European Journal of Chemistry 2012, 3(1), 71-74 | doi: https://doi.org/10.5155/eurjchem.3.1.71-74.474 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Ion association and solvation behavior of nicotinium dichromate in water-N,N-dimethyl formamide mixtures by a conductometric study


Veerati Radhika (1,*) , Nalamasa Srinivas (2) , Prerepa Manikyamba (3)

(1) Department of Chemistry, Kakatiya University, Warangal-506009, India
(2) Department of Chemistry, Varadha Reddy College of Engineering, Warangal-506371, India
(3) Department of Chemistry, Kakatiya University, Warangal-506009, India
(*) Corresponding Author

Received: 07 Jun 2011 | Revised: 08 Jul 2011 | Accepted: 14 Aug 2011 | Published: 31 Mar 2012 | Issue Date: March 2012

Abstract


The electrical conductance of nicoitinium dichromate has been measured in water-N,N-dimethyl formamide mixtures of different compositions in the temperature range 283-313 K. The limiting molar conductance, Lo and the association constant of the ion-pair, KA have been calculated using Shedlovsky equation. The effective ionic radii (ri) of (C6H6O2)+ and (C6H6O2NCr2O7)- ions have been determined from Lio values using Gill’s modification of the Stokes law. The influence of the mixed solvent composition on the solvation of ions has been discussed with the help of ‘R’-factor. Thermodynamic parameters are evaluated and reported. The results of the study have been interpreted in terms of ion-solvent interactions and solvent properties.

3_1_71_74_800


Keywords


R-factor; Ionic radius; Solvation number; Association constant; Ionic Walden product; Limiting molar conductance

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.3.1.71-74.474

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 671 times | PDF Article downloaded 239 times

Funding information


Kakatiya University, Warangal-506009, India

Citations

/


[1]. Dariusz Wyrzykowski, Anna Kloska, Joanna Pranczk, Aneta Szczepańska, Aleksandra Tesmar, Dagmara Jacewicz, Bogusław Pilarski, Lech Chmurzyński
Physicochemical and Biological Properties of Oxovanadium(IV), Cobalt(II) and Nickel(II) Complexes with Oxydiacetate Anions
Biological Trace Element Research  164(1), 139, 2015
DOI: 10.1007/s12011-014-0170-x
/


[2]. Summyia Masood, Rehana Saeed, Maria Ashfaq
Conductometric, spectrophotometric and thermodynamic studies of nickel sulfate in aqueous polyvinyl alcohol + methanol systems at different temperatures
European Journal of Chemistry  6(1), 37, 2015
DOI: 10.5155/eurjchem.6.1.37-43.1146
/


References

[1]. Rajasekhar, P.; Reddy, K. S. J. Thermochimica Acta 1987, 117, 379-383.
http://dx.doi.org/10.1016/0040-6031(87)88131-5

[2]. Rattan, V. K.; Seema, K.; Tochigi, K. J. Chem. Eng. Data 2000, 40, 207-209.

[3]. Das, D.; Das, B.; Hazra, D. K. Z. Phys. Chem. 2004, 218, 341-348.

[4]. Hefter, G. Pure Appl. Chem. 2005, 77, 605-617.
http://dx.doi.org/10.1351/pac200577030605

[5]. De, R.; Guha, C.; Das, B. J. Solution Chem. 2006, 35(11), 1505-1514.
http://dx.doi.org/10.1007/s10953-006-9078-1

[6]. Ishwara, B. J.; Sreelatha, T. Indian J. Chem. 2006, 45A, 1165-1169.

[7]. Maitra, A.; Bagchi, S. J. Chem. Eng. Data 2008, 137, 131-135.

[8]. Rafif, K. S.; Louis, M.; Donald, Mc. J. Chem. Eng. Data 2008, 53, 335-339.

[9]. Parvatalu, D.; Srivastava, A. K. J. Chem. Eng. Data 2008, 53, 933-937.
http://dx.doi.org/10.1021/je700579b

[10]. Ramesh, S.; Bikash, P.; Deepak, S. J. Chem. Eng. Data 2009, 54, 2902-2906.
http://dx.doi.org/10.1021/je801001h

[11]. Zwolak, M.; Lagerquist, J.; Ventra, M. D. J. Phys. Rev. Lett. 2009, 103, 128102-128105.
http://dx.doi.org/10.1103/PhysRevLett.103.128102
PMCid:2989414

[12]. Nikos, G.; Ioanna, E. M. Phys. Chem. Liq. 2009, 47(5), 505-514.
http://dx.doi.org/10.1080/00319100802307672

[13]. Jabbari, M.; Gharib, F. J. Acta. Chem. Slov. 2010, 57, 325-329.

[14]. Shyamal, K. D.; Anindha, J. B. J. Phys. Chem. 2010, 114B, 6830-6834.

[15]. Bartlett, P. N.; David, C. C.; George, M. W.; Jie, K.; William, L.; Gillian, R.; Wenjian, Z. Phys. Chem. Chem. Phys. 2010, 12, 492-496.

[16]. Palopoli, C. M.; Etcheverry, S. B.; Baran, E. J. Thermochimica Acta 1988, 131, 273-277.
http://dx.doi.org/10.1016/0040-6031(88)80080-7

[17]. Seung, H. A. Arch. Pharm. Res. 1986, 9(4), 229-232.
http://dx.doi.org/10.1007/BF02856637

[18]. Karunakaran, C.; Chidambaranathan, V. Croat. Chem. Acta 2001, 74, 51-54.

[19]. Sadeghi, M. M.; Mohammadpoor-Baltork, I. H.; Memarian, R.; Sobhani, S. Synthetic Commun. 2000, 30(9), 1661-1665.
http://dx.doi.org/10.1080/00397910008087204

[20]. Bhuvaneshwari, D. S.; Elango, K. P. Z. Naturforsch. 2005, 60b, 1105-1108.

[21]. Lopez, C.; Gonzalez, A.; Cossio, F. P.; Palomo, C. Synthetic Commun. 1985, 15(13), 1197-1211.
http://dx.doi.org/10.1080/00397918508077265

[22]. Shedlovsky, T. J. Franklin Inst. 1938, 225(6), 739-743.
http://dx.doi.org/10.1016/S0016-0032(38)90931-7

[23]. Ananthaswamy, J.; Sethuram, B.; Navaneeth, R. T. Indian J. Chem. 1977, 15A, 449-454.

[24]. El-Hammamy, N. H.; Amira, M. F.; Abou El Enien, S. A.; El Halim, F. M. Indian J. Chem. 1984, 23, 43-48.

[25]. Morinaga, K.; Miyaji, K. Denki. Kaigaku. 1982, 50, 736-741.

[26]. Petrella, G.; Castagnolo, M.; Giglio, D. A. J. Solution Chem. 1981, 10(2), 129-138.
http://dx.doi.org/10.1007/BF00644995

[27]. Gill, D. S.; Kumari, N.; Chauhan, M. S. J. Chem. Soc. Faraday Trans. 1 1985, 80, 687-693.
http://dx.doi.org/10.1039/f19858100687

[28]. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions, Butter Worth’s Scientific, London, 1959.

How to cite


Radhika, V.; Srinivas, N.; Manikyamba, P. Eur. J. Chem. 2012, 3(1), 71-74. doi:10.5155/eurjchem.3.1.71-74.474
Radhika, V.; Srinivas, N.; Manikyamba, P. Ion association and solvation behavior of nicotinium dichromate in water-N,N-dimethyl formamide mixtures by a conductometric study. Eur. J. Chem. 2012, 3(1), 71-74. doi:10.5155/eurjchem.3.1.71-74.474
Radhika, V., Srinivas, N., & Manikyamba, P. (2012). Ion association and solvation behavior of nicotinium dichromate in water-N,N-dimethyl formamide mixtures by a conductometric study. European Journal of Chemistry, 3(1), 71-74. doi:10.5155/eurjchem.3.1.71-74.474
Radhika, Veerati, Nalamasa Srinivas, & Prerepa Manikyamba. "Ion association and solvation behavior of nicotinium dichromate in water-N,N-dimethyl formamide mixtures by a conductometric study." European Journal of Chemistry [Online], 3.1 (2012): 71-74. Web. 15 Aug. 2020
Radhika, Veerati, Srinivas, Nalamasa, AND Manikyamba, Prerepa. "Ion association and solvation behavior of nicotinium dichromate in water-N,N-dimethyl formamide mixtures by a conductometric study" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.3.1.71-74.474

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2012, 3(1), 71-74 | doi: https://doi.org/10.5155/eurjchem.3.1.71-74.474 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort