European Journal of Chemistry

Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate



Main Article Content

Adel Abbas Ahmed Emara
Ali Mahmoud Taha
Mahmood Mohamed Mashaly
Omima Mohamed Ibrahim Adly

Abstract

New series of copper(II), nickel(II), cobalt(II), zinc(II), cadmium(II), iron(III) and oxovanadium(IV) complexes of hydrazone, H3L, ligand derived from the condensation of S-methyldithiocarbazate and 4,6-diacetylresorcinol, in the molar ratio 1:1, has been synthesized. All the metal complexes are dimmers. The structures of the ligand and its transition metal complexes were characterized by elemental analyses, spectral (Infrared, electronic, Mass, 1H NMR and ESR) data and magnetic susceptibility, molar conductivity measurements and thermal gravimetric analysis. The structure of the ligand is dibasic tridentate with ONS sites. The bonding sites, in all cases, are the azomethine nitrogen, phenolic oxygen and thiol sulfur atoms, as illustrated from the spectral data. The metal complexes exhibit different geometrical arrangements such as square planar, tetrahedral, square pyramidal and octahedral arrangements. Kinetic parameters (DG, DH, DS and DE) of the metal complexes were calculated from the thermal behaviour of the metal complexes using Coats-Redfern method. The ligand and its metal complexes were screened for its antimicrobial activity against Staphylococcus aureus and Staphylococcus pyogenes as Gram-positive bacteria, Pseudomonas phaseolicola and Pseudomonas fluorescens as Gram-negative bacteria and the fungi Fusarium oxysporum and Aspergillus fumigatus.


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Emara, A. A. A.; Taha, A. M.; Mashaly, M. M.; Adly, O. M. I. Synthesis, Spectroscopic, Thermal and Anti-Microbial Studies of Transition Metal Complexes of Hydrazone Derived from 4,6-Diacetylresorcinol and S-Methyldithiocarbazate. Eur. J. Chem. 2015, 6, 107-116.

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References

[1]. Casas, J. S.; Castellans, E. E.; Louce, M. D.; Ellena, J.; Sanchez, A.; Sordo, J.; Tabeada, C. J. Inorg. Biochem. 2006, 100(11), 1858-1860.
http://dx.doi.org/10.1016/j.jinorgbio.2006.07.006

[2]. Tain, Y. P.; Duan, C. Y.; Lu, Z. L.; You, X. Z.; Fun, H. K.; Kandasamy, S. Polyhedron 1996, 15(13), 2263-2271.
http://dx.doi.org/10.1016/0277-5387(95)00477-7

[3]. Rodrigues, M. C.; Pinelli, S. J. J. Inorg. Biochem. 1995, 58(3), 157-175.
http://dx.doi.org/10.1016/0162-0134(94)00043-A

[4]. Ferrari, M. B.; Fava, G. G.; Tarasconi, G.; Albertini, R.; Pinelli, S. J.; Starcich, R. J. Inorg. Biochem. 1994, 53(1), 13-25.
http://dx.doi.org/10.1016/0162-0134(94)80017-0

[5]. Reper, E. S. Coord. Chem. Rev. 1985, 61, 115-148.
http://dx.doi.org/10.1016/0010-8545(85)80004-7

[6]. Padhye, S. B.; Kanffman, G. B. Coord. Chem. Rev. 1985, 63, 127-160.
http://dx.doi.org/10.1016/0010-8545(85)80022-9

[7]. Tofazzal, M.; Tarafder, H.; Ali, M. A.; Saravanan, N.; Weng, W. Y.; Kumar, S.; Tsafe, N. U.; Crouse, K. A. Trans. Met. Chem. 2000, 25(3), 295-298.
http://dx.doi.org/10.1023/A:1007044910814

[8]. Liu, Z. H.; Duan, C. Y.; Hu, J. Inorg. Chem. 1999, 38(8), 1719-1724.
http://dx.doi.org/10.1021/ic9711731

[9]. Liu, Z. H.; Yang, S. R.; Duan, C. Y.; You, X. Z. Chem. Lett. Jpn. 1999, 10, 1063-1069.
http://dx.doi.org/10.1246/cl.1999.1063

[10]. Tain, Y. P.; Duan, C. Y.; Zhao, C. U.; You, X. Z.; Mak, T. C. W.; Zhang, Z. Inorg. Chem. 1997, 36(6), 1247-1252.

[11]. Taha, A.; Emara, A. A. A.; Mashaly, M. M.; Adly, O. M. I. Spectrochim. Acta A 2014, 130, 429-439.
http://dx.doi.org/10.1016/j.saa.2014.04.007

[12]. Abu-Raabah, A.; Davies, G.; El-sayed, M. A.; El-Toukhy, A.; Shaikh, S. N.; Zubieta, J. Inorg. Chim. Acta 1992, 193, 43-56.

[13]. Chan, M. H. E.; Crouse, K. A.; Tahir, M. I. M.; Rosli, R.; Tsafe, N. U.; Cowley, A. R. Polyhedron 2008, 27(4), 1141-1149.
http://dx.doi.org/10.1016/j.poly.2007.11.035

[14]. Lobana, T. Proc. Indian Acad. Sci. (Chem. Sci.) 2000, 112(3), 323-329.
http://dx.doi.org/10.1007/BF02706181

[15]. Ali, M. A.; Nazimuddin, M.; Shaha, R.; Butcher, R. J.; Bryan, J. C. Polyhedron 1998, 17(22), 3955-3961.
http://dx.doi.org/10.1016/S0277-5387(98)00189-2

[16]. Hossain, M. E.; Alam, M. N.; Ali, M. A.; Nazimuddin, M.; Smith, F. E.; Hynes, R. C. Polyhedron 1996, 150(5-6), 973-980.
http://dx.doi.org/10.1016/0277-5387(95)00310-X

[17]. West, D. X.; Liberta, A. E.; Padhye, S. B.; Chilate, R. C.; Sonawane, P. B.; Kumbhar, A. S.; Yerande, R. G. Coord. Chem. Rev. 1993, 123, 49-71.
http://dx.doi.org/10.1016/0010-8545(93)85052-6

[18]. Ali, M. A.; Haroon, C. M.; Nazimuddin, M.; Majumder, S. M. M. Trans. Met. Chem. 1992, 17(2), 133-136.
http://dx.doi.org/10.1007/BF02910804

[19]. Jain, S. K.; Garg, B. S.; Boon, Y. K.; Scovill, J. P.; Klayman, D. L. Spectrochim. Acta A 1985, 41(3), 407-413.
http://dx.doi.org/10.1016/0584-8539(85)80145-8

[20]. Campbell, M. J. Coord. Chem. Rev. 1975, 15, 279-319.
http://dx.doi.org/10.1016/S0010-8545(00)80276-3

[21]. Chew, K. B.; Tarafder, M. T. H.; Crouse, K. A.; Ali, A. M.; Yamin, B. M.; Fun, H. K. Polyhedron 2004, 23(8), 1385-1392.
http://dx.doi.org/10.1016/j.poly.2004.02.018

[22]. Emara, A. A. A.; Abou-Hussen, A. A. A. Spectrochim. Acta A 2006, 64(4), 1010-1024.
http://dx.doi.org/10.1016/j.saa.2005.09.010

[23]. Emara, A. A. A.; Saleh, A. A.; Adly, O. M. I. Spectrochim. Acta A 2007, 68(3), 592-604.
http://dx.doi.org/10.1016/j.saa.2006.12.034

[24]. Flaschka, H. A. EDTA Titration, 2nd ed. Pergamon Press: New York, 1964, 81-86.

[25]. Vogel, A. I. Textbook of Quantitative Inorganic Analysis, 4th ed. Longman: London, 1978.

[26]. West, T. S. Complexometry with EDTA and Related Reagents, 3rd ed. DBH Ltd., Pools: New York, 1969.

[27]. Mabbs, F. E.; Machin, D. J. Magnitism and Transition Metal Complexes, Dover Publications: New York, 2008.

[28]. Gross, D. C.; De Vay, S. E. Physiol. Plant Pathol. 1977, 11, 13-28.
http://dx.doi.org/10.1016/0048-4059(77)90083-2

[29]. Bauer, A. W.; Kirby, W. W. M.; Sherris, J. C.; Turck, M. Am. J. Clin. Pathol. 1966, 45(4), 493-496.

[30]. Ali, M. A.; Mirza, A. H.; Hamid, M. H. S. A.; Bernhardt, P. V. Polyhedron 2005, 24 (3), 383-390.
http://dx.doi.org/10.1016/j.poly.2004.11.023

[31]. Ali, M. A.; Mirza, A. H.; Ravoof, T. B. S. A.; Bernhardt, P. V. Polyhedron 2004, 23(18), 2031-2036

[32]. Ali, M. A.; Mirza, A. H.; Nazimuddin, M.; Ahmed, R.; Gahan, L. H.; Bernhardt, P. V. Polyhedron 2003, 22(27), 3433-3438.
http://dx.doi.org/10.1016/j.poly.2003.08.004

[33]. Emara, A. A. A.; El-sayed, B. A.; Ahmed, E. A. E. Spectrochim. Acta A 2007, 69(3), 757-769.
http://dx.doi.org/10.1016/j.saa.2007.05.028

[34]. Emara, A. A. A.; Seleem, H. S.; Madyan, A. M. J. Coord. Chem. 2009, 62(15), 2569-2582.
http://dx.doi.org/10.1080/00958970902866538

[35]. Emara, A. A. A.; El-Sayed, B. A.; Ahmed, E. A. E. Spectrochim. Acta A 2008, 69(3), 757-769.
http://dx.doi.org/10.1016/j.saa.2007.05.028

[36]. Adly, O. M. I.; Emara, A. A. A. Spectrochim. Acta A 2014, 132(1), 91-101.
http://dx.doi.org/10.1016/j.saa.2014.04.118

[37]. Pretsch, E.; Seibl, J. Tables of Spectral Data for Structure Determination of Organic Compounds, Springer-Verlag: Berlin, 1983.
http://dx.doi.org/10.1007/978-3-662-22455-7

[38]. Abou-Husse,n A. A. A.; Emara, A. A. A. J. Coord. Chem. 2004, 57(11), 973-987.

[39]. Emara, A. A. A. Spectrochim. Acta A 2010, 77(1), 117-125.
http://dx.doi.org/10.1016/j.saa.2010.04.036

[40]. Roy, S.; Mandal, T. N.; Barik, A. K.; Pal, S.; Gupta, S.; Hazra, A.; Butcher, R. J.; Hunter, A. D.; Zeller, M.; Kar, S. K. Polyhedron 2007, 26(12), 2603-2611.
http://dx.doi.org/10.1016/j.poly.2007.01.006

[41]. Khalil, S. M. E.; Emara, A. A. A. J. Coord. Chem. 2002, 55(1), 17-32.
http://dx.doi.org/10.1080/00958970211871

[42]. El-Sayed, B. A.; Abo Aly, M. M.; Emarly, A. A. A.; Khalily, S. M. E. Vibr. Spectrosc. 2002, 30, 93-100.
http://dx.doi.org/10.1016/S0924-2031(02)00043-7

[43]. Adlly, O. M. I.; Tahly, A. J. Mol. Str. 2013, 1038, 250-259.
http://dx.doi.org/10.1016/j.molstruc.2013.01.035

[44]. Nakamotly, K. Infrared Spectra of Inorganic and Coordination Compounds, 5th ed. John Willey & Sons: New York, 1997.

[45]. Adlly, O. M. I. Spectrochim. Acta A 2011, 79(5), 1295-1303.
http://dx.doi.org/10.1016/j.saa.2011.04.058

[46]. Greenwooly, N. N. Earnshaly, A.; Chemistry of the Elements, Pergamon Press: New York, 1984.

[47]. Kannappaly, R.; Tanalye, S.; Mutikainen, I.; Turpeinen, U.; Reedijk, J. Inorg. Chem. Acta 2005, 358(2), 383-388.

[48]. Ali, M. A.; Bose, R. N. Polyhedron 1984, 3(5), 517-522.
http://dx.doi.org/10.1016/S0277-5387(00)88081-X

[49]. Goodgame, M.; Goodgame, D. M. L.; Cotton, F. A. J. Am. Chem. Soc. 1961, 83(20), 4161-4167.
http://dx.doi.org/10.1021/ja01481a014

[50]. Cotton, F. A.; Wilkinson G. Advanced Inorganic Chemistry, A Comprehensive Text, 4th ed. John Wiley & Sons: New York, 1986.

[51]. Bailar, J. C.; Emeleus, H. J.; Nyholm, R.; Trotman-Dickenson, A. F. Comprehensive Inorganic Chemistry, Vol. 3. Pergamon Press: New York, 1975.

[52]. Lever, A. B. P. Inorganic Electronic Spectroscopy, 2nd ed. Elsevier: Amsterdam, 1997.

[53]. Emara, A. A. A.; Adly, O. M. I. Trans. Met. Chem. 2007, 32(7), 889-901.
http://dx.doi.org/10.1007/s11243-007-0245-z

[54]. Geary, W. J. Coord. Chem. Rev. 1971, 7(1), 81-122.
http://dx.doi.org/10.1016/S0010-8545(00)80009-0

[55]. El-Ayaan, U.; Gabr, I. M. Spectrochim. Acta A 2007, 67(1), 263-272.
http://dx.doi.org/10.1016/j.saa.2006.07.012

[56]. Al-Ayaan, U.; El-Metwally, N. M.; Youssef, M. M.; El-Bialy, S. A. A. Spectrochim. Acta A 2007, 68(5), 1278-1286.
http://dx.doi.org/10.1016/j.saa.2007.02.011

[57]. Kaim, W. Schwederski B. Bioinorganic Chemistry: Inorganic Elements in the Chemistry of life, John Wiley & Sons: New York, 1994.

[58]. Ibrahim, M. A.; El-Mahdy, K. M. Phosphorus, Sulfur and Silicon 2009, 184(11), 2945-2958.
http://dx.doi.org/10.1080/10426500802625594

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