European Journal of Chemistry 2013, 4(2), 117-120 | doi: https://doi.org/10.5155/eurjchem.4.2.117-120.738 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6


Ikram Dhouib (1,*) , Philippe Guionneau (2) , Stanislav Pechev (3) , Tahar Mhiri (4) , Zakaria Elaoud (5)

(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(5) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(*) Corresponding Author

Received: 17 Jan 2013 | Accepted: 23 Jan 2013 | Published: 30 Jun 2013 | Issue Date: June 2013

Abstract


Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.

4_2_117_120

Keywords


Single crystal; Copper(II) complex; Spectroscopic study; Tetrapropylammonium; Hexachlorodicuprate(II); Crystal structure analysis

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.4.2.117-120.738

Links for Article


| | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 807 times | PDF Article downloaded 1522 times


Citations

/


[1]. A. Oueslati, M. Gargouri
Studies on structural, electrical, and transport properties of [(C3H7)4N]2Cu2Br6 compound
Journal of Alloys and Compounds  739, 1089, 2018
DOI: 10.1016/j.jallcom.2017.12.277
/


[2]. Ikram Dhouib, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2
European Journal of Chemistry  5(3), 388, 2014
DOI: 10.5155/eurjchem.5.3.388-393.1038
/


[3]. F. Lambarki, A. Ouasri, A. Rhandour, M. Saadi, L. El Ammari, L. Hajji
Structural, vibrational and electrical studies of tetramethylammonium trichloromercurate [(CH3)4N]HgCl3
Journal of Molecular Structure  1173, 865, 2018
DOI: 10.1016/j.molstruc.2018.07.051
/


[4]. Ikram Dhouib, Habib Feki, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
Structural, vibrational and thermal studies of a new nonlinear optical crystal tetrapropylammonium dihydrogenmonoarsenate bis arsenic acid
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy  131, 274, 2014
DOI: 10.1016/j.saa.2014.04.120
/


References

[1]. Braga, D.; Desiraju, G. R.; Miller, J. S.; Orpen, A. G.; Price, S. L. Cryst. Eng. Commun. 2002, 4, 500-509.
http://dx.doi.org/10.1039/b207466b

[2]. Desiraju, G. R. Angew. Chem. Int. Ed. Engl. 1995, 34, 2311-2327.
http://dx.doi.org/10.1002/anie.199523111

[3]. Desiraju, G. R. J. Mol. Struct. 2003, 656, 5-15.
http://dx.doi.org/10.1016/S0022-2860(03)00354-5

[4]. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1-12.
http://dx.doi.org/10.1002/9780470166499.ch1

[5]. Lacroix, P. G.; Clement, R.; Nakatani, K.; Delaire, J. A.; Zyss, J.; Ledoux, I. Science 1994, 263, 658-660.
http://dx.doi.org/10.1126/science.263.5147.658
PMid:17747659

[6]. De Zea Bermudez, V.; Carlos, L. D.; Duarte, M. C.; Silva, M. M.; Silva, C. J.; Smith, M. J.; Assunc¸ M.; Alcacer, L. J. Alloys Compd. 1998, 21, 275-277.

[7]. Carlos, L. D.; Sa Ferreira, R. A.; De Zea Bermudez, V.; Ribeiro, S. J. L. Adv. Funct. Mater. 2001, 11, 2111-115.
http://dx.doi.org/10.1002/1616-3028(200104)11:2<111::AID-ADFM111>3.0.CO;2-V

[8]. Kato, Y.; Ichii, D.; Ohashi, K.; Kunugita, H.; Ema, K.; Tanaka, K.; Takahashi, T.; Kondo, T. Solid State Commun. 2003, 128, 15-18.
http://dx.doi.org/10.1016/S0038-1098(03)00626-4

[9]. El-Korashy, A.; Brik, M. G. Solid State Commun. 2005, 135, 298-303.
http://dx.doi.org/10.1016/j.ssc.2005.05.010

[10]. Ben Rhaiem, A.; Hlel, F.; Guidara, K.; Gargouri, M. J. Alloys Compd. 2008, 463, 440-445.
http://dx.doi.org/10.1016/j.jallcom.2007.09.032

[11]. Cavellec, M. R.; Albinet, C.; Greneche, J. M.; Ferey, G. J. Mater. Chem. 2001, 11, 3166-3171.
http://dx.doi.org/10.1039/b104495h

[12]. Lach, G.; Laskowski, L.; Kityk, I. V.; Kapustianyk, V.; Rudyk, V.; Shchur, Y.; Tkaczyk, S.; Swiatek, J.; Piasecki, M. J. Non-Crystalline Solid. 2007, 353, 4353-4356.
http://dx.doi.org/10.1016/j.jnoncrysol.2007.01.081

[13]. Roman, P.; Sertucha, J.; Luque, A.; Lezama, L.; Rojo, T. Polyhedron 1996, 15, 1253-1262.
http://dx.doi.org/10.1016/0277-5387(95)00386-X

[14]. Angeloni, A.; Orpen, A. G. Chem. Commun. 2001, 26, 343-344
http://dx.doi.org/10.1039/b009515j

[15]. Guckian, K. M .; Schweitzer, B. A.; Ren, R. X. F.; Sheils, C. J.; Tahmassebi, D. C.; Kool, E. T. J. Am. Chem. Soc. 2000, 122, 2213-2222.
http://dx.doi.org/10.1021/ja9934854
PMid:20865137 PMCid:2943206

[16]. Janiak, C. J. Chem. Soc. Dalton Trans. 2000, 7, 3885-3896
http://dx.doi.org/10.1039/b003010o

[17]. Muller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143-167.
http://dx.doi.org/10.1021/cr9900331
PMid:11749236

[18]. Hiroyuki, H.; Mashiyama, H.; Koshiji, N. Acta Cryst. B. 1989, 45, 467-473.
http://dx.doi.org/10.1107/S0108768189006981

[19]. Muller, E. A.; Cannon, R. J.; Sarjeant, A. N.; Ok, K. M.; Halasyamani, P. S.; Norquist, A. J. Cryst. Growth Des. 2005, 5, 1913-1917.
http://dx.doi.org/10.1021/cg050184z

[20]. Nonius, Kappa CCD Program Software, Nonius BV, Delft, The Netherlands, 1998.

[21]. Farrugia, L. J. J. Appl. Cystallogr. 1999, 32, 837-838.
http://dx.doi.org/10.1107/S0021889899006020

[22]. Sheldrick, G. M. SHELXS-97 Programs for Crystal Solution. University of Gottingen, Germany, 1997.
PMCid:20809

[23]. Sheldrick, G. M. SHELXL-97 Programs for Crystal Structure Refinement. University of Gottingen, Germany, 1997.
PMCid:20809

[24]. Herringer, S. N.; Turnbull, M. M.; Landee, C. P.; Wikaira, J. L. J. Coord. Chem. 2009, 62, 863-875.
http://dx.doi.org/10.1080/00958970802395604

[25]. Luque, A.; Sertucha, J.; Castillo, O.; Roman, P. New. J. Chem. 2001, 25, 1208-1214.
http://dx.doi.org/10.1039/b104085p

[26]. Luque, A.; Sertucha, J.; Lezama, L.; Rojo, T.; Roman, P. J. Chem. Soc. Dalton Trans. 1997, 5, 847-854.
http://dx.doi.org/10.1039/a606429i

[27]. Al-Far, A. R. H.; Haddad, S. F. Acta Cryst. E 2008, 64, 689-690.
http://dx.doi.org/10.1107/S1600536808010647
PMid:21202225 PMCid:2961314

[28]. Haddad, S. F.; AlDamen, M. A.; Willett, R. D. Inorg. Chim. Acta. 2006, 359, 424-432.
http://dx.doi.org/10.1016/j.ica.2005.05.039

[29]. Hafiz, A. A. Iran J. Chem. Soc. 2008, 5, 106-114.

[30]. Gosniowska, M.; Ciunik, Z.; Bator, G.; Jakubas, R.; Baran, J. J. Mol. Struct. 2000, 555, 243-255.
http://dx.doi.org/10.1016/S0022-2860(00)00607-4

[31]. Karbowiak, M.; Hanuza, J.; Janczak, J.; Drozdzynski, J. J. Alloys Compd. 1995, 225, 338-343.
http://dx.doi.org/10.1016/0925-8388(94)07117-9

[32]. Hedderich, H. G.; Blom, C. E. J. Chem. Phys. 1989, 90, 4660-4663.

[33]. Hedderich, H. G.; Blom, C. E. J. Mol. Spectrosc. 1990, 140, 103-106.
http://dx.doi.org/10.1016/0022-2852(90)90009-F

[34]. Kirkwood, A. D.; Bier, K. D.; Thompson, J. K.; Haslett, T. L.; Hubber, A. S.; Moskovits, M. J. Phys. Chem. 1991, 95, 2644-2652.
http://dx.doi.org/10.1021/j100160a006

[35]. Bellamy, L. J. The Infrared Spectra of Complex Molecules, 3rd ed., Vol. I and II, Chapman and Hall, London, 1975, 1980.

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I., Guionneau, P., Pechev, S., Mhiri, T., & Elaoud, Z. (2013). Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. European Journal of Chemistry, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, Ikram, Philippe Guionneau, Stanislav Pechev, Tahar Mhiri, & Zakaria Elaoud. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6." European Journal of Chemistry [Online], 4.2 (2013): 117-120. Web. 28 Mar. 2020
Dhouib, Ikram, Guionneau, Philippe, Pechev, Stanislav, Mhiri, Tahar, AND Elaoud, Zakaria. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

DOI Link: https://doi.org/10.5155/eurjchem.4.2.117-120.738

| | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2013, 4(2), 117-120 | doi: https://doi.org/10.5155/eurjchem.4.2.117-120.738 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort