European Journal of Chemistry

Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition



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Davood Azarifar
Kaveh Khosravi

Abstract

Application of trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as an efficient and high-oxygen content reagent in selective oxidation of sulfides into sulfoxides has been successfully explored. The reactions proceeded under mild and catalyst-free conditions in dichloromethane at room temperature to provide the sulfoxides in excellent yields without any significant over-oxidation to sulfones.

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Azarifar, D.; Khosravi, K. Trans-3,5-Dihydroperoxy-3,5-Dimethyl-1,2-Dioxolane As a Novel and Efficient Reagent for Selective Sulfoxidation of Sulfides under Catalyst-Free Condition. Eur. J. Chem. 2010, 1, 15-19.

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Research Council of Bu-Ali Sina University
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