European Journal of Chemistry 2015, 6(4), 404-409 | doi: https://doi.org/10.5155/eurjchem.6.4.404-409.1299 | Get rights and content

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Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene


Jabbar Saleh Hadi (1,*)

(1) Department of Chemistry, College of Education for Pure Sciences, University of Basrah, Basrah, 61004, Iraq
(*) Corresponding Author

Received: 10 Jul 2015 | Accepted: 08 Aug 2015 | Published: 31 Dec 2015 | Issue Date: December 2015

Abstract


A new series of Schiff bases were synthesized by the condensation of sulfaproxylene with various aldehydes in ethanol. The structures of Schiff bases were characterized by using elemental analysis, IR, 1H NMR, 13C NMR and Mass spectrometry techniques. Thermal stability of the prepared compounds was investigated using TG and DTG. The kinetic and thermodynamic parameters such as activation energy (E), enthalpy of activation (ΔH), entropy of activation (ΔS), and Gibbs free energy change of the decomposition (ΔG) were evaluated following Coats-Redfern method. In addition, the compounds were studied for their fluorescence properties, where compound 1 yielded the strongest intensity in 1×10-4 M DMSO solution.


Keywords


Sulfa drug; Schiff base; Fluorescence; Coats-Redfern; Sulfaproxylene; Thermal analysis

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DOI: 10.5155/eurjchem.6.4.404-409.1299

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Metal-based biologically active azoles and β-lactams derived from sulfa drugs
Bioorganic & Medicinal Chemistry  24(5), 1121, 2016
DOI: 10.1016/j.bmc.2016.01.041
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How to cite


Hadi, J. Eur. J. Chem. 2015, 6(4), 404-409. doi:10.5155/eurjchem.6.4.404-409.1299
Hadi, J. Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene. Eur. J. Chem. 2015, 6(4), 404-409. doi:10.5155/eurjchem.6.4.404-409.1299
Hadi, J. (2015). Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene. European Journal of Chemistry, 6(4), 404-409. doi:10.5155/eurjchem.6.4.404-409.1299
Hadi, Jabbar. "Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene." European Journal of Chemistry [Online], 6.4 (2015): 404-409. Web. 23 Sep. 2021
Hadi, Jabbar. "Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene" European Journal of Chemistry [Online], Volume 6 Number 4 (31 December 2015)

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