European Journal of Chemistry

Synthesis and microstructure studies of nano-sized cerium phosphates



Main Article Content

Adly Abdella Hanna
Sahar Mohamed Mousa
Gehan Mahmoud Elkomy
Marwa Adel Sherief

Abstract

Cerium phosphate, CePO4, nanoparticles with hexagonal or monoclinic phase was synthesized by the reaction between Ce(SO4)2.4H2O and two different phosphate sources, H3PO4 and Na2HPO4. The obtained gel was dried and calcined at different temperatures (200, 400, and 800 оC). The effects of the precursor materials and the calcination temperatures on the produced phases were studied. Both X-ray diffraction (XRD) and infrared spectroscopy (IR) were used to follow the changes in the phase structure for the produced samples. The thermal behaviour of the as prepared samples was studied by using differential scanning calorimetric (DSC) and thermogravimetric analysis (TGA). The morphology, crystallinity and particle size of the produced samples as prepared and calcinated were characterized by transmission electron microscope (TEM). The analysis of TEM results indicated that CePO4 was prepared in nano-sized particles.

1_3_211_215_800


icon graph This Abstract was viewed 2402 times | icon graph Article PDF downloaded 901 times

How to Cite
(1)
Hanna, A. A.; Mousa, S. M.; Elkomy, G. M.; Sherief, M. A. Synthesis and Microstructure Studies of Nano-Sized Cerium Phosphates. Eur. J. Chem. 2010, 1, 211-215.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Clearfield, A.; Stynes J. A. J. Inorg. Nucl. Chem. 1964, 26, 117 -129.
doi:10.1016/0022-1902(64)80238-4

[2]. Alberti, G.; Torracca, E. J. Inorg. Nucl. Chem. 1968, 30, 317 -318.
doi:10.1016/0022-1902(68)80096-X

[3]. Hanna, A. A.; Ali, A. F.; Gad, A. E. Phos. Res. Bull. 2009, 23, 83 -89.
doi:10.3363/prb.23.83

[4]. Khalil, M. Sh.; Hanna, A. A.; El-Sayed, M. A. Phos. Res. Bull 2002, 14, 77-88.

[5]. Hanna, A. A.; Mousa, S. M.; Ali A. F.; Sherief, M. A. Phos. Res. Bull. 2007, 21, 78-83.
doi:10.3363/prb.21.78

[6]. Hikichi, Y., Nomura, T., Timura, Y.; Suzuki, S. J. Am. Ceram. Soc. 1990, 73(12), 3594-3596.
doi:10.1111/j.1151-2916.1990.tb04263.x

[7]. Rappaz, M.; Abraham, M. M.; Ramey, J. O.; Boatner, L. A. Phys. Rev. B 1981, 23(3), 1012-1030.
doi:10.1103/PhysRevB.23.1012

[8]. Xu, L.; Guo, G.; Uy, D.; Neill, A. E.O; Weber, W. H.; Rokosz, M. J.; McCabe, R. W. Appl. Catal. B-Environ. 2004, 50, 113-125.
doi:10.1016/j.apcatb.2004.01.017

[9]. Gee, B.; Horne, C. R.; Cairns, E. J.; Reimer, J. A. J. Phys. Chem. B. 1998, 102(50), 10142-10149.
doi:10.1021/jp982301p

[10]. Adler, S. B.; Reimer, J. A. Solid State Ion. 1996, 91, 175-181.
doi:10.1016/S0167-2738(96)00440-7

[11]. Duncan, M.; Chemical Shift Tensors, 2nd edition, Farragut Press, Madison, WI, 1997.

[12]. Lopez Granados, M.; Cabello Galisteo, F.; Lambrou, P. S.; Mariscal, R.; Sanz, J.; Sobrados, I.; Fierro, J. L. G.; Efstathiou, A. M. J. Catal. 2006, 239, 410–421.
doi:10.1016/j.jcat.2006.02.007

[13]. Kitamura, N.; Amezawa, K.; Tomii, Y.; Hanada, T.; Yamamoto, N.; Omata, T.; Otsuka-Yao-Matsuo, Y. J. Electrochem. Soc. 2005, 152(4), A658-A663.
doi:10.1149/1.1861993

[14]. Mehta, V.; Aka, G.; Dawar, A. L.; Mansingh, A. Opt. Mater. 1999, 12, 53-63.
doi:10.1016/S0925-3467(98)00074-3

[15]. Imanaka, N.; Masui, T.; Hirai, H.; Adachi, G. Chem. Mater. 2003, 15, 2289-2291.
doi:10.1021/cm034200w

[16]. Onada, H.; Nariai, H.; Moriwaki, A.; Maki, H.; Motooka, I. J. Mater. Chem. 2002, 12, 1754-1760.
doi:10.1039/b110121h

[17]. Feldmann, C.; Jungk, H. O. J. Mater. Sci. 2002, 37, 3251-3254.
doi:10.1023/A:1016131016637

[18]. Sato, T.; Sato, C.; Yin, S. Phos. Res. Bull. 2008, 22, 17-21.
doi:10.3363/prb.22.17

[19]. Matraszek, A.; Szczygiel, I.; Macalik, L.; Hanuza, J. J. Rare Earths 2009, 27(4), 598-602.
doi:10.1016/S1002-0721(08)60296-3

[20]. Penot, C.; Champion, E.; Goursat, P. Phos. Res. Bull. 1999, 10, 307-312.

[21]. Masui, T.; Hirai, H.; Imanaka, N.; Adachi, G. J. Alloy and Comp. 2006, 408-412, 1141-1144.
doi:10.1016/j.jallcom.2004.12.136

[22]. Masui, T.; Hirai, H.; Imanaka, N.; Adachi, G. Phys. Status A 2003, 198(2), 364-368.
doi:10.1002/pssa.200306623

[23]. Lucas, S.; Champion, E.; Bernache-Assollant, D.; Leroy, G. J. J. Solid State Chem. 2004, 177, 1312-1320.
doi:10.1016/j.jssc.2003.11.004

[24]. Lucas, S.; Champion, E.; Bregiroux, D.; Bernache-Assollant, D.; Audubert, F. J. Solid State Chem. 2004, 177, 1302-1311.
doi:10.1016/j.jssc.2003.11.003

[25]. Pradyot Patnaik. Handbook of Inorganic Chemicals, McGraw-Hill, 2002.

[26]. Bo, L.; Liya, S.; Xiaozhen, L.; Shuiche, Z.; Yumeri, Z.; Tianmain, W.; Sasaki, Y.; Ishii, K.; Kashiwaya, Y.; Takahashi H.; Shibayama, T. J. Mater. Sci. Lett. 2001, 20, 1071-1075.
doi:10.1023/A:1010985130019

[27]. Khawaja, M. A.; Khahak, I. G. J. Sci. Ind. Res. 1994, 37, 365-371.

[28]. Hazel, A.; Ross, S. D. Spectrochim. Acta 1966, 22, 1949-1961.

[29]. Aramendia, M. A.; Borau, V.; Jimenez, C.; Marinas, J. M.; Romero, F. J. J. Colloid Interface Sci. 1999, 217, 288-298.

[30]. Hirai, H.; Masui, T.; Imanaka, N.; Adachi, G. J. Alloy and Comp. 2004, 374, 84-88.
doi:10.1016/j.jallcom.2003.11.069

[31]. Guo, Y.; Woznicki, P.; Barkatt, A. J. Mater. Res. 1996, 11(3), 639-648.
doi:10.1557/JMR.1996.0077

[32]. Nazaraly, M.; Chaneac, C.; Ribot, F.; Wallez, G.; Quarton, M.; Jolivet, J. J. Phys. Chem. Solids 2007, 68(5-6), 795-798.
doi:10.1016/j.jpcs.2007.03.010

[33]. Von, I. L.; Botto, E. J.; Baran, Z. Anorg. Allg. Chem. 1977, 430, 283-288.

[34]. Caswell, K. K.; Christopher, M. B.; Murphy, J. C. Nano Lett. 2003, 3(5), 667-669.
doi:10.1021/nl0341178

[35]. Jia, C. J.; Sun, L. D.; Yan, Z. G.; You, L. P.; Luo, F.; Han. X. D.; Pang, Y. C.; Zhang, Z.; Yan. C. H. Angew. Chem. Int. Ed. 2005, 44, 4328-4333.

[36]. Bao, J.; Zang, R.; Yu. J.; Yang, X.; Wang, D.; Deng, J.; Chen, J.; Xing, X. Cryst. Eng. Comm. 2009, 11, 1630-1634.
doi:10.1039/b901313j

Most read articles by the same author(s)

Most read articles by the same author(s)

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).