[20]. Heyrovsky, M.; Mader, P.; Vavricka, S.; Vesela, V.; Fedurco, M. J. Electroanal. Chem. 1997, 430, 103-117.
http://dx.doi.org/10.1016/S0022-0728(97)00103-4

[21]. Zuman, P. Microchem. J. 1997, 57, 4-51.
http://dx.doi.org/10.1006/mchj.1997.1468

[22]. Wopschall, R. H.; Shain, I. Anal. Chem. 1967, 39, 1514-1527.
http://dx.doi.org/10.1021/ac50156a018

[23]. Bond, A. M.; Thomson, S. B.; Tucker, D. J.; Briggs, M. H. Anal. Chim. Acta 1984, 156, 33-42.
http://dx.doi.org/10.1016/S0003-2670(00)85534-8

[24]. Mairanovskii, S. G. J. Electroanal. Chem. 1966, 12, 547-552.

[25]. Mader, P. Collection Czech. Chem. Commun. 1971, 36, 1035-1064.

Supporting Agencies

Universidad del Pais Vasco/Euskal Herriko Unibersitatea, Bilbao, Spain
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).