European Journal of Chemistry 2014, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038

Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2


Ikram Dhouib (1,*) , Philippe Guionneau (2) , Tahar Mhiri (3) , Zakaria Elaoud (4)

(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia
(*) Corresponding Author

Received: 26 Feb 2014, Accepted: 13 Mar 2014, Published: 30 Sep 2014

Abstract


An organic-inorganic hybrid compound of tetraethylammonium dihydrogenarsenate bis-arsenic acid salts of formula [(CH3CH2)4N].[H2AsO4].[H3AsO4]2(TEAs) were grown by the slow evaporation and characterized by means of single crystal X-ray diffraction, thermal analysis, FT-IR and Raman spectroscopy. This compound crystallize in the space groups Cc with unit cell parameters, a= 20.105(2) Å; b= 7.342(4) Å, c = 15.292(2) Å, γ = 115(4)°, Z = 4, R= 0.07. The structure has solved using direct methods and refined by least-squares analysis. In this case, the structure consists of infinite parallel two-dimensional planes built of mutually H2AsO4−, H3AsO4 tetrahedra connected by strong O-H···O hydrogen bonding. The thermoanalytical properties were studied using TG of TEAs method in the temperature ranges from 300 to 440 K for this hygroscopic sample. DSC measurement was carried out in the temperature range from 305 to 425 K.


Keywords


Arsenic acid; Crystal structure; Organic compounds; Raman spectroscopy; Infrared spectroscopy; Differential scanning calorimetry

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DOI: 10.5155/eurjchem.5.3.388-393.1038

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[1]. Ikram Dhouib, Philippe Guionneau, Zakaria Elaoud
Vibrational spectroscopy, electrical characterization, nonlinear optical properties and DFT calculation of (NEt4)(H2AsO4)(H3AsO4)2
Journal of Coordination Chemistry  70(21), 3585, 2017
DOI: 10.1080/00958972.2017.1406082
/

[2]. Karolina Schwendtner, Uwe Kolitsch
Three new acid M + arsenates and phosphates with multiply protonated As/PO4 groups
Acta Crystallographica Section C Structural Chemistry  75(8), 1134, 2019
DOI: 10.1107/S2053229619008489
/

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How to cite


Dhouib, I.; Guionneau, P.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2014, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038
Dhouib, I.; Guionneau, P.; Mhiri, T.; Elaoud, Z. Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2. Eur. J. Chem. 2014, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038
Dhouib, I., Guionneau, P., Mhiri, T., & Elaoud, Z. (2014). Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2. European Journal of Chemistry, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038
Dhouib, Ikram, Philippe Guionneau, Tahar Mhiri, & Zakaria Elaoud. "Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2." European Journal of Chemistry [Online], 5.3 (2014): 388-393. Web. 22 Nov. 2019
Dhouib, Ikram, Guionneau, Philippe, Mhiri, Tahar, AND Elaoud, Zakaria. "Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2" European Journal of Chemistry [Online], Volume 5 Number 3 (30 September 2014)

DOI Link: https://doi.org/10.5155/eurjchem.5.3.388-393.1038

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