

One-pot method of synthesis and supercritical carbon dioxide drying of PVdF-HFP composite membranes
Agnieszka Martyla (1,*)





(1) Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
(2) Center of Advanced Technologies Adam Mickiewicz University, 89c Umultowska St., 61-614 Poznan, Poland
(3) Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
(4) Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
(5) Institute of Non-Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, 12 Forteczna St., 61-362, Poznan, Poland
(*) Corresponding Author
Received: 10 Nov 2015 | Revised: 17 Dec 2015 | Accepted: 19 Dec 2015 | Published: 31 Mar 2016 | Issue Date: March 2016
Abstract
This paper describes one-pot method of the synthesis and properties of composite polymer gel electrolytes based on poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-HFP). As the precursor of the inorganic filler tetraethyl orthosilicate (TEOS) and titanium tetra-n-butoxide (Ti(OC4H9)4) were used. The drying of membranes with fillers was carried out with supercritical CO2. The membranes and gel electrolytes have been examined structurally and electrochemically, showing favorable properties in terms of electrolyte uptake and electrochemical characteristics in Li-ion cells.
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DOI: 10.5155/eurjchem.7.1.121-127.1361
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Funding information
the European Regional Development Fund, project No POIG.01.01.02-00-015/09.
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