European Journal of Chemistry 2016, 7(4), 436-441 | doi: https://doi.org/10.5155/eurjchem.7.4.436-441.1445 | Get rights and content

Issue cover





  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases


Hayat Hamza Abbas (1,*)

(1) Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq
(*) Corresponding Author

Received: 08 May 2016 | Accepted: 15 Oct 2016 | Published: 31 Dec 2016 | Issue Date: December 2016

Abstract


Complexes of Cu(II), Co(II) and Mn(II) with two Schiff base ligands {[(2-carboxyphenyl)imino]methyl} phenol (HLA) and {[(2-hydroxyphenyl)imino]methyl} phenol (HLB) were synthesized and characterized by FT-IR, UV-Visible, 1H NMR spectroscopy and elemental analysis. All the synthesized complexes have been evaluated for their thermal degradation studies using TG-DTA analytical methods in static air. Thermodynamic and kinetic parameters were evaluated from the TG-DTA curves using Arrhenius equation.


Keywords


Salicylaldehyde; Phenol Schiff base; Schiff base ligands; Thermogravimetry; Transition metal complexes; Thermodynamic parameters

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.7.4.436-441.1445

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 930 times | icon graph PDF Article downloaded 369 times

Funding information


Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq.

Citations

/


[1]. Gajanan Dongare, Anand Aswar
Synthesis, spectral characterization, thermo-kinetic and biological studies of some complexes derived from tridentate hydrazone Schiff base
Journal of Saudi Chemical Society  25(10), 101325, 2021
DOI: 10.1016/j.jscs.2021.101325
/

References


[1]. Yamada, S. Coord. Chem. Rev. 1999, 190, 537-555.
http://dx.doi.org/10.1016/S0010-8545(99)00099-5

[2]. Demetgul, C.; Karakaplan, M.; Serin, S.; Digrak, M. J. Coord. Chem. 2009, 62, 3544-3551.
http://dx.doi.org/10.1080/00958970903082192

[3]. Singh, M. K.; Kar, N. K.; Lal, R. A. Asthana. J. Coord. Chem. 2009, 62, 2893-2902.
http://dx.doi.org/10.1080/00958970902939822

[4]. Raman, N.; Johnson, R. S.; Sakthirel, A. J. Coord. Chem. 2009, 62, 691-709.
http://dx.doi.org/10.1080/00958970802326179

[5]. Garanovskii, A. D.; Vasilchenko, I. S.; Garsnovskii, D. A.; Kharisov, B. I. J. Coord. Chem. 2009, 62, 151-204.
http://dx.doi.org/10.1080/00958970802398178

[6]. Patra, A.; Sarkar, S.; Chakraborty, M. G. B.; Chattopadhyay, P. J. Coord. Chem. 2010, 63, 1913-1920.
http://dx.doi.org/10.1080/00958972.2010.495985

[7]. Maurla, R. C.; Patel, P.; Rajput, S. Synth. React. Inorg. Met.-Org. Chem. 2003, 33, 817-836.

[8]. Alarcon, S. H.; Olivieri, A. C.; Nordon, A.; Harris, R. K. J. Chem. Soc. Perkin Trans 1996, 2, 2293-2296.
http://dx.doi.org/10.1039/P29960002293

[9]. Mohamed, G. G.; Omar, M. M.; Hindy, A. M. Turk. J. Chem. 2009, 30, 361-382.

[10]. Tatar, L.; Ulku, D.; Atakol, O. Acta. Cryst. 1999, 55, 508-510.
http://dx.doi.org/10.1107/S0108767398013841

[11]. Vanwyk, J. L.; Mapolie, S. F.; Iennartson, A.; Hakansson, M.; Jagner S. Inorg. Chem. Acta. 2008, 361(7), 2094-2100.
http://dx.doi.org/10.1016/j.ica.2007.10.031

[12]. Vafazadeh, R.; Hayeri, V.; Willis, A. C. Polyhedron 2010, 29, 1810-1814.
http://dx.doi.org/10.1016/j.poly.2010.02.030

[13]. Rehman, W.; Saman, F.; Ahmed, I. Russ. J. Inorg. Chem. 2008, 34(9), 678-682.

[14]. Ramesh, R. Inorg. Chem. Commun. 2004, 7, 274-276.
http://dx.doi.org/10.1016/j.inoche.2003.11.020

[15]. Lean, K.; Pat U. S. Chem. Abstract 1956, 50, 6519.

[16]. Chaakraborty, B.; Banerjee, S. J. Coord. Chem. 2013, 20(66), 3619-3628.
http://dx.doi.org/10.1080/00958972.2013.848979

[17]. Ebara, N. Bull. Chem. Soc. Jpn. 1961, 34, 1151-1158.
http://dx.doi.org/10.1246/bcsj.34.1151

[18]. Wang, M.; Lee, G. H.; Dong, T. Y. J. Chin. Chem. Soc. 2002, 49, 825-832.
http://dx.doi.org/10.1002/jccs.200200118

[19]. Jian-Ning, L.; Bo-Wan, W.; Zhang, B.; Yong-Chum, L. Turk.J. Chem. 2006, 30, 41-48.

[20]. Eman, T. S.; AL-Karkhi, I. H. E-Journal Chem. 2012, 9, 1543-1549.

[21]. Sunitha, S.; Aravindakshan, K. K. Int. J. Pharm. Biomed. Sci. 2011, 2(4), 108-113.

[22]. Krishnapriya, K. R.; Kanda, S. M. Polyhedron 2005, 24(1), 113-120.
http://dx.doi.org/10.1016/j.poly.2004.10.010

[23]. Das, G.; Shukala, R.; Mandal, S. Inorg. Chem. 1997, 36, 323-329.
http://dx.doi.org/10.1021/ic9510371

[24]. Nejati, K.; Rezvani, Z. New J. Chem. 2003, 27, 1665-1669.
http://dx.doi.org/10.1039/b305278h

[25]. Xishi, T.; Xiahong, Y.; Qiang, C.; Minyu, T. Molecules 2003, 8, 439-440.
http://dx.doi.org/10.3390/80500439

[26]. Mishra, A. P.; Mishra, R. K.; Shrivastava, S. K. J. Serb. Chem. Soc. 2009, 74, 523-535.
http://dx.doi.org/10.2298/JSC0905523M

[27]. Garnovski, A. D.; Ninorozhkin, A. L.; Minkin, V. I. Rev. 1993, 126(1), 1-69.

[28]. Wang, G.; Chang, J. C. Synth. Inorg. Met.-Org. Chem. 1994, 24, 1091-1097.

[29]. Nakamoto, K. Infrared and Raman spectra of Inorganic and coordination Compounds, 5th Edition, Part A, John Wiley & Sons, Mishawaka, 1998.

[30]. Vafazadeh, R.; Gorji, A.; Ansari, S.; Willis, A.C. Acta Chim. Slovenica 2012, 59(4), 897-903.

[31]. Nakamoto, K. Infrared and Raman spectra of Inorganic and coordination Compounds, 4th Edition, John Wiley & Sons, New York, 1986.

[32]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
http://dx.doi.org/10.1016/S0010-8545(00)80455-5

[33]. Samal, S.; Acharya, S.; Dey, R. K.; Ray, A. R. Talanta 2002, 57, 1075-1083.
http://dx.doi.org/10.1016/S0039-9140(02)00144-3

[34]. Samal, S.; Mohapatra, N. K.; Acharya, S.; Dey, K. React. Funct. Polym. 1999, 42, 37-52.
http://dx.doi.org/10.1016/S1381-5148(98)00055-8

[35]. Ikram, M.; Rehman, S.; Baker, S. R. Thermochim. Acta 2013, 555, 72-80.
http://dx.doi.org/10.1016/j.tca.2012.12.023

[36]. Kaya, l.; Oksuzgulmez, S.; Guzel, H. Bull. Chem. Soc. Ethiop. 2008, 22(2), 237-246.

[37]. Cazacum, M.; Marcu, M.; Vald, A.; Rusu, G. I.; Avadanei, M. J. Organometal. Chem. 2004, 689, 3005-3015.
http://dx.doi.org/10.1016/j.jorganchem.2004.05.051

[38]. Hayat, H. A.; Roza, A. S.; Afrodet, A. S. Global J. Pure Appl. Chem. Res. 2015, 22(2), 14-23.

[39]. Mallikarjun, K. G. E-Journal Chem. 2004, 1(2), 105-109.

[40]. Vlaev, L.; Nedelchev, N.; Gyurova, K.; Zagorcheva, M. J. Anal. Appl. Pyrolysis 2008, 81, 253-262.
http://dx.doi.org/10.1016/j.jaap.2007.12.003

[41]. Chourasia, P.; Suryesh, K. K.; Mishra, A. P. Proc. Indian Acad. Sci. 1993, 105, 173-189.


How to cite


Abbas, H. Eur. J. Chem. 2016, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, H. Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases. Eur. J. Chem. 2016, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, H. (2016). Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases. European Journal of Chemistry, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, Hayat. "Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases." European Journal of Chemistry [Online], 7.4 (2016): 436-441. Web. 24 Oct. 2021
Abbas, Hayat. "Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.7.4.436-441.1445

CrossRef | Scilit | GrowKudos | Researchgate | Publons | Microsoft | scibey | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2016, 7(4), 436-441 | doi: https://doi.org/10.5155/eurjchem.7.4.436-441.1445 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c)




© Copyright 2010 - 2021 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2021 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.