European Journal of Chemistry 2017, 8(2), 174-178 | doi: https://doi.org/10.5155/eurjchem.8.2.174-178.1570 | Get rights and content






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A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)


Fatma Aydin (1,*) , Semih Dersin (2)

(1) Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Çanakkale Onsekiz Mart University, 17100, Çanakkale, Turkey
(*) Corresponding Author

Received: 23 Mar 2017 | Revised: 03 May 2017 | Accepted: 05 May 2017 | Published: 30 Jun 2017 | Issue Date: June 2017

Abstract


Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC) was easily synthesized by addition of 2,4,6-trimethylpyridine to an aqueous precipitation of silver dichromate and characterized thoroughly, using spectroscopic and others analytical methods such as FT-IR, 1H NMR, 13C NMR, DTA, SEM-EDS and XRD. When T-TMPSDC was used as an oxidative reagent, it showed selectivity in the oxidation of primary, secondary and benzylic alcohols to their corresponding carbonyl compounds in presence of benzylic carbons and arenes such as tetraline, anthracene and phenanthrene.


Keywords


Oxidation; T-TMPSDC; Alcohol oxidation; Silver dichromate; Oxidative reagent; 2,4,6-Trimethylpyridine

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DOI: 10.5155/eurjchem.8.2.174-178.1570

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Funding information


This work was financially supported by Çanakkale Onsekiz Mart University Research Fund. (Project No: BAP, 2014/191-Turkey). The authors would also like to thank Yıldız YILDIRIM (KALESERAMIK A.Ş. ArGe, Turkey) for the TG/DTG and XRD analysis.

References

[1]. Cainelli, G.; Cardillo, G. Chromium Oxidations in Organic Chemistry; Springer: Berlin, 1984.
https://doi.org/10.1007/978-3-642-69362-5

[2]. Muzart, J. Chem. Rev. 1992, 92(1), 113-140.

[3]. Corey, E. J.; Suggs, J. W. Tetrahedron Lett. 1975, 16(31), 2647-2650.
https://doi.org/10.1016/S0040-4039(00)75204-X

[4]. Piancatelli, G.; Scattri, A.; Auria, A. D. Synthesis 1982, 4, 245-258.
https://doi.org/10.1055/s-1982-29766

[5]. Bhattacharjee, M. K.; Chaudhuri, H.S.; Dasgupta, N. R. Synthesis 1982, 7, 588-590.
https://doi.org/10.1055/s-1982-29872

[6]. Corey, E. J.; Schmidt, G. Tetrahedron Lett. 1979, 20, 399-402.
https://doi.org/10.1016/S0040-4039(01)93515-4

[7]. Aydin, F.; Ozen, R. Org. Prep. Proced. Int. 2007, 39(6), 616-620.
https://doi.org/10.1080/00304940709458647

[8]. Firouzabadi, H.; Sardarian, A.; Garibi, H. Synth. Commun. 1984, 14, 89-94.
https://doi.org/10.1080/00397918408060869

[9]. Corey, E. J.; Fleet, G. W. J. Tetrahedron Lett. 1973, 14, 4499-4501.
https://doi.org/10.1016/S0040-4039(01)87260-9

[10]. Turunc, E.; Aydin, F. Org. Prep. Proced. Int. 2004, 36(4), 363-366.
https://doi.org/10.1080/00304940409458680

[11]. Collins, J. C.; Hess, W. W.; Frank, F.J. Tetrahedron Lett. 1968, 30, 3363-3366.
https://doi.org/10.1016/S0040-4039(00)89494-0

[12]. Hashemi, M. H.; Ghazaanfari, D.; Akhbari, M. Monatsh. Chem. 2004, 135, 797-797.

[13]. Loonker, K.; Sharma, P. K.; Banerji, K. K. J. Chem. Res. (S) 1997, 194-195.

[14]. Khazaei, A.; Mehdipour, E.; Yadegari, S. Phosphorus, Sulfur, Silicon Relat. Elem. 2004, 179, 437-441.
https://doi.org/10.1080/10426500490262603

[15]. Frechet, J. M. J.; Darling, P.; Farrall, M. J. Org. Chem. 1981, 46, 1728-1730.
https://doi.org/10.1021/jo00321a042

[16]. Guziec, F. S. Jr.; Luzzio, F. A. J. Org. Chem. 1982, 47, 1787-1792.
https://doi.org/10.1021/jo00348a045

[17]. Degirmenbasi, N.; Ozgun, B. Monatsh. Chem. 2002, 133, 1417-1421.
https://doi.org/10.1007/s00706-002-0476-9

[18]. Vogel, A. Vogel's Textbook of Practical Organic Chemistry, 5th Edition. Longman Scientific and Technical: New York, 1989.

[19]. Soofivand, F.; Mohandes, F.; Salavati-Niasari, M. Mater. Res. Bull. 2013, 48, 2084-2094.
https://doi.org/10.1016/j.materresbull.2013.02.025

[20]. Cieglak-Golonka, M. J. Therm. Anal. Calorim. 1992, 38, 2501-2513.
https://doi.org/10.1007/BF01974628

How to cite


Aydin, F.; Dersin, S. Eur. J. Chem. 2017, 8(2), 174-178. doi:10.5155/eurjchem.8.2.174-178.1570
Aydin, F.; Dersin, S. A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC). Eur. J. Chem. 2017, 8(2), 174-178. doi:10.5155/eurjchem.8.2.174-178.1570
Aydin, F., & Dersin, S. (2017). A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC). European Journal of Chemistry, 8(2), 174-178. doi:10.5155/eurjchem.8.2.174-178.1570
Aydin, Fatma, & Semih Dersin. "A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)." European Journal of Chemistry [Online], 8.2 (2017): 174-178. Web. 7 Apr. 2020
Aydin, Fatma, AND Dersin, Semih. "A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)" European Journal of Chemistry [Online], Volume 8 Number 2 (30 June 2017)

DOI Link: https://doi.org/10.5155/eurjchem.8.2.174-178.1570

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