European Journal of Chemistry 2019, 10(2), 125-130 | doi: https://doi.org/10.5155/eurjchem.10.2.125-130.1849 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer


Prafullya Kumar Mudi (1) orcid , Chanchal Kumar Pal (2) orcid , Bhaskar Biswas (3,*) orcid

(1) Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
(2) Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
(3) Department of Chemistry, University of North Bengal, Darjeeling, 734013, India
(*) Corresponding Author

Received: 17 Mar 2019 | Revised: 26 Apr 2019 | Accepted: 04 May 2019 | Published: 30 Jun 2019 | Issue Date: June 2019

Abstract


A one dimensional (1D) lead(II) coordination polymer, [Pb(Phen)(NO3)(OAC)(H2O)]n (1) (Phen = 1,10-Phenanthroline; OAc = Acetate) was isolated in crystalline phase and characterized through different analytical techniques. Single crystal X-ray structural analysis of compound 1 revealed that the Pb(II) polymer crystallized in a monoclinic system with P21/c space group. Pb2+ ion adopted a highly distorted octahedral geometry having O3 (water) and O5 (nitrate) at axial positions (∠O3-Pb1-O5 of 145.02°) and acetate oxygen (O4), phenanthroine nitrogens (N3, N4) and oxygen (O2) atom from bridging nitrate made a distorted square plane. This Pb(II) polymer exhibited good fluorescence property in solid state. The steric arrangement of distorted square plane around Pb(II) ion by Phen, acetate and bridging nitrate ion makes a huge gap around Pb(II) ion where a stereo-active lone pair of electrons may possibly be occupied.

 


Keywords


Pb(II); 1D polymer; Phenanthroline; X-ray crystal structure; Fluorescence property; Supramolecular interactions

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.10.2.125-130.1849

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 1010 times | icon graph PDF Article downloaded 401 times

Funding information


The Science and Engineering Research Board (SERB), (Teachers Associateship for Research Excellence (No. TAR/2018/000473 dtd. 01-3-2019)), New Delhi, India.

References


[1]. Sidgwick, N. V.; Powell, H. M. Proc. R. Soc. 1940, 176, 153-180.
https://doi.org/10.1098/rspa.1940.0084

[2]. Persson, I.; Lyczko, K.; Lundberg, D.; Eriksson, L.; Placzek, A. Inorg. Chem. 2011, 50, 1058-1072.
https://doi.org/10.1021/ic1017714

[3]. Hua, M. L.; Morsalib, A.; Aboutorabi, L. Coord. Chem. Rev. 2011, 255, 2821-2859.
https://doi.org/10.1016/j.ccr.2011.05.019

[4]. Gillespie, R. J.; Nyholm, R. S. Q. Rev. London 1957, 11, 339-380.
https://doi.org/10.1039/qr9571100339

[5]. Gillespie, R. J. Hargittai, I. The VSEPR Model of Molecular Geometry; Allyn and Bacon, Boston, MA, 1991.

[6]. Mudring, A. V. In Inorganic Chemistry in Focus, 3th ed.; G. Meyer, D. Naumann, L. Wesemann, Eds.; Wiley-VCH Verlag: Weinheim, Germany, 2006.

[7]. Mudring, A. V.; Rieger, F. Inorg. Chem. 2005, 44, 6240-6243.
https://doi.org/10.1021/ic050547k

[8]. Mudring, A. V. Eur. J. Inorg. Chem. 2007, 882-890.
https://doi.org/10.1002/ejic.200600975

[9]. Shimoni-Livny, L.; Glusker, J. P.; Bock, C. W. Inorg. Chem. 1998, 37, 1853-1867.
https://doi.org/10.1021/ic970909r

[10]. Ren, Y. X.; Zheng, X. J.; Jin, L. P. Cryst. Eng. Comm. 2011, 13, 5915-5923.
https://doi.org/10.1039/c1ce05303e

[11]. Abedini, J.; Morsali, A.; Kempe, R.; Hertl, I. J. Coord. Chem. 2005, 58, 1719-1726.
https://doi.org/10.1080/00958970500262205

[12]. Morsali, A.; Payeghader, M.; Monfareda, S. S.; Moradi, M. J. Coord. Chem, 2003, 56, 1719-1726.

[13]. Dey, D.; Yadav, H. R.; De, A.; Chatterjee, S.; Maji, M.; Choudhury, A. R.; Kole, N.; Biswas, B. J. Coord. Chem. 2015, 68, 169-180.
https://doi.org/10.1080/00958972.2014.985215

[14]. Casas, J. S.; Sordo (Ed.), J. Lead: Chemistry, Analytical Aspects, Environmental Impact and Health Effects, Elsevier, 2006.

[15]. Gracia, R. C.; Snodgrass, W. R. Am. J. Health-Syst. Pharm. 2007, 64(1), 45-53.
https://doi.org/10.2146/ajhp060175

[16]. Saxena, G.; Flora, S. J. S. J. Biochem. Mol. Toxicol. 2004, 18(4), 221-233.
https://doi.org/10.1002/jbt.20027

[17]. Claudio, E. S.; Godwin, H. A.; Magyar, J. S. Prog. Inorg. Chem. 2003, 51, 1-144.

[18]. Seko, H.; Tsuge, K.; Igashira-Kamiyama, A.; Kawamoto, T.; Konno, T. Chem. Commun. 2010, 46, 1962-1964.
https://doi.org/10.1039/b913989c

[19]. Mir, M. H.; Vittal, J. J. Angew. Chem. Int. Ed. 2007, 46, 5925-5928.
https://doi.org/10.1002/anie.200701779

[20]. Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem. Int. Ed. 2004, 43, 1466-1496.
https://doi.org/10.1002/anie.200300588

[21]. CrystalClear 2.0, Rigaku Corporation: Tokyo, Japan.

[22]. Sheldrick, G. M. Acta Crystallogr. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[23]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726

[24]. Marandi, F.; Nikpey, Z.; Khosravi, M.; Fun, H. K.; Hemamalini, M. J Coord. Chem. 2011, 64, 3012-3021.
https://doi.org/10.1080/00958972.2011.609593

[25]. Marandi, F.; Morsali, A. Inorg. Chim. Acta 2011, 370, 526-530.
https://doi.org/10.1016/j.ica.2011.01.045

[26]. Lillehaug, J. R.; Kleppe, K. Biochemistry 1975, 14, 1225-1229.
https://doi.org/10.1021/bi00677a021

[27]. Minero, C.; Mariella, G.; Maurino, V.; Pelizzetti, E. Langmuir 2000, 16, 2632-2641.
https://doi.org/10.1021/la9903301

[28]. Lu, M. C.; Chen, J. N.; Chang, C. P. Chemosphere 1997, 35, 2285-2293.
https://doi.org/10.1016/S0045-6535(97)00307-X

[29]. Shimoni-Livny, L.; Glusker, J. P.; Bock, C. W. Inorg. Chem. 1998, 37, 1853-1867.
https://doi.org/10.1021/ic970909r

[30]. De, A.; Sahu, A.; Paul, S.; Mayank, J.; Choudhury, A. R.; Biswas, B. J. Mol. Struct. 2018, 1167, 187-193.
https://doi.org/10.1016/j.molstruc.2018.04.081

[31]. Garai, M.; Dey, D.; Yadav, H. R.; Choudhury, A. R.; Kole, N.; Biswas, B. Polyhedron 2017, 129, 114-122.
https://doi.org/10.1016/j.poly.2017.03.038

[32]. J. M. Lehn, J. M. Science 1993, 260, 1762-1763.
https://doi.org/10.1126/science.8511582

[33]. Panjehpour, A.; Morsali, A. J. Inorg. Organomet. Polym. 2012, 22, 938-945.
https://doi.org/10.1007/s10904-012-9674-z

[34]. Chowdhury, B.; Bhowmik, B.; Sahu, A.; Joshi, M.; Paul, S.; Choudhury, A. R.; Biswas, B. J. Chem. Sci. 2018, 130, 161-169.
https://doi.org/10.1007/s12039-018-1562-9

[35]. Muller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143-167.
https://doi.org/10.1021/cr9900331


Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Mudi, P.; Pal, C.; Biswas, B. Eur. J. Chem. 2019, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849
Mudi, P.; Pal, C.; Biswas, B. Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer. Eur. J. Chem. 2019, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849
Mudi, P., Pal, C., & Biswas, B. (2019). Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer. European Journal of Chemistry, 10(2), 125-130. doi:10.5155/eurjchem.10.2.125-130.1849
Mudi, Prafullya, Chanchal Kumar Pal, & Bhaskar Biswas. "Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer." European Journal of Chemistry [Online], 10.2 (2019): 125-130. Web. 22 Mar. 2023
Mudi, Prafullya, Pal, Chanchal, AND Biswas, Bhaskar. "Synthesis, supramolecular architecture and fluorescence property of a mixed ligand 1D Pb(II) coordination polymer" European Journal of Chemistry [Online], Volume 10 Number 2 (30 June 2019)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.10.2.125-130.1849


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2019, 10(2), 125-130 | doi: https://doi.org/10.5155/eurjchem.10.2.125-130.1849 | Get rights and content

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c) 2019 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).


© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.