European Journal of Chemistry

Synthons for supramolecular assemblies: Synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds

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Published: Jun 30, 2013
DOI: https://doi.org/10.5155/eurjchem.4.2.149-152.750
Keywords:
Synthons, Synthesis, Triazine-core, Multi-N-donor, Supramolecular, Polyhydroxylated
Section
Research Article
Issue
Vol. 4 No. 2 (2013): June 2013
Dates
Received 2013-02-15
Accepted 2013-03-13
Published 2013-06-30


Main Article Content

Muhammad Moazzam Naseer
Department of Chemistry, Quaid-i-Azam University, Islamabad-45320, Pakistan
Habiba Nazir
Department of Biochemistry, Pir Mehr Ali Shah Arid Agriculture University, Rawalpindi, Pakistan
Shahid Hameed
Department of Chemistry, Quaid-i-Azam University, Islamabad-45320, Pakistan

Abstract

The synthesis of new triazine-core polyhydroxylated and multi-N-donor compounds are being reported. The reaction of 2,4,6-tris(4-n-butylaminophenyl)triazine (1) with cyanuric chloride provided star-shaped fragment (2) with six reactive chloro-substituents. Upon treatment of this fragment with bis(2-hydroxyethyl)amine (3a) and bis(2-pyridylmethyl)amine (3b), functionalized polyhydroxylated (4a) and multi-N-donor compounds (4b) were obtained in high yields through nucleophilic aromatic substitution. These functionalized compounds are expected to have unique applications in supramolecular self-assembly and material chemistry.

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Naseer, M. M.; Nazir, H.; Hameed, S. Synthons for Supramolecular Assemblies: Synthesis of New Triazine-Core Polyhydroxylated and Multi-N-Donor Compounds. Eur. J. Chem. 2013, 4, 149-152.

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Supporting Agencies

The higher education commission (HEC), (PM-IPFP/HRD/HEC/2011/3407), Govt. of Pakistan, Pakistan
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