European Journal of Chemistry

Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases

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Published: Dec 31, 2016
DOI: https://doi.org/10.5155/eurjchem.7.4.436-441.1445
Keywords:
Salicylaldehyde, Phenol Schiff base, Schiff base ligands, Thermogravimetry, Transition metal complexes, Thermodynamic parameters
Section
Research Article
Issue
Vol. 7 No. 4 (2016): December 2016
Dates
Received 2016-05-08
Accepted 2016-10-15
Published 2016-12-31


Main Article Content

Hayat Hamza Abbas
Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq

Abstract

Complexes of Cu(II), Co(II) and Mn(II) with two Schiff base ligands {[(2-carboxyphenyl)imino]methyl} phenol (HLA) and {[(2-hydroxyphenyl)imino]methyl} phenol (HLB) were synthesized and characterized by FT-IR, UV-Visible, 1H NMR spectroscopy and elemental analysis. All the synthesized complexes have been evaluated for their thermal degradation studies using TG-DTA analytical methods in static air. Thermodynamic and kinetic parameters were evaluated from the TG-DTA curves using Arrhenius equation.


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Abbas, H. H. Synthesis, Characterization, Kinetic and Thermodynamic Parameters Evaluation from TG-DTA Analysis of Cu(II), Co(II) and Mn(II) Complexes With Two Phenol Schiff Bases. Eur. J. Chem. 2016, 7, 436-441.

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Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq.
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