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An N-heterocyclic carbene-palladium-η3-allyl chloride complex for the Suzuki-Miyaura coupling of aryl halides
Noland William Broekemier (1)
, Noah Curtis Broekemier (2) , Randall Thomas Short (3) , Hector Palencia (4,*) (1) Department of Chemistry, University of Nebraska at Kearney, Kearney, NE 68849, USA
(2) Department of Chemistry, University of Nebraska at Kearney, Kearney, NE 68849, USA
(3) Department of Chemistry, Ball State University, Muncie, IN 47306, USA
(4) Department of Chemistry, University of Nebraska at Kearney, Kearney, NE 68849, USA
(*) Corresponding Author
Received: 29 Sep 2013 | Revised: 28 Oct 2013 | Accepted: 29 Oct 2013 | Published: 31 Mar 2014 | Issue Date: March 2014
Abstract
An unsymmetrical, well-defined N-heterocyclic carbene-palladium-η3-allyl chloride complex has been synthesized and used as an efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides. The catalyst provides moderate to high yields of cross-coupling products at 50 °C in 2 hours, using 1 mol % of the catalyst and isopropyl alcohol as solvent.
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European Journal of Chemistry
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DOI: 10.5155/eurjchem.5.1.162-166.940
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Research Corporation for Science Advancement
Citations
[1]. Isabel Monreal-Leyva, Breanna Rose Attema, Nuri Bae, Haishi Cao, Hector Palencia
Benzoin condensation of aromatic aldehydes catalyzed by N-heterocyclic carbenes under mild conditions
European Journal of Chemistry 10(1), 1, 2019
DOI: 10.5155/eurjchem.10.1.1-6.1826
[2]. Abbas Washeel Salman, Rosenani A. Haque
Pd(II) and trinuclear Ag(I) bis-N-heterocyclic carbene complexes: Synthesis, structural and in vitro anticancer activity
European Journal of Chemistry 7(1), 115, 2016
DOI: 10.5155/eurjchem.7.1.115-120.1387
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DOI Link: https://doi.org/10.5155/eurjchem.5.1.162-166.940
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European Journal of Chemistry 2014, 5(1), 162-166 | doi: https://doi.org/10.5155/eurjchem.5.1.162-166.940 | Get rights and content
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