European Journal of Chemistry 2016, 7(4), 436-441 | doi: https://doi.org/10.5155/eurjchem.7.4.436-441.1445 | Get rights and content

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Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases


Hayat Hamza Abbas (1,*)

(1) Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq
(*) Corresponding Author

Received: 08 May 2016 | Accepted: 15 Oct 2016 | Published: 31 Dec 2016 | Issue Date: December 2016

Abstract


Complexes of Cu(II), Co(II) and Mn(II) with two Schiff base ligands {[(2-carboxyphenyl)imino]methyl} phenol (HLA) and {[(2-hydroxyphenyl)imino]methyl} phenol (HLB) were synthesized and characterized by FT-IR, UV-Visible, 1H NMR spectroscopy and elemental analysis. All the synthesized complexes have been evaluated for their thermal degradation studies using TG-DTA analytical methods in static air. Thermodynamic and kinetic parameters were evaluated from the TG-DTA curves using Arrhenius equation.


Keywords


Salicylaldehyde; Phenol Schiff base; Schiff base ligands; Thermogravimetry; Transition metal complexes; Thermodynamic parameters

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DOI: 10.5155/eurjchem.7.4.436-441.1445

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Funding information


Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq.

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How to cite


Abbas, H. Eur. J. Chem. 2016, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, H. Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases. Eur. J. Chem. 2016, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, H. (2016). Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases. European Journal of Chemistry, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, Hayat. "Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases." European Journal of Chemistry [Online], 7.4 (2016): 436-441. Web. 18 Jan. 2021
Abbas, Hayat. "Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

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