European Journal of Chemistry 2016, 7(2), 182-186 | doi: https://doi.org/10.5155/eurjchem.7.2.182-186.1396 | Get rights and content






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Influence of polymer binder structure on the properties of the graphite anode for lithium-ion batteries


Monika Osinska-Broniarz (1,*) , Agnieszka Martyla (2) , Lukasz Majchrzycki (3) , Marek Nowicki (4) , Agnieszka Sierczynska (5)

(1) Institute of Non Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland
(2) Institute of Non Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland
(3) Wielkopolska Center for Advanced Technologies, Grunwaldzka 6, 60-780 Poznan, Poland
(4) Institute of Physics, Poznan University of Technology, Nieszawska 13a, PL- 60-965, Poznan, Poland
(5) Institute of Non Ferrous Metals, Division in Poznan, Central Laboratory of Batteries and Cells, Forteczna 12, 61-362 Poznan, Poland
(*) Corresponding Author

Received: 20 Jan 2016 | Accepted: 20 Feb 2016 | Published: 30 Jun 2016 | Issue Date: June 2016

Abstract


This paper discusses the impact of the structure and properties of three different polymer binders: polyvinylidene fluoride, sodium carboxymethyl cellulose and polyvinyl alcohol, on the electrochemical properties of spherical graphite anodes for Li-ion batteries. Electrochemical tests indicate that the nature of polyvinylidene fluoride contributes in decreasing the cycle life of graphite electrodes in contrast to effective water-based binders. This study demonstrates the possibility of manufacturing graphite-based electrode for Li-ion batteries that cycle longer and use water in the processing, instead of hazardous organic solvents like N-methylpyrrolidone, thereby improving performance, reducing cost and protecting the environment.


Keywords


PVA; CMC; PVdF; Anode; Li-ion battery; Polymer binder

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DOI: 10.5155/eurjchem.7.2.182-186.1396

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Funding information


Ministry of Science and Higher Education (No: DS.3787/E-138/S/2013 and no. DS.3787/E-138/S/2014-2015), Poland

Citations

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[1]. Mohammad Zarei-Jelyani, Mohsen Babaiee, Shaghayegh Baktashian, Rahim Eqra
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[2]. Trupti C. Nirmale, Bharat B. Kale, Anjani J. Varma
A review on cellulose and lignin based binders and electrodes: Small steps towards a sustainable lithium ion battery
International Journal of Biological Macromolecules  103, 1032, 2017
DOI: 10.1016/j.ijbiomac.2017.05.155
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[3]. V. V. N. Phanikumar, Vallabha Rao Rikka, Bijoy Das, Raghavan Gopalan, B. V. Appa Rao, Raju Prakash
Investigation on polyvinyl alcohol and sodium alginate as aqueous binders for lithium-titanium oxide anode in lithium-ion batteries
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[4]. Nazan Okur, Canan Saricam, Ikilem Gocek, Berdan Kalav, Umut Kivanc Sahin
Functionalized polyvinyl alcohol nanofiber webs containing β–cyclodextrin/Vitamin C inclusion complex
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DOI: 10.1177/1528083719866933
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[5]. Kelsey B. Hatzell, Marm B. Dixit, Sarah A. Berlinger, Adam Z. Weber
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[6]. Vaddi Venkata Narasimha Phanikumar, Boyapati Venkata Appa Rao, Kauveri Vengatajalabathy Gobi, Raghavan Gopalan, Raju Prakash
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[7]. Nancy Dietz Rago, Donald G. Graczyk, Yifen Tsai, Seema R. Naik, Jianlin Li, Zhijia Du, David L. Wood III, Leigh Anna Steele, Joshua Lamb, Scott Spangler, Christopher Grosso, Kyle Fenton, Ira Bloom
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How to cite


Osinska-Broniarz, M.; Martyla, A.; Majchrzycki, L.; Nowicki, M.; Sierczynska, A. Eur. J. Chem. 2016, 7(2), 182-186. doi:10.5155/eurjchem.7.2.182-186.1396
Osinska-Broniarz, M.; Martyla, A.; Majchrzycki, L.; Nowicki, M.; Sierczynska, A. Influence of polymer binder structure on the properties of the graphite anode for lithium-ion batteries. Eur. J. Chem. 2016, 7(2), 182-186. doi:10.5155/eurjchem.7.2.182-186.1396
Osinska-Broniarz, M., Martyla, A., Majchrzycki, L., Nowicki, M., & Sierczynska, A. (2016). Influence of polymer binder structure on the properties of the graphite anode for lithium-ion batteries. European Journal of Chemistry, 7(2), 182-186. doi:10.5155/eurjchem.7.2.182-186.1396
Osinska-Broniarz, Monika, Agnieszka Martyla, Lukasz Majchrzycki, Marek Nowicki, & Agnieszka Sierczynska. "Influence of polymer binder structure on the properties of the graphite anode for lithium-ion batteries." European Journal of Chemistry [Online], 7.2 (2016): 182-186. Web. 13 Jul. 2020
Osinska-Broniarz, Monika, Martyla, Agnieszka, Majchrzycki, Lukasz, Nowicki, Marek, AND Sierczynska, Agnieszka. "Influence of polymer binder structure on the properties of the graphite anode for lithium-ion batteries" European Journal of Chemistry [Online], Volume 7 Number 2 (30 June 2016)

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DOI Link: https://doi.org/10.5155/eurjchem.7.2.182-186.1396

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