European Journal of Chemistry

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure



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Hossein Eshtiagh-Hosseini
Milad Mahjoobizadeh
Masoud Mirzaei
Katharina Fromm
Aurelien Crochet

Abstract

A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6-triamino-1,3,5-triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X-ray structure determination. The crystal structure of the title compound consists of bis-2,4,6-triamino-1,3,5-triazin-1-ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O-H•••O, N-H•••O, and N-H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π-π stacking (centroid-centroid ranges 3.410-3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network.

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Eshtiagh-Hosseini, H.; Mahjoobizadeh, M.; Mirzaei, M.; Fromm, K.; Crochet, A. A New Three Dimensional Proton Transfer Compound Including Citric Acid and 2,4,6-Triamine-1,3,5-Triazine: Synthesis, Characterization and X-Ray Crystal Structure. Eur. J. Chem. 2010, 1, 179-181.

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Author Biography

Hossein Eshtiagh-Hosseini, Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran

Professor of inorganic chemistry
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