European Journal of Chemistry

Interaction of charge transfer fluorescence probe with non-ionic surfactants: Estimation of physico-chemical properties and association constant

Article Sidebar

PDF
Published: Dec 22, 2010
DOI: https://doi.org/10.5155/eurjchem.1.4.341-347.98
Keywords:
Fluorescence, Non-ionic surfactants, Intramolecular charge transfer, CMC, Micropolarity, Association constant
Section
Research Article
Issue
Vol. 1 No. 4 (2010): December 2010
Dates
Received 2010-05-06
Accepted 2010-09-20
Published 2010-12-22


Main Article Content

Takhellambam Sanjoy Singh
Department of Chemistry, North-Eastern Hill University, Shillong, IN-793022, India
Sivaprasad Mitra
Department of Chemistry, North-Eastern Hill University, Shillong, IN-793022, India

Abstract

Fluorescence behavior of intramolecular charge transfer probe trans-ethyl-p-(dimethylamino) cinnamate (EDAC) is extremely sensitive to the local environment. This study explores the interaction of EDAC with several Igepal, Brij and Tween series of non-ionic surfactants by steady state and picoseconds time-resolved fluorescence spectroscopy. The physico-chemical properties, like critical micelle concentration and micropolarity of the micellar media surrounding the probe were determined. In most of the cases, the observed values were in good agreement with the data reported in the literature. Results obtained from time-resolved fluorescence experiments show a substantial reduction in total non-radiative decay rate of the probe in micellar medium compared to that in aqueous phase. This indicates preferential association of the probe inside the micellar core. The association constant of the probe-micelle interaction was also evaluated in different cases.

1_4_341_347_800


icon graph This Abstract was viewed 2086 times | icon graph Article PDF downloaded 2043 times

How to Cite
(1)
Singh, T. S.; Mitra, S. Interaction of Charge Transfer Fluorescence Probe With Non-Ionic Surfactants: Estimation of Physico-Chemical Properties and Association Constant. Eur. J. Chem. 2010, 1, 341-347.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Thomas, J. K. Chem. Rev. 1980, 80, 283-299.
doi:10.1021/cr60326a001

[2]. Fendler, J. H. Membrane Mimetic Chemistry. Wiley-Interscience, New York, 1982.

[3]. Grätzel, M.; Kalyansundaram, K. Kinetics and Catalysis in Microheterogeneous Systems, Surfactant Science Series, Marcel Dekker, New York, vol. 38, 1991.

[4]. Bayindir, Z. S.; Yuksel, N. J. Pharm. Sci. 2010, 99, 2049-2060.

[5]. Sato, H.; Shibata, A.; Wang, Y.; Yoshikawa, H.; Tamura, H. Biomacromolecules 2003, 4, 46-51.
doi:10.1021/bm025616q
PMid:12523845

[6]. Turro, N. J.; Grätzel, M.; Braun, A. M. Angew. Chem. Int. Ed. Eng. 1980, 19, 675-696.
doi:10.1002/anie.198006751

[7]. Kalyansundaram, K. Photochemistry in Organized and Constrained Media. Ramamurthy, V. (ed), VCH Publishers, New York, pp 39, 1991.

[8]. Law, K. Y. Photochem. Photobiol. 1981, 33, 799-806.
doi:10.1111/j.1751-1097.1981.tb05495.x

[9]. Kano, K.; Ueno, Y.; Hashimoto, S. J. Phys. Chem. 1985, 89, 3161-3166.
doi:10.1021/j100260a042

[10]. Ghosh, S. K.; Khatua, P.K.; Bhattacharyya, S. C. Int. J. Mol. Sci. 2003, 4, 562-571.
doi:10.3390/i4110562

[11]. Banerjee, P.; Chatterjee, S.; Pramanik, S.; Bhattacharyya, S. C. Colloids and Surfaces A: Physicochem. Eng. Aspects 2007, 302, 44-50.
doi:10.1016/j.colsurfa.2007.01.038

[12]. Shin, M. C.; Choi, H-D.; Kim, D-H.; Baek, K. Desalination 2008, 223, 299-307.
doi:10.1016/j.desal.2007.01.223

[13]. Das, S.; Dogra, S. K. J. Chem. Soc. Faraday. Trans. 1998, 94, 139-145.

[14]. Graca, M.; Bongaerts, J. H. H.; Stokes, J. R.; Granick, S. J. Colloid and Interface Sci. 2007, 315, 662-670.
doi:10.1016/j.jcis.2007.06.057
PMid:17706238

[15]. Ghosh, S. K.; Khatua, P. K.; Bhattacharyya, S. C. J. Colloid and Interface Sci. 2004, 275, 623-631.
doi:10.1016/j.jcis.2004.02.077
PMid:15178296

[16]. Ray, R.; Bhattacharyya, S. C.; Moulik, S. P. J. Photochem. Photobiol. A. Chem. 1997, 108, 267-272.
doi:10.1016/S1010-6030(97)00088-9

[17]. Chatterjee, S.; Bhattacharyya, S. C. Spectrochim. Acta A 2006, 64, 355-362.
doi:10.1016/j.saa.2005.07.031
PMid:16531105

[18]. Bhattacharya, S. C.; Das, H.; Moulik, S. P. J. Photochem. Photobiol. A: Chem. 1993, 74, 239-245.
doi:10.1016/1010-6030(93)80122-P

[19]. Correa, N. M.; Biasutti, M. A.; Silber, J. J. J. of Colloid and Interface Sci. 1994, 186, 570-578.

[20]. Zhao, C-L.; Winnik, M. A.; Riess, G.; Croucher, M. D. Langmuir 1990, 6, 514-516.
doi:10.1021/la00092a038

[21]. Van Stam, J.; Depaemelaere, S.; De Schryver, F. C. J. Chem. Edu. 1998, 75, 93-98.
doi:10.1021/ed075p93

[22]. Beecham, J. M.; Brand, L. Ann. Rev. Biochem. 1985, 54, 43-71.
doi:10.1146/annurev.bi.54.070185.000355
PMid:3896124

[23]. Zacchariasse, K. A.; Kozankiewicz, B.; Kűhnle, W. Surfactants in Solution. Mittal, K. L.; Lindmann, B. Plenum Press, New York, vol. 1, p 565, 1984.

[24]. Stubbs, C. D.; Williams, B. W. Topics in Fluorescence Spectroscopy. Lacowicz, R., Plenum Press, New York, vol. 3. p 331, 1991.

[25]. Singh, T. S.; Mitra, S.; Chandra, A. K.; Tamai, N.; Kar, S. J. Photochem. Photobiol. A: Chem. 2008, 197, 295-305.
doi:10.1016/j.jphotochem.2008.01.007

[26]. Moyon, N. S.; Singh, T. S.; Mitra, S. Biophys. Chem. 2008, 138, 55-62.
doi:10.1016/j.bpc.2008.09.004
PMid:18819744

[27]. Bevington, P. R. Data Reduction and Error Analysis for the Physical Sciences. McGraw-Hill, New York, 1969.

[28]. O’Connor, D. V.; Philips, D. Time-correlated single photon counting. Academic press, London, 1984.

[29]. Das, S. K.; Bansal, A.; Dogra, S. K. Bull. Chem. Soc. Jpn. 1997, 70, 307-313.
doi:10.1246/bcsj.70.307

[30]. Sanjoy Singh, T.; Mitra, S. J. Colloid & Interface Sci. 2007, 311, 128-134.
doi:10.1016/j.jcis.2007.02.046
PMid:17362973

[31]. Sanjoy Singh, T.; Mitra, S. J. Incl. Phen. Macrocycl. Chem. 2009, 63, 335-345.
doi:10.1007/s10847-008-9527-0

[32]. Sanjoy Singh, T.; Mitra, S. Photochem. Photobiol. Sci. 2008, 7, 1063-1070.
doi:10.1039/b717475f

[33]. Maciejewski, A.; Kubicki, J.; Dobek, K. J. Phys. Chem. B 2003, 107, 13986-13999.
doi:10.1021/jp036340z

[34]. Greiser, F.; Drummond, C. J. J. Phys. Chem. 1988, 92, 5580-5593.
doi:10.1021/j100331a012

[35]. Demchenko, A. P.; Shcherbatska, N. V. Biophys. Chem. 1985, 22, 131-143.
doi:10.1016/0301-4622(85)80035-1

[36]. Hirose, C.; Sepulveda, L. J. Phys. Chem. 1981, 85, 3689-3694.
doi:10.1021/j150624a032

[37]. Sanjoy Singh, T.; Mitra, S. J. Lumin. 2007, 127, 508-514.
doi:10.1016/j.jlumin.2007.03.001

[38]. Reichardt, C. Chem. Rev. 1994, 94, 2319-2358.
doi:10.1021/cr00032a005

[39]. Sanjoy Singh, T.; Moyon, N. S.; Mitra, S. Spectrochim. Acta A 2009, 73, 630-636.
doi:10.1016/j.saa.2009.03.004
PMid:19380249

Supporting Agencies

UGC, India
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).