European Journal of Chemistry 2012, 3(1), 32-36 | doi: https://doi.org/10.5155/eurjchem.3.1.32-36.525 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Composition and properties of tectosilicate-uranium layers of soil


Cecilio Duarte Alaniz (1) , Eduardo Ordonez Regil (2,*) , Guillermo Jesus Cruz Cruz (3) , Jesus Ramirez Torres (4) , Jose Lopez Monroy (5)

(1) Facultad de Ciencias, Universidad Autónoma del Estado de México, Unidad Académica del Cerrillo, Piedras Blancas El Cerrillo, Tlachaloya Estado de México, CP 50000, México
(2) Departamento de Química, Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca S/N, La Marquesa, Ocoyoacac, Estado de México, CP 52750, México
(3) Departamento de Física, Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca S/N, La Marquesa, Ocoyoacac, Estado de México, CP 52750, México
(4) Acelerador Tandem, Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca S/N, La Marquesa, Ocoyoacac, Estado de México, CP 52750, México
(5) Acelerador Tandem, Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca S/N, La Marquesa, Ocoyoacac, Estado de México, CP 52750, México
(*) Corresponding Author

Received: 07 Sep 2011 | Revised: 09 Oct 2011 | Accepted: 13 Oct 2011 | Published: 31 Mar 2012 | Issue Date: March 2012

Abstract


Structure and superficial properties of tectosilicates found in soils with potential to retain uranium are studied in this work. These tectosilicates are largely available as natural minerals in the soil and are composed mainly by anorthite (CaAl2Si2O8), albite (NaAlSi3O8) and orthoclase (KAlSi3O8), in which albite has approximately 3 times the content of orthoclase and 2.5 times the content of anorthite. However, anorthite has a double cell structure, which could result in approximately the same sorption effect as albite. The acidity constants calculated with the surface complexation model suggested that the three components have similar amphoteric behavior in presence of high ionic strength ground salt solutions. The composite mineral has a specific surface area of 20.5 m2g-1 with site density of 2.8 sites nm-2. These characteristics make this mineral a good candidate for uranium capture.

3_1_32_36_800


Keywords


Albite; Anorthite; Orthoclase; Surface area; Acidity constants; Potentiometric titrations

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.3.1.32-36.525

Links for Article


| | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 659 times | PDF Article downloaded 235 times


Citations

/


[1]. Christopher T. Elliott, Lisa Connolly, Oluwatobi Kolawole
Potential adverse effects on animal health and performance caused by the addition of mineral adsorbents to feeds to reduce mycotoxin exposure
Mycotoxin Research  36(1), 115, 2020
DOI: 10.1007/s12550-019-00375-7
/


[2]. Oľga Rosskopfová’s, Lucia Pivarčiová’s, Adrián Krajňák’s, Michal Galamboš’s, Pavol Rajec’s
Adsorption of nickel on illite/smectite Dolná Ves
Journal of Radioanalytical and Nuclear Chemistry  307(1), 179, 2016
DOI: 10.1007/s10967-015-4110-9
/


[3]. Agnieszka Gładysz-Płaska, Ewelina Grabias, Marek Majdan
Simultaneous adsorption of uranium(VI) and phosphate on red clay
Progress in Nuclear Energy  104, 150, 2018
DOI: 10.1016/j.pnucene.2017.09.010
/


[4]. A. Krajňák, L. Pivarčiová, O. Rosskopfová, M. Galamboš, P. Rajec
Adsorption of nickel on rhyolitic Slovak bentonites
Journal of Radioanalytical and Nuclear Chemistry  304(2), 587, 2015
DOI: 10.1007/s10967-014-3832-4
/


[5]. Kolawole, Meneely, Greer, Chevallier, Jones, Connolly, Elliott
Comparative In Vitro Assessment of a Range of Commercial Feed Additives with Multiple Mycotoxin Binding Claims
Toxins  11(11), 659, 2019
DOI: 10.3390/toxins11110659
/


References

[1]. Kratz, S.; Schnug E.; Markel B. J.; Hasche-Berger A. (Eds.), Rock phosphates and P fertilizers as sources of U contamination in agricultural soils, Springer, Berlin, Heidelberg, 2006, pp. 57-68.

[2]. Guzman, R. E. T.; Regil, O. E.; Alberich, E. M. V.; Hernandez, R. A.; Gutierrez, R. L. R.; Regil, O. E. Water, Air, Soil Pollut. 2006, 175, 77-98.
http://dx.doi.org/10.1007/s11270-006-9114-1

[3]. Guzman, R. E. T.; Alberich, E. M. V.; Regil, O. E. J. Radioanal. Nucl. Chem. 2002, 254(3), 509-517.
http://dx.doi.org/10.1023/A:1021690005227

[4]. DeMasily, G. Radiochim. Acta 1998, 44-45, 159-164.

[5]. Grenthe, I. Radiochim. Acta 1991, 52-53, 425-432.

[6]. Jaquier, P. Radiochim. Acta 1991, 52-53, 495-500.

[7]. Dozol, M.; Hagemann, R. Pure App. Chem. 1993, 65(5), 1081-1102.
http://dx.doi.org/10.1351/pac199365051081

[8]. Guillaumont, R. Radiochim. Acta 1994, 66-67, 231-237.

[9]. Day, D. H.; Hughes, A. E.; Leake, J. W.; Marples, J. A.; Marsh, G. P.; Rae, J.; Wade, B. O. Rep. Prog. Phys. 1985, 48, 1091-1154.
http://dx.doi.org/10.1088/0034-4885/48/1/003

[10]. Hueckel, T.; Peano, A. Comput. Geotech. 1987, 3(2-3), 157-182.
http://dx.doi.org/10.1016/0266-352X(87)90019-X

[11]. Abdelouahed, H. B.; Reguigui, N. J. Radioanal. Nucl. Chem. 2011, 289, 103-111.
http://dx.doi.org/10.1007/s10967-011-1035-9

[12]. Guzman, R. E. T.; Rios, S. M.; Garcia, I. J. L.; Regil, O. E. J. Radioanal. Nucl. Chem. 1995, 189(2), 301-305.
http://dx.doi.org/10.1007/BF02042609

[13]. Souka, N.; Shabana, R.; Farah, K. J. Radional. Nucl. Chem. 1976, 33, 15-23.

[14]. Yinjie, S.; Hui, Z.; Qiaoling, Y.; Aimin, Z. J. Radioanal. Nucl. Chem. Art. 1995, 198(2), 375-387.
http://dx.doi.org/10.1007/BF02036553

[15]. Lomenech, C.; Drot, R.; Simoni, E. Radiochim. Acta 2003, 91, 453-461.
http://dx.doi.org/10.1524/ract.91.8.453.20004

[16]. Regil, O. E.; Drot, R.; Simoni, E. J. Colloid. Interface Sci. 2003, 263, 391-398.

[17]. Galambos, M.; Rosskopfova, O.; Kufcakova, J.; Rajec, P. L. J. Radioanal. Nucl. Chem. 2011, 288, 765-777.
http://dx.doi.org/10.1007/s10967-011-0987-0

[18]. Garcia, G.; Ordoñez, E.; Drot, R.; Perez, M. Inf. Tecnol. 2004, 15(4), 31-38.
http://dx.doi.org/10.4067/S0718-07642004000400006

[19]. Zhang, Y.; Zhao, H.; Fan, Q.; Zheng, X.; Li, P.; Liu, S.; Wu, W. J. Radioanal. Nucl. Chem. 2011, 288, 395-404.
http://dx.doi.org/10.1007/s10967-010-0948-z

[20]. Drot, R.; Lindecker, C.; Fourest, B.; Simoni, E.; New J. Chem. 1998, 1, 1105-1109.
http://dx.doi.org/10.1039/a803215g

[21]. Hayes, K. F.; Redden, G.; Ela, W.; Leckie, J. O. J. Colloid. Interface Sci. 1991, 142(2), 448-469.
http://dx.doi.org/10.1016/0021-9797(91)90075-J

[22]. Noh, J.; Schwarz, J. J. J. Colloid. Interface. Sci. 1989, 130, 157-164.
http://dx.doi.org/10.1016/0021-9797(89)90086-6

[23]. Herbelin, A.; Westall, J., FITEQL4 V 4.0 program; Report 96-01. Department of Chemistry, Oregon State University, Corvallis, 1996.

[24]. Preocanin, T.; Kallay, N. Croat. Chem. Acta 1998, 71(4), 1117-1125.

[25]. Available at: http://adsorption.org/awm/ads/EnCorr.htm by Marczewski, A. W. Last update on: 01/04/2012.

[26]. Cerius Database, Biosym/Molecular Simulations. USA, 1995.

[27]. Hodgson, M. E. J. Geochem. Explor. 2006, 88, 288-303.
http://dx.doi.org/10.1016/j.gexplo.2005.08.058

[28]. Armbruster, T.; Bürgi, H. B.; Kunz, M.; Gnos, E.; Bröniman, S.; Lienert, C. Am. Mineral. 1990, 75, 135-140.

[29]. Harlow, G.; Brown, G. E. Jr. Am. Mineral. 1980, 65, 986-995.

[30]. Murakami, T.; Kogure, T.; Kadohara, H.; Ohniki, T. Am. Mineral. 1998, 83, 1209-1219.

[31]. Simoni, E., Encyclopedia of surface and colloid science, Marcel Dekker Inc. 2002.

[32]. Appelo, C. A. J.; Postma, D. Geochim. Cosmochim. Acta 1999, 63(19-20), 3039-3048.
http://dx.doi.org/10.1016/S0016-7037(99)00231-8

How to cite


Alaniz, C.; Regil, E.; Cruz, G.; Torres, J.; Monroy, J. Eur. J. Chem. 2012, 3(1), 32-36. doi:10.5155/eurjchem.3.1.32-36.525
Alaniz, C.; Regil, E.; Cruz, G.; Torres, J.; Monroy, J. Composition and properties of tectosilicate-uranium layers of soil. Eur. J. Chem. 2012, 3(1), 32-36. doi:10.5155/eurjchem.3.1.32-36.525
Alaniz, C., Regil, E., Cruz, G., Torres, J., & Monroy, J. (2012). Composition and properties of tectosilicate-uranium layers of soil. European Journal of Chemistry, 3(1), 32-36. doi:10.5155/eurjchem.3.1.32-36.525
Alaniz, Cecilio, Eduardo Ordonez Regil, Guillermo Jesus Cruz Cruz, Jesus Ramirez Torres, & Jose Lopez Monroy. "Composition and properties of tectosilicate-uranium layers of soil." European Journal of Chemistry [Online], 3.1 (2012): 32-36. Web. 24 Feb. 2020
Alaniz, Cecilio, Regil, Eduardo, Cruz, Guillermo, Torres, Jesus, AND Monroy, Jose. "Composition and properties of tectosilicate-uranium layers of soil" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

DOI Link: https://doi.org/10.5155/eurjchem.3.1.32-36.525

| | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2012, 3(1), 32-36 | doi: https://doi.org/10.5155/eurjchem.3.1.32-36.525 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2019  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2019 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 4614 Lavista road, Tucker, GA, 30084, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort