European Journal of Chemistry

Influence of polymer binder structure on the properties of the graphite anode for lithium-ion batteries

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Published: Jun 30, 2016
DOI: https://doi.org/10.5155/eurjchem.7.2.182-186.1396
Keywords:
PVA, CMC, PVdF, Anode, Li-ion battery, Polymer binder
Section
Research Article
Issue
Vol. 7 No. 2 (2016): June 2016
Dates


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Monika Osinska-Broniarz
Institute of Non Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland
Agnieszka Martyla
Institute of Non Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland
Lukasz Majchrzycki
Wielkopolska Center for Advanced Technologies, Grunwaldzka 6, 60-780 Poznan, Poland
Marek Nowicki
Institute of Physics, Poznan University of Technology, Nieszawska 13a, PL- 60-965, Poznan, Poland
Agnieszka Sierczynska
Institute of Non Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland

Abstract

This paper discusses the impact of the structure and properties of three different polymer binders: polyvinylidene fluoride, sodium carboxymethyl cellulose and polyvinyl alcohol, on the electrochemical properties of spherical graphite anodes for Li-ion batteries. Electrochemical tests indicate that the nature of polyvinylidene fluoride contributes in decreasing the cycle life of graphite electrodes in contrast to effective water-based binders. This study demonstrates the possibility of manufacturing graphite-based electrode for Li-ion batteries that cycle longer and use water in the processing, instead of hazardous organic solvents like N-methylpyrrolidone, thereby improving performance, reducing cost and protecting the environment.


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Osinska-Broniarz, M.; Martyla, A.; Majchrzycki, L.; Nowicki, M.; Sierczynska, A. Influence of Polymer Binder Structure on the Properties of the Graphite Anode for Lithium-Ion Batteries. Eur. J. Chem. 2016, 7, 182-186.

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