European Journal of Chemistry 2012, 3(1), 17-20 | doi: https://doi.org/10.5155/eurjchem.3.1.17-20.534 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine


Huang Yuanyuan (1) , Bai Fang (2) , Gao Guowei (3) , Men Jian (4,*)

(1) College of Chemistry, Sichuan University, Chengdu, 610064, China
(2) College of Chemistry, Sichuan University, Chengdu, 610064, China
(3) College of Chemistry, Sichuan University, Chengdu, 610064, China
(4) College of Chemistry, Sichuan University, Chengdu, 610064, China
(*) Corresponding Author

Received: 28 Sep 2011 | Accepted: 12 Oct 2011 | Published: 31 Mar 2012 | Issue Date: March 2012

Abstract


The novel compound, 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine has been synthesized starting from 2,4,6-trichloro-1,3,5-triazine and characterized by 1H NMR, 13C NMR, IR, mass spectroscopy and elemental analysis. The single crystal of the title compound was obtained and subjected to X-ray diffraction analysis. The single crystal data illustrates that it belongs to the monoclinic system, space group C2/c with a = 13.818(3) Å, b = 7.8964(16) Å, c = 30.718(6) Å, β = 96.52(3) o, V = 3330.0(12) Å3, Z = 8, Dc = 1.537 g/cm3, C16H11N5O7, Mr = 385.30, µ (MoKα) = 0.124 mm−1, F(000) = 1584, the final R = 0.0489 and wR = 0.1821 for 2491 observed reflections with I>2σ(I).

3_1_17_20_800


Keywords


Synthesis; Bis-maleimides; π-π Interactions; Crystal structure; 2,4,6-Trichloro-1,3,5-triazine; 2-Methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.3.1.17-20.534

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 646 times | PDF Article downloaded 253 times


Citations

/


[1]. Adel Sayed Orabi, Sahar Said El-Sakka
Correlation between single crystal data and molecular mechanics calculation of 3-(2-hydroxy-phenylimino)-1,3-diphenyl-propan-1-one
European Journal of Chemistry  10(2), 139, 2019
DOI: 10.5155/eurjchem.10.2.139-145.1838
/


References

[1]. Chandra, R.; Rajabi, L. J. Macromol. Sci. Rev. Macromol. Chem. Phys. 1997, 37, 61-96.
http://dx.doi.org/10.1080/15321799708014733

[2]. Lee, H. N.; Rield, F. R. Mater. Soc. 1989, 13, 301-318.

[3]. Owusu, A. O.; Martin, G. C.; Gotro, J. T. Polym. Eng. Sci. 1991, 31, 1604-1609.
http://dx.doi.org/10.1002/pen.760312208

[4]. Takao, I.; Hidehiko, S. J. Appl. Polym. Sci. 1997, 65, 1349-1357.
http://dx.doi.org/10.1002/(SICI)1097-4628(19970815)65:7<1349::AID-APP12>3.0.CO;2-Q

[5]. Liu, Y. L.; Chen, Y. J.; Wei, W. L. Polym. 2003, 44, 6465-6473.
http://dx.doi.org/10.1016/j.polymer.2003.08.006

[6]. Watanabe, M.; Yoshie, N. Polym. 2006, 47, 4946-4952.
http://dx.doi.org/10.1016/j.polymer.2006.05.036

[7]. Lin, R. H.; Liu, Y. H.; Chen, Y. H.; Lee, A. C.; Ho, T. H. Eur. Polym. J. 2007, 43, 4197-4209.
http://dx.doi.org/10.1016/j.eurpolymj.2007.08.004

[8]. Lin, R. H.; Lu, W. H.; Lin, C. W. Polym. 2004, 45, 4423-4435.
http://dx.doi.org/10.1016/j.polymer.2004.04.050

[9]. Hwang, H. L.; Li, C. H.; Wang, C. S. Polym. 2006, 47, 1291-1299.
http://dx.doi.org/10.1016/j.polymer.2005.12.040

[10]. Liu, Y. L.; Chen, Y. J. Polym. 2004, 45, 1797-1804.
http://dx.doi.org/10.1016/j.polymer.2004.01.001

[11]. Fang, Q.; Li, G. Z.; Zeng, X.; Jiang, L. X. J. Appl. Polym. 2004, 93, 475-480.
http://dx.doi.org/10.1002/app.20467

[12]. Fang, Q.; Ding, X. M.; Wu, X. Y.; Jiang, L. X. Polym. 2001, 47, 7595-7602.
http://dx.doi.org/10.1016/S0032-3861(01)00274-9

[13]. Hao, J.; Jiang, L.; Cai, X. Polym. 1996, 16, 3721-3727.
http://dx.doi.org/10.1016/0032-3861(96)00186-3

[14]. Lin, J.; Yuki, Y.; Kunisada, H.; Kondo, S. J. Appl. Polym. 1990, 40, 2113-2122.
http://dx.doi.org/10.1002/app.1990.070401124

[15]. Saida, K.; Sakai, M.; Narahara, T. Japan Patent (Jpn Kokai Tokkyo Koho) 52 136 298 and 52 136 189, 1977.

[16]. Sheldrick G. M., SHELXS97. Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.

[17]. Jetti. R. K. R.; Thallapally, P. K.; Nangia, A. Chem. Comm. 2002, 952-953.

[18]. Ohkita, M.; Kawano, M.; Suzuki, T.; Tsuji, T. Chem. Comm. 2002, 3054-3055.

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Yuanyuan, H.; Fang, B.; Guowei, G.; Jian, M. Eur. J. Chem. 2012, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534
Yuanyuan, H.; Fang, B.; Guowei, G.; Jian, M. Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine. Eur. J. Chem. 2012, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534
Yuanyuan, H., Fang, B., Guowei, G., & Jian, M. (2012). Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine. European Journal of Chemistry, 3(1), 17-20. doi:10.5155/eurjchem.3.1.17-20.534
Yuanyuan, Huang, Bai Fang, Gao Guowei, & Men Jian. "Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine." European Journal of Chemistry [Online], 3.1 (2012): 17-20. Web. 27 May. 2020
Yuanyuan, Huang, Fang, Bai, Guowei, Gao, AND Jian, Men. "Synthesis and crystal structure of 2-methoxy-4,6-bis(4-nitrophenoxy)-1,3,5-triazine" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.3.1.17-20.534

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2012, 3(1), 17-20 | doi: https://doi.org/10.5155/eurjchem.3.1.17-20.534 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort