Ziziphus mauritiana leaves extracts as corrosion inhibitor for mild steel in H2SO4 and HCl solutions

Shivapura Subbappa Shivakumar, Kikkeri Narasimha Shetty Mohana

Abstract


The inhibition performance of extracts of Ziziphus mauritiana on mild steel corrosion in 0.5 M H2SO4 and 0.5 M HCl was investigated using gravimetric, electrochemical polarization, electrochemical impedance spectroscopy and scanning electron microscopic studies. The gravimetric results indicate that Ziziphus mauritiana leaves extract exhibits good inhibition efficiency in both the acids. Furthermore, the inhibition efficiency decreases with increase in temperature. Polarization measurements showed that the studied inhibitor is mixed type in both acids with significant reduction of cathodic and anodic current densities. Electrochemical impedance spectroscopy measurements revealed that the charge transfer resistance increases with increase in the concentration of Ziziphus mauritiana extracts. Various thermodynamic parameters such as activation energy, activation enthalpy and activation entropy are evaluated and discussed. Adsorption thermodynamic parameters are also computed, and SEM was used to analyze the surface adsorbed film.

3_4_426_432_800


Keyword(s)


Mild steel; Corrosion; Weight loss; Polarization; Ziziphus mauritiana; Electrochemical impedance

European Journal of Chemistry, 3 (4), (2012), 426-432

Full Text:

PDF    /    /

DOI: http://dx.doi.org/10.5155/eurjchem.3.4.426-432.671

Cited by

[1]. Chikkur B. Pradeep Kumar, Kikkeri N. Mohana
The Effect of Achyranthes aspera Extracts on Mild Steel Corrosion in Industrial Water Medium
ISRN Corrosion  2013, 1, 2013
DOI: 10.1155/2013/261847
/


[2]. Djamel Daoud, Tahar Douadi, Saifi Issaadi, Salah Chafaa
Adsorption and corrosion inhibition of new synthesized thiophene Schiff base on mild steel X52 in HCl and H2SO4 solutions
Corrosion Science  79, 50, 2014
DOI: 10.1016/j.corsci.2013.10.025
/


[3]. Raman Kumar, Ompal Singh Yadav, Gurmeet Singh
Electrochemical and surface characterization of a new eco-friendly corrosion inhibitor for mild steel in acidic media: A cumulative study
Journal of Molecular Liquids  237, 413, 2017
DOI: 10.1016/j.molliq.2017.04.103
/


[4]. P. Muthukrishnan, P. Prakash, B. Jeyaprabha, K. Shankar
Stigmasterol extracted from Ficus hispida leaves as a green inhibitor for the mild steel corrosion in 1M HCl solution
Arabian Journal of Chemistry  , , 2015
DOI: 10.1016/j.arabjc.2015.09.005
/


[5]. Samy M. Shaban, Ali A. Abd-Elaal, Salah M. Tawfik
Gravimetric and electrochemical evaluation of three nonionic dithiol surfactants as corrosion inhibitors for mild steel in 1M HCl solution
Journal of Molecular Liquids  216, 392, 2016
DOI: 10.1016/j.molliq.2016.01.048
/


[6]. Manpreet Kaur Bagga, Ranu Gadi, Ompal Singh Yadav, Raman Kumar, Rashi Chopra, Gurmeet Singh
Investigation of phytochemical components and corrosion inhibition property of Ficus racemosa stem extract on mild steel in H 2 SO 4 medium
Journal of Environmental Chemical Engineering  4(4), 4699, 2016
DOI: 10.1016/j.jece.2016.10.022
/


[7]. Manpreet Kaur Bagga, Ranu Gadi, Gurmeet Singh
Ficus racemosa as corrosion inhibitor for mild steel in acid medium
Emerging Materials Research  6(1), 117, 2017
DOI: 10.1680/jemmr.15.00055
/


[8]. Chuan Lai, Bin Xie, Like Zou, Xingwen Zheng, Xiao Ma, Shasha Zhu
Adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by S-allyl-O,O′-dialkyldithiophosphates
Results in Physics  7, 3434, 2017
DOI: 10.1016/j.rinp.2017.09.012
/


References

[1]. Shyamala, M.; Kasthuri, P. K. Int. J. Corros. 2012, 1-13.
http://dx.doi.org/10.1155/2012/852827

[2]. Quraishi, M. A.; Singh, A.; Singh, V. K.; Yadav, D. K.; Singh, A. K. Mater. Chem. Phys. 2010, 122, 114-122.
http://dx.doi.org/10.1016/j.matchemphys.2010.02.066

[3]. Chauhan, L. R.; Gunasekaran, G. Corros. Sci. 2007, 49, 1143-1161.
http://dx.doi.org/10.1016/j.corsci.2006.08.012

[4]. Ostavari, A.; Hoseinieh, S. M.; Peikari, M.; Shadizadeh, S. R.; Hashemi, S. J. Corros. Sci. 2009, 51, 1935-1949.
http://dx.doi.org/10.1016/j.corsci.2009.05.024

[5]. Trindade, L. G.; Goncalves, R. S. Corros. Sci. 2009, 51, 1578-1583.
http://dx.doi.org/10.1016/j.corsci.2009.03.038

[6]. Mohana, K. N.; Shivakumar, S. S.; Badiea, A. M. J. Korean. Chem. Soc. 2011, 55, 364-372.

[7]. El-Etre, A. Y. Appl. Surf. Sci. 2006, 252, 8521-8525.
http://dx.doi.org/10.1016/j.apsusc.2005.11.066

[8]. Abdel-Gaber, A. M.; Abd-El-Nabey, B. A.; Saadawy, M.; Sidahmed, I. M.; El- Zayady, A. M. Corros. Sci. 2006, 48, 2765-2779.
http://dx.doi.org/10.1016/j.corsci.2005.09.017

[9]. Oguzie, E. E. Corros. Sci. 2008, 50, 2993-2998.
http://dx.doi.org/10.1016/j.corsci.2008.08.004

[10]. Lebrini, M.; Robert, F.; Blandinieres, P. A.; Roos, C. Int. J. Electrochem. Sci. 2011, 6, 2443-2460.

[11]. Sharma, M. K.; Arora, P.; Kumar, S.; Mathur, S. P.; Ratnani, R. Corros. Eng. Sci. Technol. 2008, 43, 213-218.
http://dx.doi.org/10.1179/174327807X196816

[12]. Oguzie, E. E. Port. Electrochem. Acta. 2008, 26, 303-314.
http://dx.doi.org/10.4152/pea.200803303

[13]. Gopiraman, M.; Sakunthala, P.; Kanmani, R.; Alex, R. V.; Sulochana N. Ionics. 2011, 17, 843-852.
http://dx.doi.org/10.1007/s11581-011-0584-9

[14]. Abiola, O. K.; James, A. O. Corros. Sci. 2009, 51, 1879-1881.
http://dx.doi.org/10.1016/j.corsci.2009.04.016

[15]. Eddy, N. O. Port. Electrochim. Acta. 2009, 27, 579-589.
http://dx.doi.org/10.4152/pea.200905579

[16]. Umoren, S. A.; Obot, I. B.; Ebenso, E. E.; Obi-Egbedi, N. O. Port. Electrochim. Acta. 2008, 26, 199-209.
http://dx.doi.org/10.4152/pea.200802199

[17]. Quraishi, M. A.; Singh, A.; Singh, V. K.; Yadav, D. K.; Singh, A. K. Mat. Chem. Phys. 2010, 122, 114-122.
http://dx.doi.org/10.1016/j.matchemphys.2010.02.066

[18]. Lahhit, N.; Bouyanzer, A.; Desjobert, J. M. Port. Electrochem. Acta. 2011, 29, 127-138.
http://dx.doi.org/10.4152/pea.201102127

[19]. Obot, I. B.; Obi-Egbedi, N. O. J. Appl. Electrochem. 2010, 40, 1977-1984.
http://dx.doi.org/10.1007/s10800-010-0175-x

[20]. Badiea, A. M.; Mohana, K. N. J. Mater. Eng. Perform. 2009, 18, 1264-1271.
http://dx.doi.org/10.1007/s11665-009-9378-x

[21]. Ambrish, S.; Ishtiaque, A.; Singh, V. K.; Quraishi, M. A. J. Solid. State. Electrochem. 2011, 15, 1087-1097.

[22]. Niketan, P.; Anamika, R.; Smita, J.; Girish, M. Eur. J. Chem. 2010, 1, 129-133.
http://dx.doi.org/10.5155/eurjchem.1.2.129-133.52

[23]. Onder, K.; Sezai, E.; Memnune, S.; Celil, T.; Sedat, S. African. J. Biotic. 2009, 8, 303-307.

[24]. Chadha, Y. R. The Wealth of India, A Dictionary of Indian Raw Materials and Industrial Products, Vol. 11, Publication and information directorate, CSIR, New Delhi, 1976, 112-122.

[25]. Cheng, G.; Bai, Y.; Zhao, Y.; Tao, J.; Liu, Y.; Tu, G. Tetrahedron 2000, 56, 8915-8920.
http://dx.doi.org/10.1016/S0040-4020(00)00842-5

[26]. Yoshikawa, M.; Murakami, T.; Ikebata, A.; Wakao, S.; Murakami, N.; Matsuda, H. Chem. Pharm. Bull. 1997, 45, 1186-1192.
http://dx.doi.org/10.1248/cpb.45.1186

[27]. Lee, S. M.; Park, J. G.; Lee, Y. H.; Lee, C. G.; Min, B. S.; Kim, J. H.; Lee, H. K. Biol. Pharm. Bull. 2004, 27, 1883-1886.
http://dx.doi.org/10.1248/bpb.27.1883
PMid:15516743

[28]. Sena, L. P.; Vanderjagt, D. J. Plant. Foods. Human. Nutr. 1998, 52, 17-30.
http://dx.doi.org/10.1023/A:1008010009170

[29]. Yoganarasimhan, S. N. Medicinal Plants of India, Tamilnadu. Vol. 2. Cyber Media, Bangalore, 2000.

[30]. Schorr, M.; Yahalom, J. Corros. Sci. 1972, 12, 867-868.
http://dx.doi.org/10.1016/S0010-938X(72)80015-5

[31]. Mu, G. N.; Li, X. H.; Qu, Q.; Zhou, J. Corros. Sci. 2006, 48, 445-459.
http://dx.doi.org/10.1016/j.corsci.2005.01.013

[32]. Hosseini, M. G.; Ehteshamazadeh, M.; Shahrabi, T. Electrochim. Acta. 2007, 52, 3680-3685.
http://dx.doi.org/10.1016/j.electacta.2006.10.041

[33]. Cao, C. Corros. Sci. 1996, 38, 2073-2082.
http://dx.doi.org/10.1016/S0010-938X(96)00034-0

[34]. Lebrini, M.; Traisnel, M.; Lagrenee, M.; Mernari, B.; Bentiss, F. Corros. Sci. 2008, 50, 473-479.
http://dx.doi.org/10.1016/j.corsci.2007.05.031

[35]. Murlidharan, S.; Phani, K. L. N.; Pitchumani, S.; Ravichandran, S. J. Electrochem. Soc. 1995, 142, 1478–1483.
http://dx.doi.org/10.1149/1.2048599

[36]. Bentiss, F.; Traisnel, M.; Lagrenee, M. Corros. Sci. 2000, 42, 127-146.
http://dx.doi.org/10.1016/S0010-938X(99)00049-9

[37]. Growcock, F. B.; Jasinski, R. J. J. Electrochem. Soc. 1989, 136, 2310-2314.
http://dx.doi.org/10.1149/1.2097847

[38]. Bataillon, C.; Brunet, S. Electrochim. Acta. 1994, 39, 455-465.
http://dx.doi.org/10.1016/0013-4686(94)80086-3

[39]. Li, W.; Zhao, X.; Liu, F.; Hou, B. Corros. Sci. 2008, 50, 3261-3266.
http://dx.doi.org/10.1016/j.corsci.2008.08.015

[40]. Prabhu, R. A.; Shanbhag, A. V.; Venkatesha T. V. J. Appl. Electrochem. 2007, 37, 491–497.
http://dx.doi.org/10.1007/s10800-006-9280-2

[41]. Dehri, I.; Ozcan, M. Mater. Chem. Phys. 2006, 98, 316-323.
http://dx.doi.org/10.1016/j.matchemphys.2005.09.020

[42]. Popova A, Corros. Sci. 2007, 49, 2144-2158.
http://dx.doi.org/10.1016/j.corsci.2006.10.020

[43]. Guan, N. M.; Xueming, L.; Fei, L. Mater. Chem. Phys. 2004, 86, 59-68.
http://dx.doi.org/10.1016/j.matchemphys.2004.01.041

[44]. Soltani, N.; Behpour, M.; Ghoreishi, S. M.; Naeimi, H. Corros. Sci. 2010, 52, 1351-1361.
http://dx.doi.org/10.1016/j.corsci.2009.11.045

[45]. Gomma, M. K.; Wahden, M. H. Mater. Chem. Phys. 1995, 39, 209-213.
http://dx.doi.org/10.1016/0254-0584(94)01436-K

[46]. Tang, L.; Li, X.; Li, L.; Qu, Q.; Mu, G.; Liu, G. Mater. Chem. Phys. 2005, 94, 353-359.
http://dx.doi.org/10.1016/j.matchemphys.2005.05.015

[47]. Bensajjay, E.; Alehyen, S.; El Achouri, M.; Kertit, S. Anti-Corros. Meth. Mater. 2003, 50, 402-409.

[48]. Machnikova, E.; Whitmire, K. H.; Hackerman, N. Electrochim. Acta. 2008, 53, 6024-6032.
http://dx.doi.org/10.1016/j.electacta.2008.03.021

[49]. Bentiss, F.; Lebrini, M.; Lagrenee, M. Corros. Sci. 2005, 47, 2915-2931.
http://dx.doi.org/10.1016/j.corsci.2005.05.034

[50]. Mertens, S. F.; Xhoffer, C.; Decooman, B. C.; Temmerman, E. Corrosion. 1997, 53, 381-388.
http://dx.doi.org/10.5006/1.3280481

[51]. Bentiss, F.; Lagrenee, M.; Traisnel, M.; Hornez, J. C. Corros. Sci. 1999, 41, 789-803.
http://dx.doi.org/10.1016/S0010-938X(98)00153-X


Refbacks

  • There are currently no refbacks.