European Journal of Chemistry 2013, 4(2), 117-120 | doi: https://doi.org/10.5155/eurjchem.4.2.117-120.738 | Get rights and content

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Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6


Ikram Dhouib (1,*) , Philippe Guionneau (2) , Stanislav Pechev (3) , Tahar Mhiri (4) , Zakaria Elaoud (5)

(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(5) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisie
(*) Corresponding Author

Received: 17 Jan 2013 | Accepted: 23 Jan 2013 | Published: 30 Jun 2013 | Issue Date: June 2013

Abstract


Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.

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Keywords


Single crystal; Copper(II) complex; Spectroscopic study; Tetrapropylammonium; Hexachlorodicuprate(II); Crystal structure analysis

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DOI: 10.5155/eurjchem.4.2.117-120.738

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Citations

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[1]. A. Oueslati, M. Gargouri
Studies on structural, electrical, and transport properties of [(C3H7)4N]2Cu2Br6 compound
Journal of Alloys and Compounds  739, 1089, 2018
DOI: 10.1016/j.jallcom.2017.12.277
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[2]. Ikram Dhouib, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2
European Journal of Chemistry  5(3), 388, 2014
DOI: 10.5155/eurjchem.5.3.388-393.1038
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[3]. F. Lambarki, A. Ouasri, A. Rhandour, M. Saadi, L. El Ammari, L. Hajji
Structural, vibrational and electrical studies of tetramethylammonium trichloromercurate [(CH3)4N]HgCl3
Journal of Molecular Structure  1173, 865, 2018
DOI: 10.1016/j.molstruc.2018.07.051
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[4]. Ikram Dhouib, Habib Feki, Philippe Guionneau, Tahar Mhiri, Zakaria Elaoud
Structural, vibrational and thermal studies of a new nonlinear optical crystal tetrapropylammonium dihydrogenmonoarsenate bis arsenic acid
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy  131, 274, 2014
DOI: 10.1016/j.saa.2014.04.120
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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. Eur. J. Chem. 2013, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, I., Guionneau, P., Pechev, S., Mhiri, T., & Elaoud, Z. (2013). Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. European Journal of Chemistry, 4(2), 117-120. doi:10.5155/eurjchem.4.2.117-120.738
Dhouib, Ikram, Philippe Guionneau, Stanislav Pechev, Tahar Mhiri, & Zakaria Elaoud. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6." European Journal of Chemistry [Online], 4.2 (2013): 117-120. Web. 3 Jun. 2023
Dhouib, Ikram, Guionneau, Philippe, Pechev, Stanislav, Mhiri, Tahar, AND Elaoud, Zakaria. "Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6" European Journal of Chemistry [Online], Volume 4 Number 2 (30 June 2013)

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