

Influence of some synthesized pyrimidine derivatives on corrosion inhibition of mild steel in hydrochloric acid medium
Doddahosuru Mahadevappa Gurudatt (1)


(1) Department of Studies in Chemistry, University of Mysore, Manasagangothri, Mysore 570 006, India
(2) Department of Studies in Chemistry, University of Mysore, Manasagangothri, Mysore 570 006, India
(*) Corresponding Author
Received: 27 Jul 2013 | Accepted: 30 Aug 2013 | Published: 31 Mar 2014 | Issue Date: March 2014
Abstract
The influence of four newly synthesized pyrimidine derivatives on the corrosion inhibition of mild steel in 0.5 M HCl solution is studied using mass loss and electrochemical techniques. The corrosion rate was found to depend on concentration and temperature of the medium. Adsorption of all the four inhibitors obeys Langmuir isotherm model. Polarization curves indicated that the studied inhibitors are of mixed type. Electrochemical impedance spectroscopy explains the mechanism of inhibitor’s action. Various activation and adsorption thermodynamic parameters were calculated and discussed. The results obtained from weight loss and electrochemical studies are in good agreement with each other. The variation in inhibitive efficiency mainly depends on the type and nature of the substituents present in the inhibitor molecule.
Announcements
Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.
1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).
2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).
3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF

DOI: 10.5155/eurjchem.5.1.53-64.899
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics


Citations
[1]. A. S. Fouda, M. A. Ismail, M. A. Khaled, A. A. El-Hossiany
Experimental and computational chemical studies on the corrosion inhibition of new pyrimidinone derivatives for copper in nitric acid
Scientific Reports 12(1), , 2022
DOI: 10.1038/s41598-022-20306-4

[2]. Vandana Saraswat, M. Yadav
Computational and electrochemical analysis on quinoxalines as corrosion inhibitors for mild steel in acidic medium
Journal of Molecular Liquids 297, 111883, 2020
DOI: 10.1016/j.molliq.2019.111883

[3]. M. Tiskar, M. Galai, H. Elhadiri, M. Ebn Touhami, M. Sfaira, B. Satrani, M. Ghanmi, A. Chaouch, R. Touir
Juniperus Phoenicea essential oil as green corrosion inhibitor for mild steel in molar hydrochloric acid
Matériaux & Techniques 104(6-7), 609, 2016
DOI: 10.1051/mattech/2017003

[4]. Kedila Rasheeda, Aeshah Hassan Alamri, P.A. Krishnaprasad, N. Phadke Swathi, Vijaya D.P. Alva, Talal A. Aljohani
Efficiency of a pyrimidine derivative for the corrosion inhibition of C1018 carbon steel in aqueous acidic medium: Experimental and theoretical approach
Colloids and Surfaces A: Physicochemical and Engineering Aspects 642, 128631, 2022
DOI: 10.1016/j.colsurfa.2022.128631

References
[1]. Moretti, G.; Guidi, F.; Grion, G. Corros. Sci. 2004, 46, 387-403.
http://dx.doi.org/10.1016/S0010-938X(03)00150-1
[2]. Dahmani, M.; Et-Touhami, A.; Al-Deyab, S. S.; Hammouti B.; Bouyanzer, A. Int. J. Electrochem. Sci. 2010, 5, 1060-1069.
[3]. Collins, W. D.; Weyers, R. E.; Al-Qadi, I. L. Corrossion 1993, 49, 74-78.
http://dx.doi.org/10.5006/1.3316037
[4]. Obot, I. B.; Obi-Egbedi, N. O.; Umoren, S. A. Corros. Sci. 2009, 51, 276-282.
http://dx.doi.org/10.1016/j.corsci.2008.11.013
[5]. Obot, I. B.; Obi-Egbedi, N. O. Surf. Rev. Lett. 2008, 15, 903-910.
http://dx.doi.org/10.1142/S0218625X08012074
[6]. Ashassi-Sorkhabi, H.; Shaabani, B.; Seifzadeh, D. Electrochim. Acta 2005, 50, 3446-3452.
http://dx.doi.org/10.1016/j.electacta.2004.12.019
[7]. Hammouti, B.; Zarrouk, A.; Al-Deyab, S. S.; Warad, I. Oriental J. Chem. 2011, 27, 23-31.
[8]. Elayyachy, M.; Hammouti, B.; El Idrissi, A.; Aouniti, A. Port. Electrochim. Acta. 2011, 29, 57-68.
http://dx.doi.org/10.4152/pea.201101057
[9]. Zarrouk, A.; Warad, I.; Hammouti, B.; Dafali, A.; Al-Deyab, S. S.; Benchat, N. Int. J. Electrochem. Sci. 2010, 5, 1516-1526.
[10]. Khaled, K. F.; Abdelshafi, N. S.; El-Maghraby, A.; Al-Mobarak, N. J. Mater. Environ. Sci. 2011, 2, 166-173.
[11]. Chetouani, A.; Hammouti, B.; Aouniti, A.; Benchat, N.; Benhadda, T. Prog. Org. Coat. 2002, 45, 373-378.
http://dx.doi.org/10.1016/S0300-9440(02)00123-6
[12]. Wang, L. Corros. Sci. 2006, 48, 608-616.
http://dx.doi.org/10.1016/j.corsci.2005.02.007
[13]. Bentiss, F.; Gassama, F.; Barbry, D.; Gengembre, L.; Vezin, H.; Lagrenee, M.; Traisnel, M. Appl. Surf. Sci. 2006, 252, 2684-2691.
http://dx.doi.org/10.1016/j.apsusc.2005.03.231
[14]. Ghazoui, A.: Saddik, R.; Guenbour, M.; Benchat, N.; Hammouti, B.; Al-Deyab, S. S. Zarrouk, A. A. Int. J. Electrochem. Sci. 2012, 7, 7080-7097.
[15]. Elewady G. Y. Int. J. Electrochem. Sci. 2008, 3, 1149-1161
[16]. Zarrok, H.; Saddik, R.; Oudda, H.; Hammouti, B.; El Midaoui, A.; Zarrouk, A.; Benchat, N.; Ebn Touhami, M. Der Pharma Chemica 2011, 3, 272-282.
[17]. Vasantasree, V.; Ranachan, T. Z. J. Electro Chem. 1996, 15, 71-75.
[18]. Ayre, J. A; Corrosion Aspects of Reactor Decontamination and Corrosion of Reactor Materials, International Atomic Agency, Wien, 1962, 199.
[19]. Akhaja, T. N.; Raval, J. P. Eur. J. Med. Chem. 2011, 46, 5573-5579.
http://dx.doi.org/10.1016/j.ejmech.2011.09.023
[20]. Zhao, W. Li, X.; Liu, F. L.; Hou, B. Corros. Sci. 2008, 50, 3261-3266.
[21]. Chetouani, A.; Hammouti, B.; Aouniti, A.; Benchat, N.; Benhadda, T. Prog. Org. Coat. 2002, 45, 373-378.
http://dx.doi.org/10.1016/S0300-9440(02)00123-6
[22]. Ita, B. I.; Offiong, O. E. Mater. Chem. Phys. 2001, 70, 330-335.
http://dx.doi.org/10.1016/S0254-0584(00)00476-4
[23]. Ehteram, A. N. Int. J. Electrochem. Sci. 2007, 2, 996-1017.
[24]. Putilova, I. N.; Balezin, S. A.; Baranik. Metallic Corrosion Inhibitors, Pergamon Press, New York, 1960.
[25]. Popova, A.; Sokolova, E.; Raicheva, S.; Chritov, M. Corros. Sci. 2003, 45, 33-41.
http://dx.doi.org/10.1016/S0010-938X(02)00072-0
[26]. Quartarone, G.; Moretti, G.; Tassan, A.; Zingales, Werkst. Korros. 1994, 45, 641-647.
[27]. Ramesh, S. V.; Adhikari, V. Bull. Mater. Sci. 2007, 31, 699-711.
http://dx.doi.org/10.1007/s12034-008-0111-4
[28]. Bensajjay, E.; Alehyen, S.; Achouri, M. E.; Kertit, S. Anti-Corros. Method M. 2003, 50 402-409.
[29]. Ashassi-Sorkhabi, H.; Eshaghi, M. Mater. Chem. Phys. 2009, 114, 267-271.
http://dx.doi.org/10.1016/j.matchemphys.2008.09.019
[30]. Bentiss, F.; Lebrini, M.; Lagrenee, M. Corros. Sci. 2005, 47 (12), 2915-2931.
http://dx.doi.org/10.1016/j.corsci.2005.05.034
[31]. Mertens, S. F.; Xhoffer, C.; Decooman, B. C.; Temmerman, E. Corrosion 2000, 53 (5), 381-388.
http://dx.doi.org/10.5006/1.3280481
[32]. Behpour, M.; Ghoreishi, S. M.; Soltani, N.; Salavati-Niasari, M.; Hamadanian, M.; Gandomi, A. Corros. Sci. 2008, 50, 2172-2181.
http://dx.doi.org/10.1016/j.corsci.2008.06.020
[33]. Tang, Y.; Yang, X.; Yang, W.; Wan, R.; Chen, Y.; Yin, X. Corros. Sci. 2010, 52, 1801-1808.
http://dx.doi.org/10.1016/j.corsci.2010.01.028
[34]. Mc-Cafferty, E.; Hackerman, N. J. Electrochem. Soc. 1972, 119, 146-154.
http://dx.doi.org/10.1149/1.2404150
[35]. Martinez, S.; Hucovic, M. M. J. Appl. Electrochem. 2003, 33, 1137-1142.
http://dx.doi.org/10.1023/B:JACH.0000003851.82985.5e
[36]. Ferreira, E. S.; Giancomelli, C.; Giacomelli, F. C.; Spinelli, A. Chem. Phys. Lett. 2004, 83, 129-134.
[37]. Li, W. H.; He, Q.; Zhang, S. T.; Pei, C. L.; Hou, B. R. J. Appl. Electrochem. 2008, 38, 289-295.
http://dx.doi.org/10.1007/s10800-007-9437-7
[38]. Hoar, T. P.; Holliday, R. D. J. Appl. Chem. 1953, 3, 502-513.
http://dx.doi.org/10.1002/jctb.5010031105
[39]. Donnelly, B.; Downie, T. C.; Grzeskowiak, R. Corros. Sci. 1974, 14, 597- 606.
http://dx.doi.org/10.1016/S0010-938X(74)80024-7
[40]. Ozcan, M.; Dehri, I. Prog. Org. Coat. 2004, 51, 181-187.
http://dx.doi.org/10.1016/j.porgcoat.2004.07.017
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.5.1.53-64.899

















European Journal of Chemistry 2014, 5(1), 53-64 | doi: https://doi.org/10.5155/eurjchem.5.1.53-64.899 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.