European Journal of Chemistry

Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene



Main Article Content

Jabbar Saleh Hadi

Abstract

A new series of Schiff bases were synthesized by the condensation of sulfaproxylene with various aldehydes in ethanol. The structures of Schiff bases were characterized by using elemental analysis, IR, 1H NMR, 13C NMR and Mass spectrometry techniques. Thermal stability of the prepared compounds was investigated using TG and DTG. The kinetic and thermodynamic parameters such as activation energy (E), enthalpy of activation (ΔH), entropy of activation (ΔS), and Gibbs free energy change of the decomposition (ΔG) were evaluated following Coats-Redfern method. In addition, the compounds were studied for their fluorescence properties, where compound 1 yielded the strongest intensity in 1×10-4 M DMSO solution.


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Hadi, J. S. Synthesis, Characterization, Fluorescence, and Thermal Studies of a New Series of Schiff Bases Derived from Sulfaproxylene. Eur. J. Chem. 2015, 6, 404-409.

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References

[1]. Patai, S. The Chemistry of the Carbon-Nitrogen Double Bond; Science, John Wiley & Sons Ltd, London,1970.
http://dx.doi.org/10.1002/9780470771204

[2]. Maurya, M. R.; Uprety, B.; Avecilla, F.; Tariq, S.; Azam, A. Eur. J. Med. Chem. 2015, 98, 54-60.
http://dx.doi.org/10.1016/j.ejmech.2015.05.006

[3]. Masoud, M. S.; Ali, A. E.; Elasala, G. S. J. Mol. Struct. 2015, 1084, 259-273.
http://dx.doi.org/10.1016/j.molstruc.2014.11.049

[4]. Zayed, E.; Mohamed, G.; Hindy, A. M. J. Therm. Anal. Calorim. 2015, 120(1), 893-903.
http://dx.doi.org/10.1007/s10973-014-4061-3

[5]. Rathi, P.; Singh, D. P. Spectrochim. Acta A 2015, 136, 381-387.
http://dx.doi.org/10.1016/j.saa.2014.09.044

[6]. Tigineh, G. T.; Wen, Y. S.; Liu, L. K. Tetrahedron 2015, 71(1), 170-175.
http://dx.doi.org/10.1016/j.tet.2014.10.074

[7]. Sumrra, S. H.; Ibrahim, M.; Ambreen, S.; Imran, M.; Danish, M.; Rehmani, F. S. Bioinorg. Chem. Appl. 2014, 2014, 1-10.

[8]. Khan, S. A.; Asiri, A. M.; Al-Amry, K.; Malik, M. A. Sci. World J. 2014, 2014, 592375, 9.

[9]. Raghuwanshi, P. B.; Mahalle, P. V; Mahavidyalaya, B. B.; Amravati, M. S. S. Der Pharma Chem. 2014, 6(1), 262-266.

[10]. Bhanu, P. T.; Dinneswara, R. G.; Padmaja, A.; Padmavathi, V. Eur. J. Med. Chem. 2014, 82, 347-354.
http://dx.doi.org/10.1016/j.ejmech.2014.06.001

[11]. Jaman, Z.; Karim, M. R.; Dumenyo, K.; Mirza, A. H. Adv. Microb. Physiol. 2014, 4, 1140-1153.
http://dx.doi.org/10.4236/aim.2014.415124

[12]. Castelino, P. A.; Naik, P.; Dasappa, J. P.; Sujayraj, R. S.; Sharath Chandra, K.; Chaluvaiah, K.; Nair, R.; Sandya Kumari, M. V.; Kalthur, G.; Adiga, S. K. Eur. J. Med. Chem. 2014, 84, 194-199.
http://dx.doi.org/10.1016/j.ejmech.2014.06.072

[13]. Kaushal, R.; Thakur, S. Chem. Eng. Trans. 2013, 32, 1801-1806.

[14]. Hisaindee, S.; Al-Kaabi, L.; Ajeb, S.; Torky, Y.; Iratni, R.; Saleh, N.; AbuQamar, S. F. Arab. J. Chem. doi:10.1016/j.arabjc.2013.03.013.
http://dx.doi.org/10.1016/j.arabjc.2013.03.013

[15]. Hadi, J. S.; Jarallah, H. M. S. Res. J. Pharm. Biol. Chem. Sci. 2013, 4(1), 292-301.

[16]. Ahmed, R. M.; Yousif, E. I.; Hasan, H. A.; Al-Jeboori, M. J. Sci. World J. 2013, 2013, 289805, 7.

[17]. Imran, S.; Taha, M.; Ismail, N. H.; Khan, K. M.; Naz, F.; Hussain, M.; Tauseef, S. Molecules 2014, 19(8), 11722-11740.
http://dx.doi.org/10.3390/molecules190811722

[18]. Valarmathy, G.; Subbalakshmi, R.; Selvameena, R.; Gomathi, V. Orient. J. Chem. 2013, 29, 315-320.
http://dx.doi.org/10.13005/ojc/290151

[19]. Chohan, Z. H.; Shad, H.; Youssoufi, M. H.; Ben Hadda, T. S. Eur. J. Med. Chem. 2010, 45(7), 2893-2901.
http://dx.doi.org/10.1016/j.ejmech.2010.03.014

[20]. Mapari, A. K.; Hate, M. S.; Mangaonkar, K. V. E-J. Chem. 2011, 8(3), 1258-1263.

[21]. Kumar, S.; Niranjan, M. S.; Chaluvaraju, K. C.; Jamakhandi, C. M. J. Curr. Pharm. Res. 2010, 1, 39-42.

[22]. Shebl, M.; Khalil, S. M. E.; Al-Gohani, F. S. J. Mol. Struct. 2010, 980(1-3), 78-87.
http://dx.doi.org/10.1016/j.molstruc.2010.06.040

[23]. Ebrahimi, H.; Hadi, J. S.; Al-Ansari, H. S. A. J. Mol. Struct. 2013, 1039, 37-45.
http://dx.doi.org/10.1016/j.molstruc.2013.01.063

[24]. Ebrahimi, H. P.; Hadi, J. S.; Alsalim, T. A.; Ghali, T. S.; Bolandnazar, Z. Spectrochim. Acta A 2015, 137, 1067–1077.
http://dx.doi.org/10.1016/j.saa.2014.08.146

[25]. Ebrahimi, H. P.; Hadi, J. S.; Abdulnabi, Z. A.; Bolandnazar, Z. Spectrochim. Acta A 2014, 117, 485-492.
http://dx.doi.org/10.1016/j.saa.2013.08.044

[26]. Hadi, J. S.; Almayah, A. A.; Swadi, A. G. S. Res. J. Pharm. Biol. Chem. Sci. 2014, 5, 233-246.

[27]. Al-Salim, T.; Saeed, M. E. M.; Hadi, J. S.; Zeino, M.; Gany, R.; Kadioglu, O.; Titinchi, S. J. J.; Abbo, H. S.; Efferth, T. Curr. Med. Chem. 2014, 21(23), 2715-2725.
http://dx.doi.org/10.2174/0929867321666140120120708

[28]. Alsalim, T. A.; Hadi, Jabbar, S.; Al-Nasir, E. A.; Abbo, H. S.; Titinchi, S. J. Catal. Lett. 2010, 136, 228-233.
http://dx.doi.org/10.1007/s10562-010-0326-z

[29]. Alsalim, T. A.; Hadi, J. S.; Ali, O. N.; Abbo, H. S.; Titinchi, S. J. Chem. Cent. J. 2013, 7(1), 3-11.
http://dx.doi.org/10.1186/1752-153X-7-3

[30]. Tawfik, A. M.; El-Ghamry, M. A.; Abu-El-Wafa, S. M.; Ahmed, N. M. Spectrochim. Acta A 2012, 97, 1172-1180.
http://dx.doi.org/10.1016/j.saa.2012.07.102

[31]. Abdel-Rahman, R. M.; Makki, M. S. I. T.; Bawazir, W. A. E-J. Chem. 2011, 8, 405-414.

[32]. Keser, G.; Avciata, U.; Gul, A. Indian J. Chem. 2007, 46, 1273-1276.

[33]. Neelakantan, M. A.; Esakkiammal, M.; Mariappan, S. S.; Dharmaraja, J.; Jeyakumar, T. Indian J. Pharm. Sci. 2010, 72 216-222.
http://dx.doi.org/10.4103/0250-474X.65015

[34]. Ebrahimi-Kahrizsangi, R.; Abbasi, M. H. Trans. Nonferrous Met. Soc. China 2008, 18(1), 217-221.
http://dx.doi.org/10.1016/S1003-6326(08)60039-4

[35]. Maurya, R. C.; Rajput, S. J. Mol. Struct. 2006, 794(1-3), 24-34.
http://dx.doi.org/10.1016/j.molstruc.2006.01.031

[36]. Pretsch, E.; Buhlmann, P.; Badertscher, M. Structure Determination of Organic Compounds; Springer, Berlin, 2009.

[37]. Singh, K.; Pal, D. J. Serbian Chem. Soc. 2010, 75(7), 917-927.
http://dx.doi.org/10.2298/JSC081216063S

[38]. Yang, T. L.; Qin, W. W.; Xiao, Z. F.; Liu, W. S. Chem. Pap. 2005, 59(1), 17-20.

[39]. Nardo, L.; Paderno, R.; Andreoni, A.; Masson, M.; Haukvik, T.; Tonnesen, H. H. Spectroscopy 2008, 22(2-3), 187-198.
http://dx.doi.org/10.1155/2008/928407

[40]. Sawhney; S. S.; Bansal, A. K. Thermochim. Acta 1983, 66, 347-350.
http://dx.doi.org/10.1016/0040-6031(93)85046-C

[41]. Cavalheiro, E. T.; Lemos, F. C.; Schpector, J. Z.; Dockal, E. R. Thermochim. Acta 2001, 370, 129-133.
http://dx.doi.org/10.1016/S0040-6031(00)00777-2

[42]. Chen, H. J.; Lai, K. M. J. Chem. Eng. Japan 2004, 37(9), 1172-1178
http://dx.doi.org/10.1252/jcej.37.1172

[43]. Coats, A. W.; Redfern, J. T. Nature (London) 1964, 201, 68-69.
http://dx.doi.org/10.1038/201068a0

[44]. Hillier, J.; Bezzant, T.; Fletcher, T. H. Energy Fuels 2010, 24(5), 2841-2847.
http://dx.doi.org/10.1021/ef1001265

[45]. Georgieva, V.; Zvezdova, D.; Vlaev, L. Chem. Cent. J. 2012, 6(1), 81-90.
http://dx.doi.org/10.1186/1752-153X-6-81

[46]. Abd El-Halim, H. F.; Omar, M. M.; Mohamed, G. G.; Sayed, M. A. Eur. J. Chem. 2011, 2(2), 178-188.
http://dx.doi.org/10.5155/eurjchem.2.2.178-188.240

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