European Journal of Chemistry

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure

Article Sidebar

PDF
Published: Sep 29, 2010
DOI: https://doi.org/10.5155/eurjchem.1.3.179-181.44
Keywords:
Proton transfer compound, X-ray crystal structure, 2, 4, 6-Triamino-1, 3, 5-triazine, Citric acid, π−π Stacking
Section
Research Article
Issue
Vol. 1 No. 3 (2010): September 2010
Dates
Received 2010-04-07
Accepted 2010-08-04
Published 2010-09-29


Main Article Content

Hossein Eshtiagh-Hosseini
Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
Milad Mahjoobizadeh
Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
Masoud Mirzaei
Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran
Katharina Fromm
Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland
Aurelien Crochet
Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland

Abstract

A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6-triamino-1,3,5-triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X-ray structure determination. The crystal structure of the title compound consists of bis-2,4,6-triamino-1,3,5-triazin-1-ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O-H•••O, N-H•••O, and N-H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π-π stacking (centroid-centroid ranges 3.410-3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network.

1_3_179_181_800


icon graph This Abstract was viewed 2482 times | icon graph Article PDF downloaded 866 times

How to Cite
(1)
Eshtiagh-Hosseini, H.; Mahjoobizadeh, M.; Mirzaei, M.; Fromm, K.; Crochet, A. A New Three Dimensional Proton Transfer Compound Including Citric Acid and 2,4,6-Triamine-1,3,5-Triazine: Synthesis, Characterization and X-Ray Crystal Structure. Eur. J. Chem. 2010, 1, 179-181.

Article Details

Author Biography

Hossein Eshtiagh-Hosseini, Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, 917791436, Mashhad, Iran

Professor of inorganic chemistry
Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Sharif, M. A.; Aghabozorg, H.; Shokrollahi, A.; Kickelbick, G.; Moghimi, A.; Shamsipur, M. Polish J. Chem. 2006, 80, 847-863.

[2]. Aghabozorg, H.; Aghajani, Z.; Sharif, M. A. Acta Cryst. 2006, E62, m1930-m1932.

[3]. Aghabozorg, H.; Attar Gharamaleki, J.; Daneshvar, S.; Ghadermazi, M.; Khavasi, H. R. Acta Cryst. 2008, E64, m187-m188.

[4]. Aghajani, Z.; Sharif, M. A.; Aghabozorg, H.; Naderpour, A. Acta Cryst. 2006, E62, m830-m832.

[5]. Sharif, M. A.; Aghabozorg, H.;Moghimi, A. Acta Cryst. 2007, E63, m1599-m1601.

[6]. Perpétuo, G. J.; Janczak, J. Acta Cryst. 2006, C62, o372-o375.

[7]. Zhang, X.-L.; Chen, X.-M.; Ng, S.W. Acta Cryst. 2005, E61, o156-o157.

[8]. Perpétuo, G. J.; Janczak, J. Acta Cryst. 2005, E61, o287-o289.

[9]. Janczak, J.; Perpétuo, G. J. Acta Cryst. 2001, C57, 123-125.

[10]. Zhang, J.; Kang, Y.; Wen, Y.-H.; Li, Z.-J.; Qin, Y.-Y.; Yao, Y.-G. Acta Cryst. 2004, E60, o462- o463.

[11]. Zhang, X.-L.; Chen, X.-M. Cryst. Growth Des. 2005, 5, 617-622.
doi:10.1021/cg0498251

[12]. Karle, I.; Gilardi, R.D.; Rao, C.C.; Muraleedharan, K.M.; Ranganathan, S. J. Chem. Crystallogr. 2003, 33, 727-749.
doi:10.1023/A:1026151222486

[13]. Janczak, J.; Perpétuo, G.J. Acta Cryst. 2001, C57, 1431-1433.

[14]. Zhu, B.-Y.; Cui, D.-L. and Jing, H.-P. Acta Cryst. 2008, E64, o351-o351.

[15]. Aghabozorg, H.; Manteghi, F.; Ghadermazi, M.; Mirzaei, M.; Salimi, A.R.; Eshtiagh-Hosseini, H. J. Iran. Chem. Soc., 2010, 7(2), 500-509.

[16]. Aghabozorg, H.; Manteghi, F.; Sheshmani, S. J. Iran. Chem. Soc. 2008, 5, 184-227.

[17]. Aghabozorg, H.; Manteghi, F.; Ghadermazi, M.; Mirzaei, M.; Salimi, A.R.; Shokrollahi, A.; Derki, S.; Eshtiagh-Hosseini, H. J. Mol. Struct. 2009, 919, 381-388.
doi:10.1016/j.molstruc.2008.10.019

[18]. Eshtiagh-Hosseini, H.; Yousefi, Z.; Mirzaei, M. Acta Cryst. 2009, E65, o2816-o2816.

[19]. Eshtiagh-Hosseini, H.; Yousefi, Z.; Mirzaei, M.; Chen, Y.-G.; Beyramabadi, S.A.; Shokrollahi, A.; Aghaei, R. J. Mol. Struct. 2010, 973, 1-8.
doi:10.1016/j.molstruc.2010.02.054

[20]. Eshtiagh-Hosseini, H.; Mirzaei, M.; Aghabozorg, H.; Beyramabadi, S.A.; Eshghi, H.; Morsali, A.; Shokrollahi, A.; Aghaei, R. Spectrochim Acta Part A, 2010, In press.

[21]. Eshtiagh-Hosseini, H.; Aghabozorg, H.; Mirzaei, M. Acta Cryst. 2010, E66, m882-m882.

[22]. Eshtiagh-Hosseini, H.; Aghabozorg, H.; Mirzaei, M.; Amini, M.M.; Chen, Y.G.; Shokrollahi, A.; Aghaei, R. J. Mol. Struct. 2010, 973, 180-189.
doi:10.1016/j.molstruc.2010.03.068

[23]. Eshtiagh-Hosseini, H.; Yousefi, Z.; Shafiee, M.; Mirzaei, M. J. Coord. Chem. 2010, 63, 3187-3197
doi:10.1080/00958972.2010.508284

[24]. Eshtiagh-Hosseini, H.; Hassanpoor, A.; Alfi, N.; Mirzaei, M.; Fromm, K.M.; Shokrollahi, A.; Gschwind, F.; Aghaei, R. J. Coord. Chem. 2010, 63, 3175-3186
doi:10.1080/00958972.2010.508518

[25]. Eshtiagh-Hosseini, H.; Hassanpoor, A.; Canadillas-Delgado, L.; Mirzaei, M. Acta Crystallogr. 2010, E66, o1368-o1368.

[26]. Eshtiagh-Hosseini, H.; Gschwind, F.; Alfi, N.; Mirzaei, M. Acta Cryst. 2010, E66, m826-m826.

[27]. Aghabozorg, H.; Eshtiagh-Hosseini, H.; Mirzaei, M.; Salimi, A.R. J. Iran. Chem. Soc., 2010, 7(2), 289-300.

[28]. Eshtiagh-Hosseini, H.; Aghabozorg, H.; Shamsipur, M.; Mirzaei, M.; Ghanbari, M. J. Iran. Chem. Soc. 2010, In press.

[29]. Sheldrick, G.M. Acta Cryst. 2008, A64, 112-122.

[30]. Etter, M.C.; MacDonald, J.C.; Bernstein, J. Acta Cryst. 1990, B46, 256-262.

[31]. Aghabozorg, H.; Ghadermazi, M.; Nakhjavan, B.; Manteghi, F. J. Chem. Crystallogr. 2008, 38, 135-145.
doi:10.1007/s10870-007-9279-5

Supporting Agencies

Ferdowsi University of Mashhad, Mashhad, Iran
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).