European Journal of Chemistry 2016, 7(4), 463-467. doi:10.5155/eurjchem.7.4.463-467.1449

Chemical oxidative synthesis and characterization of poly(o-phenylenediamine) doped with different acids


Omar Melad (1,*)

(1) Chemistry Department, Al-Azhar University, P.O. Box 1277, 79702, Gaza, Palestine
(*) Corresponding Author

Received: 10 May 2016, Accepted: 11 Jun 2016, Published: 31 Dec 2016

Abstract


Poly o-phenylenediamine (PoPD) doped with different acids such as hydrochloric, sulfuric, formic, phosphoric and glacial acetic acids was synthesized by a chemical oxidative polymerization technique using potassium dichromate as oxidizing agent. The polymer products were characterized by FT-IR and UV-visible spectroscopy. The FT-IR spectra showed shift to lower wave number in case of PoPD-H2SO4 and PoPD-H3PO4, indicating that the doping degree of PoPD in H2SO4 and H3PO4 are the greatest. A successful doping of PoPD in H3PO4 was observed in UV-vis spectroscopy. The three steps decomposition observed from the thermogravimetric analysis (TGA). The second step loss related to the loss of the dopant is found to be higher in H3PO4 doped polymer. The electrical conductivity values of PoPD-H2SO4 and PoPD-H3PO4 are found to be the highest among the other acids.


Keywords


Dopant; Conductivity; Oxidizing agent; Doped polymer; Thermal analysis; Poly o-phenylenediamine

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DOI: 10.5155/eurjchem.7.4.463-467.1449

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How to cite


Melad, O. Eur. J. Chem. 2016, 7(4), 463-467. doi:10.5155/eurjchem.7.4.463-467.1449
Melad, O. Chemical oxidative synthesis and characterization of poly(o-phenylenediamine) doped with different acids. Eur. J. Chem. 2016, 7(4), 463-467. doi:10.5155/eurjchem.7.4.463-467.1449
Melad, O. (2016). Chemical oxidative synthesis and characterization of poly(o-phenylenediamine) doped with different acids. European Journal of Chemistry, 7(4), 463-467. doi:10.5155/eurjchem.7.4.463-467.1449
Melad, Omar. "Chemical oxidative synthesis and characterization of poly(o-phenylenediamine) doped with different acids." European Journal of Chemistry [Online], 7.4 (2016): 463-467. Web. 22 Sep. 2019
Melad, Omar. "Chemical oxidative synthesis and characterization of poly(o-phenylenediamine) doped with different acids" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

DOI Link: https://doi.org/10.5155/eurjchem.7.4.463-467.1449

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