European Journal of Chemistry 2014, 5(2), 305-310 | doi: https://doi.org/10.5155/eurjchem.5.2.305-310.1004 | Get rights and content

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Vibrational spectra and normal coordinate analysis of lithium pyruvate monohydrate and its isotopic compounds


Kazuhiko Hanai (1,*) , Akio Kuwae (2) , Ko-Ki Kunimoto (3) , Soh-Ichi Kitoh (4)

(1) Graduate School of Natural Sciences, Nagoya City University, Mizuho-Ku, Nagoya 467-8501, Japan
(2) Graduate School of Natural Sciences, Nagoya City University, Mizuho-Ku, Nagoya 467-8501, Japan
(3) Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-Machi, Kanazawa 920-1129, Japan
(4) Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-Machi, Kanazawa 920-1129, Japan
(*) Corresponding Author

Received: 18 Dec 2013 | Revised: 31 Jan 2014 | Accepted: 01 Feb 2014 | Published: 30 Jun 2014 | Issue Date: June 2014

Abstract


IR and Raman spectra of lithium pyruvate monohydrate and its O- and C-deuterated and 13C- and 18O-substituted compounds have been recorded in the solid state, and the observed bands have been assigned by using the isotope effects and the normal coordinate calculations based on the gem-diol structure (lithium 2,2-dihydroxypropionate). The refined force constants have well reproduced the observed frequencies and the 13C- and 18O-shifts. These results support the structures of these compounds discussed by many authors. The potential energy distributions show that many vibrational modes are very complicated except for the well-known group vibrations. The additive property of the isotopic frequency shifts has also been discussed.


Keywords


Gem-Diol form; Isotope shifts; IR spectroscopy; Raman spectroscopy; Normal coordinate analysis; Lithium pyruvate monohydrate

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DOI: 10.5155/eurjchem.5.2.305-310.1004

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The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Hanai, K.; Kuwae, A.; Kunimoto, K.; Kitoh, S. Eur. J. Chem. 2014, 5(2), 305-310. doi:10.5155/eurjchem.5.2.305-310.1004
Hanai, K.; Kuwae, A.; Kunimoto, K.; Kitoh, S. Vibrational spectra and normal coordinate analysis of lithium pyruvate monohydrate and its isotopic compounds. Eur. J. Chem. 2014, 5(2), 305-310. doi:10.5155/eurjchem.5.2.305-310.1004
Hanai, K., Kuwae, A., Kunimoto, K., & Kitoh, S. (2014). Vibrational spectra and normal coordinate analysis of lithium pyruvate monohydrate and its isotopic compounds. European Journal of Chemistry, 5(2), 305-310. doi:10.5155/eurjchem.5.2.305-310.1004
Hanai, Kazuhiko, Akio Kuwae, Ko-Ki Kunimoto, & Soh-Ichi Kitoh. "Vibrational spectra and normal coordinate analysis of lithium pyruvate monohydrate and its isotopic compounds." European Journal of Chemistry [Online], 5.2 (2014): 305-310. Web. 25 Jan. 2021
Hanai, Kazuhiko, Kuwae, Akio, Kunimoto, Ko-Ki, AND Kitoh, Soh-Ichi. "Vibrational spectra and normal coordinate analysis of lithium pyruvate monohydrate and its isotopic compounds" European Journal of Chemistry [Online], Volume 5 Number 2 (30 June 2014)

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