European Journal of Chemistry 2013, 4(2), 149-152 | doi: https://doi.org/10.5155/eurjchem.4.2.149-152.750 | Get rights and content

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Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds


Muhammad Moazzam Naseer (1,*) , Habiba Nazir (2) , Shahid Hameed (3)

(1) Department of Chemistry, Quaid-i-Azam University, Islamabad-45320, Pakistan
(2) Department of Biochemistry, Pir Mehr Ali Shah Arid Agriculture University, Rawalpindi, Pakistan
(3) Department of Chemistry, Quaid-i-Azam University, Islamabad-45320, Pakistan
(*) Corresponding Author

Received: 15 Feb 2013 | Revised: 02 Mar 2013 | Accepted: 13 Mar 2013 | Published: 30 Jun 2013 | Issue Date: June 2013

Abstract


The synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds are being reported. The reaction of 2,4,6-tris(4-n-butylaminophenyl)triazine (1) with cyanuric chloride provided star-shaped fragment (2) with six reactive chloro-substituents. Upon treatment of this fragment with bis(2-hydroxyethyl)amine (3a) and bis(2-pyridylmethyl)amine (3b), functionalized polyhydroxylated (4a) and multi-N-donor compounds (4b) were obtained in high yields through nucleophilic aromatic substitution. These functionalized compounds are expected to have unique applications in supramolecular self-assembly and material chemistry.

4_2_149_152

Keywords


Synthons; Synthesis; Triazine-core; Multi-N-donor; Supramolecular; Polyhydroxylated

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DOI: 10.5155/eurjchem.4.2.149-152.750

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Funding information


The higher education commission (HEC), (PM-IPFP/HRD/HEC/2011/3407), Govt. of Pakistan, Pakistan

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How to cite


Naseer, M.; Nazir, H.; Hameed, S. Eur. J. Chem. 2013, 4(2), 149-152. doi:10.5155/eurjchem.4.2.149-152.750
Naseer, M.; Nazir, H.; Hameed, S. Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds. Eur. J. Chem. 2013, 4(2), 149-152. doi:10.5155/eurjchem.4.2.149-152.750
Naseer, M., Nazir, H., & Hameed, S. (2013). Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds. European Journal of Chemistry, 4(2), 149-152. doi:10.5155/eurjchem.4.2.149-152.750
Naseer, Muhammad, Habiba Nazir, & Shahid Hameed. "Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds." European Journal of Chemistry [Online], 4.2 (2013): 149-152. Web. 24 Jan. 2021
Naseer, Muhammad, Nazir, Habiba, AND Hameed, Shahid. "Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

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