European Journal of Chemistry 2013, 4(2), 124-131 | doi: https://doi.org/10.5155/eurjchem.4.2.124-131.741 | Get rights and content

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The use of calixarene as ionophores in potentiometric ion-selective electrodes of naftidrofuryl oxalate using microsized membrane sensors for kinetic study of naftidrofuryl (NFT) degradation


Mohammad Abdalla El-Sayed (1,*)

(1) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Umm Al-Qura University, Makkah, P.O.Box 715, Saudi Arabia
(*) Corresponding Author

Received: 07 Feb 2013 | Revised: 14 Mar 2013 | Accepted: 06 Apr 2013 | Published: 30 Jun 2013 | Issue Date: June 2013

Abstract


Novel miniaturized polyvinyl chloride membrane sensors in all-solid state graphite and platinum wire supports were developed, electrochemically evaluated and used for the assay of naftidrofuryl oxalate. The naftidrofuryl oxalate sensors were based on the formation of an ion-association complex between the drug cation and tetrakis-(4-chlorophenyl)borateanionic exchanger as electroactive material and sulfocalix-8-arene as ionophore dispersed in a polyvinyl chloride matrix. Linear responses of 10-2-10-6 M and 10-2-10-5 M with cationic slopes of 56.9 mV and 54.1 mV over the pH range 2-5 were obtained by using the naftidrofuryl oxalate-coated graphite (Sensor 1) and platinum wire (Sensor 2) membrane sensors, respectively. The utility of 4-sulfocalix-8-arene as ionophore had a significant influence on increasing the membrane sensitivity and selectivity. The methods were also used to determine the intact drug in the presence of it’s degradate in Praxilene® tablets, plasma and cerebrospinal fluid with good recovery. Sensor 1 was used to study the kinetics of naftidrofuryl oxalate alkaline degradation that was found to follow a pseudo first-order reaction. The activation energy could be estimated from the Arrhenius plot to be 12.572 Kcal/mol.

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Keywords


Potentiometry; Cerebrospinal fluid; 4-Sulfocalix-8-arene; Naftidrofuryl oxalate; Stabilityindicating method; Tetrakis-(4-chlorophenyl)borate

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DOI: 10.5155/eurjchem.4.2.124-131.741

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Funding information


Faculty of Pharmacy, Cairo University, ET 11562, Cairo, Egypt

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How to cite


El-Sayed, M. Eur. J. Chem. 2013, 4(2), 124-131. doi:10.5155/eurjchem.4.2.124-131.741
El-Sayed, M. The use of calixarene as ionophores in potentiometric ion-selective electrodes of naftidrofuryl oxalate using microsized membrane sensors for kinetic study of naftidrofuryl (NFT) degradation. Eur. J. Chem. 2013, 4(2), 124-131. doi:10.5155/eurjchem.4.2.124-131.741
El-Sayed, M. (2013). The use of calixarene as ionophores in potentiometric ion-selective electrodes of naftidrofuryl oxalate using microsized membrane sensors for kinetic study of naftidrofuryl (NFT) degradation. European Journal of Chemistry, 4(2), 124-131. doi:10.5155/eurjchem.4.2.124-131.741
El-Sayed, Mohammad. "The use of calixarene as ionophores in potentiometric ion-selective electrodes of naftidrofuryl oxalate using microsized membrane sensors for kinetic study of naftidrofuryl (NFT) degradation." European Journal of Chemistry [Online], 4.2 (2013): 124-131. Web. 9 Mar. 2021
El-Sayed, Mohammad. "The use of calixarene as ionophores in potentiometric ion-selective electrodes of naftidrofuryl oxalate using microsized membrane sensors for kinetic study of naftidrofuryl (NFT) degradation" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

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