European Journal of Chemistry 2016, 7(1), 81-90 | doi: https://doi.org/10.5155/eurjchem.7.1.81-90.1356 | Get rights and content

Issue cover





  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide


Ahmed Abd-Elhamied El-Asmy (1,*) , Bakir Jeragh (2) , Mayada Samir Ali (3)

(1) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(2) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(3) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(*) Corresponding Author

Received: 03 Nov 2015 | Revised: 25 Nov 2015 | Accepted: 29 Nov 2015 | Published: 31 Mar 2016 | Issue Date: March 2016

Abstract


Single crystal of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)succinohydrazide (SHBH) was grown by slow evaporation method. Its, Co(II), Ni(II), Cu(II), Zn(II), Co(II)/Zn(II), Ni(II)/Zn(II) and Cu(II)/Zn(II) complexes have been prepared and characterized by elemental analysis, UV-Vis, IR, NMR, MS spectra, thermal and magnetic measurements. The data confirm the formation of tri- and tetra-metallic complexes (homo- and hetero-nuclear). The ligand behaves as a tetranegative hexadentate in the Co(II)/Zn(II) complex; hexanegative hexadentate in the Co(II) complex and hexanegative octadentate in the tetrametallic complexes. A square-planar for [Co3(SHBH-6H)(H2O)6], [Cu4(SHBH-H)(H2O)4(OAc)2]⋅3H2O, [Ni3Zn(SHBH-6H)(H2O)6Cl2]⋅H2O and [Cu3Zn(SHBH-6H)(H2O)6Cl2] and tetrahedral for [Ni4(SHBH-H)(H2O)4(OAc)2]⋅6H2O, [Zn3(SHBH-4H)-(H2O)4Cl2]⋅2H2O and [Co2Zn(SHBH-6H) (H2O)6Cl2]⋅2H2O were suggested based on the magnetic and spectral data. The TGA data confirm hydrated and coordinated water as well as the final product. The mass spectra depict their molecular ion peaks and the isotopic species of each complex. It is found that the homometallic complexes are highly stable than the heterometallic complexes. The calculated energies for [Co2Zn(SHBH-4H)(H2O)4Cl2].2H2O are higher than [Co3(SHBH-6H)-(H2O)6] indicating that the three Co stabilized the complex.


Announcements


Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.

1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).

2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).

3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).


Editor-in-Chief
European Journal of Chemistry

Keywords


Bis(hydrazones); Metal complexes; Thermal analysis; Magnetic moment; X-ray crystallography; Tetrametallic complexes

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.7.1.81-90.1356

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 1086 times | icon graph PDF Article downloaded 467 times

Funding information


Kuwait University Research Grant No. SC05/14, Kuwait

Citations

/


[1]. Ahmed Abdel-Hameed El-Asmy, Bakir Jeragh, Mayada Samir Ali
Chelation activity of N'1,N'6-bis((E)-3,4-dihydroxybenzylidene)adipohydrazide towards some transition metal ions
European Journal of Chemistry  7(3), 283, 2016
DOI: 10.5155/eurjchem.7.3.283-289.1461
/


References


[1]. Golcu, A.; Tumer, M.; Demirelli, H.; Wheatley, R. A. Inorg. Chim. Acta 2005, 358, 1797-1804.
http://dx.doi.org/10.1016/j.ica.2004.11.026

[2]. Ranford, J. D.; Vittal, J. J.; Wang, Y. M. Inorg. Chem. 1998, 37, 1226-1231.
http://dx.doi.org/10.1021/ic970805g

[3]. Jing-Lin, W.; Ya-Qin, Z.; Bin-Sheng, Y. Inorg. Chim. Acta 2014, 409, 484-496.
http://dx.doi.org/10.1016/j.ica.2013.09.001

[4]. Agarwal, R. K.; Singh, L.; Sharma, D. K.; Singh, R. Turk. J. Chem. 2005, 29, 309-316.

[5]. Suvarapu, L. N.; Seo, Y. K.; Baek, S. O.; Ammireddy, V. R. E-J. Chem. 2012, 9(3), 1288-1304.

[6]. El-Metwally, N. M.; El-Asmy, A. A.; Abu-Hussen, A. A. Int. J. Pure Appl. Chem. 2006, 1, 75-81.

[7]. Adams, H.; Clunas, S.; Fenton, D. E. Inorg. Chem. Commun. 2002, 15, 1063-1150.
http://dx.doi.org/10.1016/S1387-7003(02)00639-1

[8]. Jeragh, B.; Ali, M. S.; El-Asmy, A. A. Spectrochim. Acta A 2015, 145, 295-301.
http://dx.doi.org/10.1016/j.saa.2015.03.021

[9]. Borthakur, R.; Kumar, A.; Lal, R. A. J. Ind. Chem. Soc. 2014, 91(3), 407-423.

[10]. Monfareda, H. H.; Lalami, N. A.; Pazio, A.; Wozniak, K. Inorg. Chim. Acta 2013, 406, 241-250.
http://dx.doi.org/10.1016/j.ica.2013.04.044

[11]. El-Sayed, A. E. M.; Al-Fulaij, O. A.; Elaasar, A.; El-Defrawy, M. M.; El-Asmy, A. A. Spectrochim. Acta A 2015, 135, 211-218.
http://dx.doi.org/10.1016/j.saa.2014.07.006

[12]. Jeragh, B.; El-Asmy, A. A. Spectrochim. Acta A 2014, 129, 307-313.
http://dx.doi.org/10.1016/j.saa.2014.02.195

[13]. El-Asmy, A. A.; Al-Abdeen, A. Z.; Abo El-Maaty, W. M.; Mostafa, M. M. Spectrochim. Acta A 2010, 75, 1516-1524.
http://dx.doi.org/10.1016/j.saa.2010.02.009

[14]. Jeragh, B.; El-Asmy, A. A. Spectrochim. Acta A 2014, 130, 546-552.
http://dx.doi.org/10.1016/j.saa.2014.04.013

[15]. Becke, A. D.; J. Chem. Phys. 1993, 98, 5648-5652.
http://dx.doi.org/10.1063/1.464913

[16]. Gumus, I.; Solmaz, U. A.; Celik, O.; Binzet, G. Eur. J. Chem. 2015, 6(3), 237-241.
http://dx.doi.org/10.5155/eurjchem.6.3.237-241.1265

[17]. Tudose, R.; Mosoarca, E. M.; Simulescu, V.; Sasca, V.; Linert, W.; Costisor, O. J. Coord. Chem. 2010, 63, 4358-4366.
http://dx.doi.org/10.1080/00958972.2010.539683

[18]. El-Metwally, N. M.; El-Shazly, R. M.; Gabr, I. M.; El-Asmy, A. A. Spectrochim. Acta A 2005, 61, 1113-1119.
http://dx.doi.org/10.1016/j.saa.2004.06.027

[19]. Amer, S.; El-Wakiel, N.; El-Ghamry, H. J. Mol. Strut. 2013, 1049, 326-335.
http://dx.doi.org/10.1016/j.molstruc.2013.06.059

[20]. Hassanien, M. M.; Gabr, I. M.; Abdel-Rhman, M. H.; El-Asmy, A. A. Spectrochim. Acta A 2008, 73, 71-78.

[21]. Meghdadi, S.; Amirnasr, M.; Mereiter, K.; Motaharipour, S.; Nasehi, M.; Bagheri, M.; Abbasi, S. J. Coord. Chem. 2015, 68, 4055-4069.
http://dx.doi.org/10.1080/00958972.2015.1085977

[22]. Nejo, A. A.; Kolawola, G. A.; Nejo, A. O. J. Coord. Chem. 2010, 63, 4398-4410.
http://dx.doi.org/10.1080/00958972.2010.532871

[23]. El-Shazly, R. M.; Al-Hazmi, G. A. A.; Ghazy, S. E.; El-Shahawi, M. S.; El-Asmy, A. A. J. Coord. Chem. 2006, 59, 846-859.
http://dx.doi.org/10.1080/00958970500412099

[24]. Keypour, H.; Shayesteh, M.; Golbedaghi, R. Trans. Metal Chem. 2013, 38, 611-616.
http://dx.doi.org/10.1007/s11243-013-9728-2

[25]. Nejo, A. A.; Kolawola, G. A.; Dumbele, M. C.; Opoku, A. R. J. Coord. Chem. 2010, 63, 4367-4379.
http://dx.doi.org/10.1080/00958972.2010.539684

[26]. Al-Fulaij, O.; Jeragh, B.; El-Sayed, A.; El-Defrawy, M.; El-Asmy, A. Spectrochim. Acta A 2015, 136, 1834-1841.
http://dx.doi.org/10.1016/j.saa.2014.10.093


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


El-Asmy, A.; Jeragh, B.; Ali, M. Eur. J. Chem. 2016, 7(1), 81-90. doi:10.5155/eurjchem.7.1.81-90.1356
El-Asmy, A.; Jeragh, B.; Ali, M. Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide. Eur. J. Chem. 2016, 7(1), 81-90. doi:10.5155/eurjchem.7.1.81-90.1356
El-Asmy, A., Jeragh, B., & Ali, M. (2016). Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide. European Journal of Chemistry, 7(1), 81-90. doi:10.5155/eurjchem.7.1.81-90.1356
El-Asmy, Ahmed, Bakir Jeragh, & Mayada Samir Ali. "Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide." European Journal of Chemistry [Online], 7.1 (2016): 81-90. Web. 3 Oct. 2023
El-Asmy, Ahmed, Jeragh, Bakir, AND Ali, Mayada. "Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide" European Journal of Chemistry [Online], Volume 7 Number 1 (31 March 2016)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.7.1.81-90.1356


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2016, 7(1), 81-90 | doi: https://doi.org/10.5155/eurjchem.7.1.81-90.1356 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)





© Copyright 2010 - 2023  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.