European Journal of Chemistry

Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene

Article Sidebar

PDF
Published: Mar 31, 2012
DOI: https://doi.org/10.5155/eurjchem.3.1.57-64.448
Keywords:
EPR, Antimicrobial, Molecular modeling, Potential separation, Splitting parameters, Coordination entities
Section
Research Article
Issue
Vol. 3 No. 1 (2012): March 2012
Dates
Received 2011-04-24
Accepted 2011-06-17
Published 2012-03-31


Main Article Content

Rajiv Kumar
Department of Chemistry, Shivaji College University of Delhi, New Delhi, 110027, India
Rajni Johar
Department of Chemistry, Guru Govind Singh Indraprashtha University, New Delhi, 110002, India
Anil Krishan Aggarwal
Department of Chemistry, Shivaji College University of Delhi, New Delhi, 110027, India

Abstract

9,17-Diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene, macrocycle was synthesized, thereafter formulation and designing strategies applied for the preparation of coordination entities of Co(II) and Ni(II). Coordination behaviour of N2S4 donor macrocycle towards metal ion(s) was assessed by physiochemical measurements and spectral investigations viz. elemental analysis, molar conductance, magnetic susceptibility measurements, infrared, UV-Vis, 1H and 13 C NMR, mass spectroscopy, electron paramagnetic resonance (EPR), cyclic voltammetry and molecular modeling. Side-by-side comparison of the spectral findings exposed different geometrical aspects of macrocycle and coordination entities. Cyclic voltammogram showed fully oxidized and reduced species in one unified experiment. Macrocycle and coordination entities were screened for antimicrobial effectiveness (antifungal properties against Aspergillus-niger).

3_1_57_64_800


icon graph This Abstract was viewed 3284 times | icon graph Article PDF downloaded 836 times

How to Cite
(1)
Kumar, R.; Johar, R.; Aggarwal, A. K. Synthesis, Structural Elucidation and Antimicrobial Effectiveness of Coordination Entities of Cobalt (II) and Nickel (II) Derived from 9,17-Diaza-2,6,11,15-Tetrathia-1,7,10,16-(1,2)-Tetrabenzenacyclooctadecaphan-8,17-Diene. Eur. J. Chem. 2012, 3, 57-64.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Saeeda, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. Eur. J. Chem. 2010, 1(3), 221‐227.
http://dx.doi.org/10.5155/eurjchem.1.3.221-227.124

[2]. Aghatabay, M. N.; Mahmiani, Y.; Cevik, H.; Dulger, B. Eur. J. Med. Chem. 2009, 44, 365-372.
http://dx.doi.org/10.1016/j.ejmech.2008.02.038
PMid:18417256

[3]. Aghatabay, M. N.; Bas, A.; Kircali, A.; Sen, G.; Yazicioglu, M. B.; Gucin, F.; Dulger, B. Eur. J. Med. Chem. 2009, 44, 4681-4689.
http://dx.doi.org/10.1016/j.ejmech.2009.07.003
PMid:19700225

[4]. Boeyens, J. C. A.; Dobson, S. M.; Bernal, I. Stereochemical and Stereo-physical Behaviour of Macrocycles, Vol. 2. Elsevier, Amsterdam, 1987.

[5]. Lippard, S. J.; Berg, M. J. Principles of Bioinorganic Chemistry, University Science Books, Mill Valley, 1994.

[6]. Chandra, S.; Kumar, R. Trans. Metal Chem. 2004, 29, 269-275.
http://dx.doi.org/10.1023/B:TMCH.0000020359.84853.72

[7]. Allinger, N. L. J. Am. Chem. Soc. 1977, 99, 8127-8134.
http://dx.doi.org/10.1021/ja00467a001

[8]. Saeeda, S.; Rashida, N.; Alib, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200‐205.
http://dx.doi.org/10.5155/eurjchem.1.3.200-205.120

[9]. Odhiambo, R.; Muthakia, G. K.; Kagwanja, S. M. Bull. Chem. Soc. Ethiop. 2010, 24(1), 47-58.

[10]. Mehmet, K.; Ismail, Y.; Semra, K.; Atıf, K. Polyhedron 2002, 21, 825-834.
http://dx.doi.org/10.1016/S0277-5387(02)00860-4

[11]. Yuan, J. L.; Zhang, Q. L.; Liang, X.; Zhu, B. X.; Lindoy, L. F.; Wet, G. Polyhedron 2008, 27, 344-348.
http://dx.doi.org/10.1016/j.poly.2007.09.012

[12]. Anvarhuaein, A. I.; Mohammed, I.; Wazer, M. J. Coord. Chem. 2005, 58, 529-537.
http://dx.doi.org/10.1080/00958970500038951

[13]. Ilhan, S.; Temel, H.; Yilmaz, I.; Sekerci, M. J. Organomet. Chem. 2007, 692, 3855-3865.
http://dx.doi.org/10.1016/j.jorganchem.2007.05.031

[14]. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd edition, Wiley Interscience, New York, 1978.

[15]. Karadeniz, H.; Gok, Y.; Kantekin, H. Dyes Pigm. 2007, 75, 498-504.
http://dx.doi.org/10.1016/j.dyepig.2006.06.027

[16]. Aghatabay, N. M.; Somer, M.; Senel, M.; Dulger, B.; Gucin, F. Eur. J. Med. Chem. 2007, 42, 1069-1075.
http://dx.doi.org/10.1016/j.ejmech.2007.01.011
PMid:17350734

[17]. Kahn, O. Molecular Magnetism, VCH, New York, 1993.

[18]. Earnshaw, A. Introduction to Magnetochemistry, Academic Press, London, 1968.

[19]. Boca, R. Struct. Bond. 2006, 117, 1-264.
http://dx.doi.org/10.1007/b136907

[20]. Lever, B. P. Electronic Spectra of the Ions in Inorganic Electronic Spectroscopy, 2nd edition, Elsevier, Amsterdam, Netherlands, 1984.

[21]. Balhausen, C. J. An Introduction to Ligand Field, McGraw Hill, New York, 1962.

[22]. Aurkie, R.; Georgina, M. R.; Ramakant, K.; Samiran, M. Polyhedron 2009, 28, 796-806.
http://dx.doi.org/10.1016/j.poly.2008.12.040

[23]. Salih, I.; Hamdi, T.; Ismail, Y.; Memet, S. Polyhedron 2007, 26, 2795-2802.
http://dx.doi.org/10.1016/j.poly.2007.01.015

[24]. Koca, A.; Dincer, H. A.; Kocak, M. B.; Gul, A. Russ. J. Electrochem. 2006, 42(1), 31-37.
http://dx.doi.org/10.1134/S102319350601006X

[25]. Meryem, N.; Yarasir, M. K.; Atıf, K.; Bekir, S. Polyhedron 2007, 26, 1139-1147.
http://dx.doi.org/10.1016/j.poly.2006.10.002

[26]. Athanassis, C. T.; Paraskevas A. K. Polyhedron 2008, 27, 289-298.
http://dx.doi.org/10.1016/j.poly.2007.09.005

[27]. William, H.; Stephen, V. Theory and Application of Microbiological Assays; Academic Press: San Diego, 1998.

[28]. Pedersen, C. J. Synthetic Multidentate Macrocyclic Compounds, Academic Press, New York, 1978.

[29]. Pedersen, C. J. J. Am. Chem. Soc. 1967, 89, 2495-2496.
http://dx.doi.org/10.1021/ja00986a052

Supporting Agencies

Central Science Library, University Delhi, Delhi, India, Indian Institute of Technology Bombay and Indian Institute of Technology Delhi,
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).