

The use of calixarene as ionophores in potentiometric ion-selective electrodes of naftidrofuryl oxalate using microsized membrane sensors for kinetic study of naftidrofuryl (NFT) degradation
Mohammad Abdalla El-Sayed (1,*)

(1) Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Umm Al-Qura University, Makkah, P.O.Box 715, Saudi Arabia
(*) Corresponding Author
Received: 07 Feb 2013 | Revised: 14 Mar 2013 | Accepted: 06 Apr 2013 | Published: 30 Jun 2013 | Issue Date: June 2013
Abstract
Novel miniaturized polyvinyl chloride membrane sensors in all-solid state graphite and platinum wire supports were developed, electrochemically evaluated and used for the assay of naftidrofuryl oxalate. The naftidrofuryl oxalate sensors were based on the formation of an ion-association complex between the drug cation and tetrakis-(4-chlorophenyl)borateanionic exchanger as electroactive material and sulfocalix-8-arene as ionophore dispersed in a polyvinyl chloride matrix. Linear responses of 10-2-10-6 M and 10-2-10-5 M with cationic slopes of 56.9 mV and 54.1 mV over the pH range 2-5 were obtained by using the naftidrofuryl oxalate-coated graphite (Sensor 1) and platinum wire (Sensor 2) membrane sensors, respectively. The utility of 4-sulfocalix-8-arene as ionophore had a significant influence on increasing the membrane sensitivity and selectivity. The methods were also used to determine the intact drug in the presence of it’s degradate in Praxilene® tablets, plasma and cerebrospinal fluid with good recovery. Sensor 1 was used to study the kinetics of naftidrofuryl oxalate alkaline degradation that was found to follow a pseudo first-order reaction. The activation energy could be estimated from the Arrhenius plot to be 12.572 Kcal/mol.

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European Journal of Chemistry
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DOI: 10.5155/eurjchem.4.2.124-131.741
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Funding information
Faculty of Pharmacy, Cairo University, ET 11562, Cairo, Egypt
Citations
[1]. Mehmet Soner ENGİN, Serkan SAYIN, Seydahmet ÇAY
Yeni Kaliks[4]aren-içeren Polimerik Membranların Hazırlanması, Karakterizasyonu ve Uygulamaları
Karadeniz Fen Bilimleri Dergisi 11(2), 533, 2021
DOI: 10.31466/kfbd.943146

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