

Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6
Ikram Dhouib (1,*)





(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(5) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(*) Corresponding Author
Received: 17 Jan 2013 | Accepted: 23 Jan 2013 | Published: 30 Jun 2013 | Issue Date: June 2013
Abstract
Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.

Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF

DOI: 10.5155/eurjchem.4.2.117-120.738
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics


Citations
[1]. A. Oueslati, M. Gargouri
Studies on structural, electrical, and transport properties of [(C3H7)4N]2Cu2Br6 compound
Journal of Alloys and Compounds 739, 1089, 2018
DOI: 10.1016/j.jallcom.2017.12.277

[2]. Ikram Dhouib, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2
European Journal of Chemistry 5(3), 388, 2014
DOI: 10.5155/eurjchem.5.3.388-393.1038

[3]. F. Lambarki, A. Ouasri, A. Rhandour, M. Saadi, L. El Ammari, L. Hajji
Structural, vibrational and electrical studies of tetramethylammonium trichloromercurate [(CH3)4N]HgCl3
Journal of Molecular Structure 1173, 865, 2018
DOI: 10.1016/j.molstruc.2018.07.051

[4]. Ikram Dhouib, Habib Feki, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
Structural, vibrational and thermal studies of a new nonlinear optical crystal tetrapropylammonium dihydrogenmonoarsenate bis arsenic acid
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 131, 274, 2014
DOI: 10.1016/j.saa.2014.04.120

References
[1]. Braga, D.; Desiraju, G. R.; Miller, J. S.; Orpen, A. G.; Price, S. L. Cryst. Eng. Commun. 2002, 4, 500-509.
http://dx.doi.org/10.1039/b207466b
[2]. Desiraju, G. R. Angew. Chem. Int. Ed. Engl. 1995, 34, 2311-2327.
http://dx.doi.org/10.1002/anie.199523111
[3]. Desiraju, G. R. J. Mol. Struct. 2003, 656, 5-15.
http://dx.doi.org/10.1016/S0022-2860(03)00354-5
[4]. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1-12.
http://dx.doi.org/10.1002/9780470166499.ch1
[5]. Lacroix, P. G.; Clement, R.; Nakatani, K.; Delaire, J. A.; Zyss, J.; Ledoux, I. Science 1994, 263, 658-660.
http://dx.doi.org/10.1126/science.263.5147.658
PMid:17747659
[6]. De Zea Bermudez, V.; Carlos, L. D.; Duarte, M. C.; Silva, M. M.; Silva, C. J.; Smith, M. J.; Assunc¸ M.; Alcacer, L. J. Alloys Compd. 1998, 21, 275-277.
[7]. Carlos, L. D.; Sa Ferreira, R. A.; De Zea Bermudez, V.; Ribeiro, S. J. L. Adv. Funct. Mater. 2001, 11, 2111-115.
http://dx.doi.org/10.1002/1616-3028(200104)11:2<111::AID-ADFM111>3.0.CO;2-V
[8]. Kato, Y.; Ichii, D.; Ohashi, K.; Kunugita, H.; Ema, K.; Tanaka, K.; Takahashi, T.; Kondo, T. Solid State Commun. 2003, 128, 15-18.
http://dx.doi.org/10.1016/S0038-1098(03)00626-4
[9]. El-Korashy, A.; Brik, M. G. Solid State Commun. 2005, 135, 298-303.
http://dx.doi.org/10.1016/j.ssc.2005.05.010
[10]. Ben Rhaiem, A.; Hlel, F.; Guidara, K.; Gargouri, M. J. Alloys Compd. 2008, 463, 440-445.
http://dx.doi.org/10.1016/j.jallcom.2007.09.032
[11]. Cavellec, M. R.; Albinet, C.; Greneche, J. M.; Ferey, G. J. Mater. Chem. 2001, 11, 3166-3171.
http://dx.doi.org/10.1039/b104495h
[12]. Lach, G.; Laskowski, L.; Kityk, I. V.; Kapustianyk, V.; Rudyk, V.; Shchur, Y.; Tkaczyk, S.; Swiatek, J.; Piasecki, M. J. Non-Crystalline Solid. 2007, 353, 4353-4356.
http://dx.doi.org/10.1016/j.jnoncrysol.2007.01.081
[13]. Roman, P.; Sertucha, J.; Luque, A.; Lezama, L.; Rojo, T. Polyhedron 1996, 15, 1253-1262.
http://dx.doi.org/10.1016/0277-5387(95)00386-X
[14]. Angeloni, A.; Orpen, A. G. Chem. Commun. 2001, 26, 343-344
http://dx.doi.org/10.1039/b009515j
[15]. Guckian, K. M .; Schweitzer, B. A.; Ren, R. X. F.; Sheils, C. J.; Tahmassebi, D. C.; Kool, E. T. J. Am. Chem. Soc. 2000, 122, 2213-2222.
http://dx.doi.org/10.1021/ja9934854
PMid:20865137 PMCid:2943206
[16]. Janiak, C. J. Chem. Soc. Dalton Trans. 2000, 7, 3885-3896
http://dx.doi.org/10.1039/b003010o
[17]. Muller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143-167.
http://dx.doi.org/10.1021/cr9900331
PMid:11749236
[18]. Hiroyuki, H.; Mashiyama, H.; Koshiji, N. Acta Cryst. B. 1989, 45, 467-473.
http://dx.doi.org/10.1107/S0108768189006981
[19]. Muller, E. A.; Cannon, R. J.; Sarjeant, A. N.; Ok, K. M.; Halasyamani, P. S.; Norquist, A. J. Cryst. Growth Des. 2005, 5, 1913-1917.
http://dx.doi.org/10.1021/cg050184z
[20]. Nonius, Kappa CCD Program Software, Nonius BV, Delft, The Netherlands, 1998.
[21]. Farrugia, L. J. J. Appl. Cystallogr. 1999, 32, 837-838.
http://dx.doi.org/10.1107/S0021889899006020
[22]. Sheldrick, G. M. SHELXS-97 Programs for Crystal Solution. University of Gottingen, Germany, 1997.
PMCid:20809
[23]. Sheldrick, G. M. SHELXL-97 Programs for Crystal Structure Refinement. University of Gottingen, Germany, 1997.
PMCid:20809
[24]. Herringer, S. N.; Turnbull, M. M.; Landee, C. P.; Wikaira, J. L. J. Coord. Chem. 2009, 62, 863-875.
http://dx.doi.org/10.1080/00958970802395604
[25]. Luque, A.; Sertucha, J.; Castillo, O.; Roman, P. New. J. Chem. 2001, 25, 1208-1214.
http://dx.doi.org/10.1039/b104085p
[26]. Luque, A.; Sertucha, J.; Lezama, L.; Rojo, T.; Roman, P. J. Chem. Soc. Dalton Trans. 1997, 5, 847-854.
http://dx.doi.org/10.1039/a606429i
[27]. Al-Far, A. R. H.; Haddad, S. F. Acta Cryst. E 2008, 64, 689-690.
http://dx.doi.org/10.1107/S1600536808010647
PMid:21202225 PMCid:2961314
[28]. Haddad, S. F.; AlDamen, M. A.; Willett, R. D. Inorg. Chim. Acta. 2006, 359, 424-432.
http://dx.doi.org/10.1016/j.ica.2005.05.039
[29]. Hafiz, A. A. Iran J. Chem. Soc. 2008, 5, 106-114.
[30]. Gosniowska, M.; Ciunik, Z.; Bator, G.; Jakubas, R.; Baran, J. J. Mol. Struct. 2000, 555, 243-255.
http://dx.doi.org/10.1016/S0022-2860(00)00607-4
[31]. Karbowiak, M.; Hanuza, J.; Janczak, J.; Drozdzynski, J. J. Alloys Compd. 1995, 225, 338-343.
http://dx.doi.org/10.1016/0925-8388(94)07117-9
[32]. Hedderich, H. G.; Blom, C. E. J. Chem. Phys. 1989, 90, 4660-4663.
[33]. Hedderich, H. G.; Blom, C. E. J. Mol. Spectrosc. 1990, 140, 103-106.
http://dx.doi.org/10.1016/0022-2852(90)90009-F
[34]. Kirkwood, A. D.; Bier, K. D.; Thompson, J. K.; Haslett, T. L.; Hubber, A. S.; Moskovits, M. J. Phys. Chem. 1991, 95, 2644-2652.
http://dx.doi.org/10.1021/j100160a006
[35]. Bellamy, L. J. The Infrared Spectra of Complex Molecules, 3rd ed., Vol. I and II, Chapman and Hall, London, 1975, 1980.
Supporting information
The Supplementary Material for this article can be found online at: Supplementary files
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.4.2.117-120.738

















European Journal of Chemistry 2013, 4(2), 117-120 | doi: https://doi.org/10.5155/eurjchem.4.2.117-120.738 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.