European Journal of Chemistry 2019, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849

Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer


Prafullya Kumar Mudi (1) orcid , Chanchal Kumar Pal (2) orcid , Bhaskar Biswas (3,*) orcid

(1) Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
(2) Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
(3) Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
(*) Corresponding Author

Received: 17 Mar 2019, Accepted: 04 May 2019, Published: 30 Jun 2019

Abstract


A one dimensional (1D) lead(II) coordination polymer, [Pb(Phen)(NO3)(OAC)(H2O)]n (1) (Phen = 1,10-Phenanthroline; OAc = Acetate) was isolated in crystalline phase and characterized through different analytical techniques. Single crystal X-ray structural analysis of compound 1 revealed that the Pb(II) polymer crystallized in a monoclinic system with P21/c space group. Pb2+ ion adopted a highly distorted octahedral geometry having O3 (water) and O5 (nitrate) at axial positions (∠O3-Pb1-O5 of 145.02°) and acetate oxygen (O4), phenanthroine nitrogens (N3, N4) and oxygen (O2) atom from bridging nitrate made a distorted square plane. This Pb(II) polymer exhibited good fluorescence property in solid state. The steric arrangement of distorted square plane around Pb(II) ion by Phen, acetate and bridging nitrate ion makes a huge gap around Pb(II) ion where a stereo-active lone pair of electrons may possibly be occupied.

 


Keywords


Pb(II); 1D polymer; Phenanthroline; X-ray crystal structure; Fluorescence property; Supramolecular interactions

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DOI: 10.5155/eurjchem.10.2.125-130.1849

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How to cite


Mudi, P.; Pal, C.; Biswas, B. Eur. J. Chem. 2019, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849
Mudi, P.; Pal, C.; Biswas, B. Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer. Eur. J. Chem. 2019, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849
Mudi, P., Pal, C., & Biswas, B. (2019). Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer. European Journal of Chemistry, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849
Mudi, Prafullya, Chanchal Kumar Pal, & Bhaskar Biswas. "Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer." European Journal of Chemistry [Online], 10.2 (2019): 125-130. Web. 14 Oct. 2019
Mudi, Prafullya, Pal, Chanchal, AND Biswas, Bhaskar. "Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer" European Journal of Chemistry [Online], Volume 10 Number 2 (30 June 2019)

DOI Link: https://doi.org/10.5155/eurjchem.10.2.125-130.1849

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