European Journal of Chemistry

Synthesis, characterization, fluorescence, and thermal studies of a new series of Schiff bases derived from sulfaproxylene

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Published: Dec 31, 2015
DOI: https://doi.org/10.5155/eurjchem.6.4.404-409.1299
Keywords:
Sulfa drug, Schiff base, Fluorescence, Coats-Redfern, Sulfaproxylene, Thermal analysis
Section
Research Article
Issue
Vol. 6 No. 4 (2015): December 2015
Dates
Received 2015-07-10
Accepted 2015-08-08
Published 2015-12-31


Main Article Content

Jabbar Saleh Hadi
Department of Chemistry, College of Education for Pure Sciences, University of Basrah, Basrah, 61004, Iraq

Abstract

A new series of Schiff bases were synthesized by the condensation of sulfaproxylene with various aldehydes in ethanol. The structures of Schiff bases were characterized by using elemental analysis, IR, 1H NMR, 13C NMR and Mass spectrometry techniques. Thermal stability of the prepared compounds was investigated using TG and DTG. The kinetic and thermodynamic parameters such as activation energy (E), enthalpy of activation (ΔH), entropy of activation (ΔS), and Gibbs free energy change of the decomposition (ΔG) were evaluated following Coats-Redfern method. In addition, the compounds were studied for their fluorescence properties, where compound 1 yielded the strongest intensity in 1×10-4 M DMSO solution.


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Hadi, J. S. Synthesis, Characterization, Fluorescence, and Thermal Studies of a New Series of Schiff Bases Derived from Sulfaproxylene. Eur. J. Chem. 2015, 6, 404-409.

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