Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Synthesis, spectroscopic, thermal and anti-microbial studies of transition metal complexes of hydrazone derived from 4,6-diacetylresorcinol and S-methyldithiocarbazate
Adel Abbas Ahmed Emara (1,*)
, Ali Mahmoud Taha (2) , Mahmood Mohamed Mashaly (3) , Omima Mohamed Ibrahim Adly (4) (1) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(2) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(3) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(4) Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, Cairo, 11711, Egypt
(*) Corresponding Author
Received: 26 Sep 2014 | Revised: 30 Oct 2014 | Accepted: 31 Oct 2014 | Published: 30 Jun 2015 | Issue Date: June 2015
Abstract
New series of copper(II), nickel(II), cobalt(II), zinc(II), cadmium(II), iron(III) and oxovanadium(IV) complexes of hydrazone, H3L, ligand derived from the condensation of S-methyldithiocarbazate and 4,6-diacetylresorcinol, in the molar ratio 1:1, has been synthesized. All the metal complexes are dimmers. The structures of the ligand and its transition metal complexes were characterized by elemental analyses, spectral (Infrared, electronic, Mass, 1H NMR and ESR) data and magnetic susceptibility, molar conductivity measurements and thermal gravimetric analysis. The structure of the ligand is dibasic tridentate with ONS sites. The bonding sites, in all cases, are the azomethine nitrogen, phenolic oxygen and thiol sulfur atoms, as illustrated from the spectral data. The metal complexes exhibit different geometrical arrangements such as square planar, tetrahedral, square pyramidal and octahedral arrangements. Kinetic parameters (DG, DH, DS and DE) of the metal complexes were calculated from the thermal behaviour of the metal complexes using Coats-Redfern method. The ligand and its metal complexes were screened for its antimicrobial activity against Staphylococcus aureus and Staphylococcus pyogenes as Gram-positive bacteria, Pseudomonas phaseolicola and Pseudomonas fluorescens as Gram-negative bacteria and the fungi Fusarium oxysporum and Aspergillus fumigatus.
Announcements
Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.
1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).
2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).
3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.6.2.107-116.1162
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 1728 times |
PDF Article downloaded 649 times
Citations
[1]. Mannar R. Maurya, Lata Rana, Fernando Avecilla
Phloroglucinol and resorcinol based mononuclear dioxidomolybdenum(VI) complexes: Synthesis, structural characterization and catalytic epoxidation
Polyhedron 126, 60, 2017
DOI: 10.1016/j.poly.2017.01.006
[2]. Magdy Shebl
Coordination behavior of new bis(tridentate ONO, ONS and ONN) donor hydrazones towards some transition metal ions: Synthesis, spectral, thermal, antimicrobial and antitumor studies
Journal of Molecular Structure 1128, 79, 2017
DOI: 10.1016/j.molstruc.2016.08.056
References
[1]. Casas, J. S.; Castellans, E. E.; Louce, M. D.; Ellena, J.; Sanchez, A.; Sordo, J.; Tabeada, C. J. Inorg. Biochem. 2006, 100(11), 1858-1860.
http://dx.doi.org/10.1016/j.jinorgbio.2006.07.006
[2]. Tain, Y. P.; Duan, C. Y.; Lu, Z. L.; You, X. Z.; Fun, H. K.; Kandasamy, S. Polyhedron 1996, 15(13), 2263-2271.
http://dx.doi.org/10.1016/0277-5387(95)00477-7
[3]. Rodrigues, M. C.; Pinelli, S. J. J. Inorg. Biochem. 1995, 58(3), 157-175.
http://dx.doi.org/10.1016/0162-0134(94)00043-A
[4]. Ferrari, M. B.; Fava, G. G.; Tarasconi, G.; Albertini, R.; Pinelli, S. J.; Starcich, R. J. Inorg. Biochem. 1994, 53(1), 13-25.
http://dx.doi.org/10.1016/0162-0134(94)80017-0
[5]. Reper, E. S. Coord. Chem. Rev. 1985, 61, 115-148.
http://dx.doi.org/10.1016/0010-8545(85)80004-7
[6]. Padhye, S. B.; Kanffman, G. B. Coord. Chem. Rev. 1985, 63, 127-160.
http://dx.doi.org/10.1016/0010-8545(85)80022-9
[7]. Tofazzal, M.; Tarafder, H.; Ali, M. A.; Saravanan, N.; Weng, W. Y.; Kumar, S.; Tsafe, N. U.; Crouse, K. A. Trans. Met. Chem. 2000, 25(3), 295-298.
http://dx.doi.org/10.1023/A:1007044910814
[8]. Liu, Z. H.; Duan, C. Y.; Hu, J. Inorg. Chem. 1999, 38(8), 1719-1724.
http://dx.doi.org/10.1021/ic9711731
[9]. Liu, Z. H.; Yang, S. R.; Duan, C. Y.; You, X. Z. Chem. Lett. Jpn. 1999, 10, 1063-1069.
http://dx.doi.org/10.1246/cl.1999.1063
[10]. Tain, Y. P.; Duan, C. Y.; Zhao, C. U.; You, X. Z.; Mak, T. C. W.; Zhang, Z. Inorg. Chem. 1997, 36(6), 1247-1252.
[11]. Taha, A.; Emara, A. A. A.; Mashaly, M. M.; Adly, O. M. I. Spectrochim. Acta A 2014, 130, 429-439.
http://dx.doi.org/10.1016/j.saa.2014.04.007
[12]. Abu-Raabah, A.; Davies, G.; El-sayed, M. A.; El-Toukhy, A.; Shaikh, S. N.; Zubieta, J. Inorg. Chim. Acta 1992, 193, 43-56.
[13]. Chan, M. H. E.; Crouse, K. A.; Tahir, M. I. M.; Rosli, R.; Tsafe, N. U.; Cowley, A. R. Polyhedron 2008, 27(4), 1141-1149.
http://dx.doi.org/10.1016/j.poly.2007.11.035
[14]. Lobana, T. Proc. Indian Acad. Sci. (Chem. Sci.) 2000, 112(3), 323-329.
http://dx.doi.org/10.1007/BF02706181
[15]. Ali, M. A.; Nazimuddin, M.; Shaha, R.; Butcher, R. J.; Bryan, J. C. Polyhedron 1998, 17(22), 3955-3961.
http://dx.doi.org/10.1016/S0277-5387(98)00189-2
[16]. Hossain, M. E.; Alam, M. N.; Ali, M. A.; Nazimuddin, M.; Smith, F. E.; Hynes, R. C. Polyhedron 1996, 150(5-6), 973-980.
http://dx.doi.org/10.1016/0277-5387(95)00310-X
[17]. West, D. X.; Liberta, A. E.; Padhye, S. B.; Chilate, R. C.; Sonawane, P. B.; Kumbhar, A. S.; Yerande, R. G. Coord. Chem. Rev. 1993, 123, 49-71.
http://dx.doi.org/10.1016/0010-8545(93)85052-6
[18]. Ali, M. A.; Haroon, C. M.; Nazimuddin, M.; Majumder, S. M. M. Trans. Met. Chem. 1992, 17(2), 133-136.
http://dx.doi.org/10.1007/BF02910804
[19]. Jain, S. K.; Garg, B. S.; Boon, Y. K.; Scovill, J. P.; Klayman, D. L. Spectrochim. Acta A 1985, 41(3), 407-413.
http://dx.doi.org/10.1016/0584-8539(85)80145-8
[20]. Campbell, M. J. Coord. Chem. Rev. 1975, 15, 279-319.
http://dx.doi.org/10.1016/S0010-8545(00)80276-3
[21]. Chew, K. B.; Tarafder, M. T. H.; Crouse, K. A.; Ali, A. M.; Yamin, B. M.; Fun, H. K. Polyhedron 2004, 23(8), 1385-1392.
http://dx.doi.org/10.1016/j.poly.2004.02.018
[22]. Emara, A. A. A.; Abou-Hussen, A. A. A. Spectrochim. Acta A 2006, 64(4), 1010-1024.
http://dx.doi.org/10.1016/j.saa.2005.09.010
[23]. Emara, A. A. A.; Saleh, A. A.; Adly, O. M. I. Spectrochim. Acta A 2007, 68(3), 592-604.
http://dx.doi.org/10.1016/j.saa.2006.12.034
[24]. Flaschka, H. A. EDTA Titration, 2nd ed. Pergamon Press: New York, 1964, 81-86.
[25]. Vogel, A. I. Textbook of Quantitative Inorganic Analysis, 4th ed. Longman: London, 1978.
[26]. West, T. S. Complexometry with EDTA and Related Reagents, 3rd ed. DBH Ltd., Pools: New York, 1969.
[27]. Mabbs, F. E.; Machin, D. J. Magnitism and Transition Metal Complexes, Dover Publications: New York, 2008.
[28]. Gross, D. C.; De Vay, S. E. Physiol. Plant Pathol. 1977, 11, 13-28.
http://dx.doi.org/10.1016/0048-4059(77)90083-2
[29]. Bauer, A. W.; Kirby, W. W. M.; Sherris, J. C.; Turck, M. Am. J. Clin. Pathol. 1966, 45(4), 493-496.
[30]. Ali, M. A.; Mirza, A. H.; Hamid, M. H. S. A.; Bernhardt, P. V. Polyhedron 2005, 24 (3), 383-390.
http://dx.doi.org/10.1016/j.poly.2004.11.023
[31]. Ali, M. A.; Mirza, A. H.; Ravoof, T. B. S. A.; Bernhardt, P. V. Polyhedron 2004, 23(18), 2031-2036
[32]. Ali, M. A.; Mirza, A. H.; Nazimuddin, M.; Ahmed, R.; Gahan, L. H.; Bernhardt, P. V. Polyhedron 2003, 22(27), 3433-3438.
http://dx.doi.org/10.1016/j.poly.2003.08.004
[33]. Emara, A. A. A.; El-sayed, B. A.; Ahmed, E. A. E. Spectrochim. Acta A 2007, 69(3), 757-769.
http://dx.doi.org/10.1016/j.saa.2007.05.028
[34]. Emara, A. A. A.; Seleem, H. S.; Madyan, A. M. J. Coord. Chem. 2009, 62(15), 2569-2582.
http://dx.doi.org/10.1080/00958970902866538
[35]. Emara, A. A. A.; El-Sayed, B. A.; Ahmed, E. A. E. Spectrochim. Acta A 2008, 69(3), 757-769.
http://dx.doi.org/10.1016/j.saa.2007.05.028
[36]. Adly, O. M. I.; Emara, A. A. A. Spectrochim. Acta A 2014, 132(1), 91-101.
http://dx.doi.org/10.1016/j.saa.2014.04.118
[37]. Pretsch, E.; Seibl, J. Tables of Spectral Data for Structure Determination of Organic Compounds, Springer-Verlag: Berlin, 1983.
http://dx.doi.org/10.1007/978-3-662-22455-7
[38]. Abou-Husse,n A. A. A.; Emara, A. A. A. J. Coord. Chem. 2004, 57(11), 973-987.
[39]. Emara, A. A. A. Spectrochim. Acta A 2010, 77(1), 117-125.
http://dx.doi.org/10.1016/j.saa.2010.04.036
[40]. Roy, S.; Mandal, T. N.; Barik, A. K.; Pal, S.; Gupta, S.; Hazra, A.; Butcher, R. J.; Hunter, A. D.; Zeller, M.; Kar, S. K. Polyhedron 2007, 26(12), 2603-2611.
http://dx.doi.org/10.1016/j.poly.2007.01.006
[41]. Khalil, S. M. E.; Emara, A. A. A. J. Coord. Chem. 2002, 55(1), 17-32.
http://dx.doi.org/10.1080/00958970211871
[42]. El-Sayed, B. A.; Abo Aly, M. M.; Emarly, A. A. A.; Khalily, S. M. E. Vibr. Spectrosc. 2002, 30, 93-100.
http://dx.doi.org/10.1016/S0924-2031(02)00043-7
[43]. Adlly, O. M. I.; Tahly, A. J. Mol. Str. 2013, 1038, 250-259.
http://dx.doi.org/10.1016/j.molstruc.2013.01.035
[44]. Nakamotly, K. Infrared Spectra of Inorganic and Coordination Compounds, 5th ed. John Willey & Sons: New York, 1997.
[45]. Adlly, O. M. I. Spectrochim. Acta A 2011, 79(5), 1295-1303.
http://dx.doi.org/10.1016/j.saa.2011.04.058
[46]. Greenwooly, N. N. Earnshaly, A.; Chemistry of the Elements, Pergamon Press: New York, 1984.
[47]. Kannappaly, R.; Tanalye, S.; Mutikainen, I.; Turpeinen, U.; Reedijk, J. Inorg. Chem. Acta 2005, 358(2), 383-388.
[48]. Ali, M. A.; Bose, R. N. Polyhedron 1984, 3(5), 517-522.
http://dx.doi.org/10.1016/S0277-5387(00)88081-X
[49]. Goodgame, M.; Goodgame, D. M. L.; Cotton, F. A. J. Am. Chem. Soc. 1961, 83(20), 4161-4167.
http://dx.doi.org/10.1021/ja01481a014
[50]. Cotton, F. A.; Wilkinson G. Advanced Inorganic Chemistry, A Comprehensive Text, 4th ed. John Wiley & Sons: New York, 1986.
[51]. Bailar, J. C.; Emeleus, H. J.; Nyholm, R.; Trotman-Dickenson, A. F. Comprehensive Inorganic Chemistry, Vol. 3. Pergamon Press: New York, 1975.
[52]. Lever, A. B. P. Inorganic Electronic Spectroscopy, 2nd ed. Elsevier: Amsterdam, 1997.
[53]. Emara, A. A. A.; Adly, O. M. I. Trans. Met. Chem. 2007, 32(7), 889-901.
http://dx.doi.org/10.1007/s11243-007-0245-z
[54]. Geary, W. J. Coord. Chem. Rev. 1971, 7(1), 81-122.
http://dx.doi.org/10.1016/S0010-8545(00)80009-0
[55]. El-Ayaan, U.; Gabr, I. M. Spectrochim. Acta A 2007, 67(1), 263-272.
http://dx.doi.org/10.1016/j.saa.2006.07.012
[56]. Al-Ayaan, U.; El-Metwally, N. M.; Youssef, M. M.; El-Bialy, S. A. A. Spectrochim. Acta A 2007, 68(5), 1278-1286.
http://dx.doi.org/10.1016/j.saa.2007.02.011
[57]. Kaim, W. Schwederski B. Bioinorganic Chemistry: Inorganic Elements in the Chemistry of life, John Wiley & Sons: New York, 1994.
[58]. Ibrahim, M. A.; El-Mahdy, K. M. Phosphorus, Sulfur and Silicon 2009, 184(11), 2945-2958.
http://dx.doi.org/10.1080/10426500802625594
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.6.2.107-116.1162
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2015, 6(2), 107-116 | doi: https://doi.org/10.5155/eurjchem.6.2.107-116.1162 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.