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Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds
Muhammad Moazzam Naseer (1,*)
, Habiba Nazir (2) , Shahid Hameed (3) (1) Department of Chemistry, Quaid-i-Azam University, Islamabad-45320, Pakistan
(2) Department of Biochemistry, Pir Mehr Ali Shah Arid Agriculture University, Rawalpindi, Pakistan
(3) Department of Chemistry, Quaid-i-Azam University, Islamabad-45320, Pakistan
(*) Corresponding Author
Received: 15 Feb 2013 | Revised: 02 Mar 2013 | Accepted: 13 Mar 2013 | Published: 30 Jun 2013 | Issue Date: June 2013
Abstract
The synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds are being reported. The reaction of 2,4,6-tris(4-n-butylaminophenyl)triazine (1) with cyanuric chloride provided star-shaped fragment (2) with six reactive chloro-substituents. Upon treatment of this fragment with bis(2-hydroxyethyl)amine (3a) and bis(2-pyridylmethyl)amine (3b), functionalized polyhydroxylated (4a) and multi-N-donor compounds (4b) were obtained in high yields through nucleophilic aromatic substitution. These functionalized compounds are expected to have unique applications in supramolecular self-assembly and material chemistry.
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DOI: 10.5155/eurjchem.4.2.149-152.750
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Funding information
The higher education commission (HEC), (PM-IPFP/HRD/HEC/2011/3407), Govt. of Pakistan, Pakistan
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DOI Link: https://doi.org/10.5155/eurjchem.4.2.149-152.750
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European Journal of Chemistry 2013, 4(2), 149-152 | doi: https://doi.org/10.5155/eurjchem.4.2.149-152.750 | Get rights and content
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