European Journal of Chemistry

Synthesis, characterization and crystal structure of a novel tetranuclear Co(II) cubane cluster

Crossmark


Main Article Content

Hong Chen
Jianchun Wu
Mingguo Liu

Abstract

A new tetranuclear Co(II) cubane cluster 1, [Co4(L1)4(L2)4]·4CH3CH2OH (HL1 = 2-Methylquinolin-8-ol, HL2 = t-Bu-COOH), has been synthesized and characterized by X-ray single crystal diffraction, FT-IR, TG/DSC, and elementary analysis. The data reveals that it has a very interesting structural motif consisting of a [Co4O4] core in the form of a cube with the Co and O occupying opposite corners. In the crystal structure of complex 1, the molecules are linked by intramolecular CH···O hydrogen bonding interactions and Van der Waals forces, forming a three-dimensional network structure. Crystal data for complex 1: C60H68Co4N4O12, triclinic, space group P-1 (no. 2), with a = 12.0644(4), b = 12.0996(3), c = 20.2858(7) Å, α = 92.005(3)o, β = 92.182(3)°, γ = 97.943(3)°, Z = 2, V = 2928.25(16) Å3, T = 293 K, μ(Mo) = 1.178 mm-1, Dcalc = 1.444 g/cm3, 16737 reflections measured (3.00° ≤ θ ≤ 28.53°), 9010 unique (Rint = 0.024, Rsigma = 0.0574) which were used in all calculations. The final R1 was 0.039 (I≥2σ(I)) and wR2 was 0.090 (all data).


icon graph This Abstract was viewed 1314 times | icon graph Article PDF downloaded 520 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Chen, H.; Wu, J.; Liu, M. Synthesis, Characterization and Crystal Structure of a Novel Tetranuclear Co(II) Cubane Cluster. Eur. J. Chem. 2019, 10, 256-262.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Fujita, D.; Ueda, Y.; Sato, S.; Mizuno, N.; Kumasaka, T.; Fujita, M. Nature 2016, 540, 563-566.
https://doi.org/10.1038/nature20771

[2]. Brown, C. J.; Toste, F. D.; Bergman, R. G.; Raymond, K. N. Chem. Rev. 2015, 115, 3012-3035.
https://doi.org/10.1021/cr4001226

[3]. McConnell, A. J.; Wood, C. S.; Neelakandan, P. P.; Nitschke, J. R. Chem. Rev. 2015, 115, 7729-7793.
https://doi.org/10.1021/cr500632f

[4]. Saha, M. L.; Yan, X.; Stang, P. J. Acc. Chem. Res. 2016, 49, 2527-2539.
https://doi.org/10.1021/acs.accounts.6b00416

[5]. Ballester, P.; Fujita, M.; Rebek, Jr. J. Chem. Soc. Rev. 2015, 44, 392-393.
https://doi.org/10.1039/C4CS90101K

[6]. Cook, T. R.; Stang, P. J. Chem. Rev. 2015, 115, 7001-7045.
https://doi.org/10.1021/cr5005666

[7]. Smulders, M. M. J.; Riddell, I. A.; Browne, C.; Nitschke, J. R. Chem. Soc. Rev. 2013, 42, 1728-1754.
https://doi.org/10.1039/C2CS35254K

[8]. Han, M.; Engelhard, D. M.; Clever, G. H. Chem. Soc. Rev. 2014, 43, 1848-1860.
https://doi.org/10.1039/C3CS60473J

[9]. Saalfrank, R. W.; Maid, H.; Scheurer, A. Angew. Chem. Int. Ed. 2008, 47, 8794-8824.
https://doi.org/10.1002/anie.200702075

[10]. Yoshizawa, M.; Klosterman, J. K.; Fujita, M. Angew. Chem. Int. Ed. 2009, 48, 3418-3438.
https://doi.org/10.1002/anie.200805340

[11]. Breiner, B.; Clegg, J. K.; Nitschke, J. R. Chem. Sci. 2011, 2, 51-56.
https://doi.org/10.1039/C0SC00329H

[12]. Galan, A.; Ballester, P. Chem. Soc. Rev. 2016, 45, 1720-1737.
https://doi.org/10.1039/C5CS00861A

[13]. Koblenz, T. S.; Wassenaar, J.; Reek J. N. H. Chem. Soc. Rev. 2008, 37, 247-262.
https://doi.org/10.1039/B614961H

[14]. Georgieva, I.; Trendafilova, N.; Dodoff, N.; Kovacheva. D. Spectrochim. Acta A 2017, 176, 58-66.
https://doi.org/10.1016/j.saa.2017.01.008

[15]. Song, J.; Duan, B. F.; Lu, J. F.; Wu, R.; Du. Q. C. J. Mol. Struct. 2019, 1195, 252-258.
https://doi.org/10.1016/j.molstruc.2019.05.030

[16]. Akhtar, M.; Alharthi, A. I.; Alotaibi, M. A.; Trendafilova, N. Polyhedron 2017, 122, 105-115.
https://doi.org/10.1016/j.poly.2016.11.017

[17]. Chen, H.; Liu, M. G. J. Mol. Struct. 2019, 1180, 31-40.

[18]. Jeon, I. R.; Clérac, R. Dalton Trans. 2012, 41, 9565-9686.
https://doi.org/10.1039/c2dt30906h

[19]. Sato, Y.; Ohkoshi, S.; Arai, K.; Tozawa, M.; Hashimoto, K. J. Am. Chem. Soc. 2003, 125, 14590-14595.
https://doi.org/10.1021/ja030375v

[20]. Liu, C. M.; Zhang, D. Q.; Zhu, D. B. Chem. Commun. 2008, 368-370.
https://doi.org/10.1039/B715080F

[21]. Hao, Z. M.; Zhang, X. M. Dalton Trans. 2011, 40, 2092-2098.
https://doi.org/10.1039/c0dt00979b

[22]. Das, A.; Klinke, F. J.; Demeshko, S.; Meyer, S.; Dechert, S.; Meyer, F. Inorg. Chem. 2012, 51, 8141-8149.
https://doi.org/10.1021/ic300535d

[23]. Murrie, M.; Teat, S. J.; Stoeckli-Evans, H.; Gudel, H. U. Angew. Chem., Int. Ed. 2003, 42, 4653-4656.
https://doi.org/10.1002/anie.200351753

[24]. Song, Y. M.; Luo, F.; Luo, M. B.; Liao, Z. W.; Sun, G. M.; Tian, X. Z.; Zhu, Y.; Yuan, Z. J.; Liu, S. J.; Xu, W. Y.; Feng, X. F. Chem. Commun. 2012, 48, 1006-1008.
https://doi.org/10.1039/C2CC17080A

[25]. Zeng, M. H.; Yin, Z.; Liu, Z. H.; Xu, H. B.; Feng, Y. C.; Hu, Y. Q.; Chang, L. X.; Zhang, Y. X.; Huang, J.; Kurmoo, M. Angew. Chem., Int. Ed. 2016, 55, 11407-11411.
https://doi.org/10.1002/anie.201604813

[26]. Shi, X. C.; Chen, Z. Y.; Wang, Y. J.; Guo, Z. J.; Wang, X. Y. Dalton Trans. 2018, 47, 5049-5054.
https://doi.org/10.1039/C8DT00794B

[27]. Hannon, M. J. Chem. Soc. Rev. 2007, 36, 280-295.
https://doi.org/10.1039/B606046N

[28]. Hannon, M. J. Pure Appl. Chem. 2007, 79, 2243-2261.
https://doi.org/10.1351/pac200779122243

[29]. Passard, G.; Ullman, A. M.; Brodsky, C. N.; Nocera, D. G. J. Am. Chem. Soc. 2016, 138, 2925-2928.
https://doi.org/10.1021/jacs.5b12828

[30]. Becker, H. G. O.; Berger, W.; Domschke, G.; Fanghanel, E.; Faust, J.; Fischer, M.; Gentz, F.; Gewald, K.; Gluch, R.; Mayer, R.; Müller, K.; Pavel, D.; Schmidt, H.; Schollberg, K.; Schwetlick, K.; Seiler, E.; Zeppenfeld, G. Organikum, 19th ed.; Johann Ambrosius Barth Verlag GmbH: Leipzig, Berlin, Heidelberg, 1993.

[31]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Cryst. 2009, 42, 339-341.
https://doi.org/10.1107/S0021889808042726

[32]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
https://doi.org/10.1107/S0108767307043930

[33]. K. Brandenburg, DIAMOND Version 3.0, Crystal Impact GbR, Bonn, Germany, 2014.

[34]. Kresse, G.; Hafner, J. Phys. Rev. B 1993, 47, 558-561.
https://doi.org/10.1103/PhysRevB.47.558

[35]. Kresse, G.; Hafner, J. Phys. Rev. B 1994, 49, 14251-14269.
https://doi.org/10.1103/PhysRevB.49.14251

[36]. Kresse, G.; Furthmüller, J. Phys. Rev. B 1996, 54, 11169-11186.
https://doi.org/10.1103/PhysRevB.54.11169

[37]. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865-3868.
https://doi.org/10.1103/PhysRevLett.77.3865

[38]. Kresse, G.; Joubert, D. Phys. Rev. B 1999, 59, 1758-1775.
https://doi.org/10.1103/PhysRevB.59.1758

[39]. Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.; Humphreys, C. J.; Sutton, A. P. Phys. Rev. B 1998, 57, 1505-1509.
https://doi.org/10.1103/PhysRevB.57.1505

[40]. Klinke, F. J.; Das, A.; Demeshko, S.; Dechert, S.; Meyer, F. Inorg. Chem. 2014, 53, 2976-2982.
https://doi.org/10.1021/ic4027656

[41]. Ma, X. F.; Wang, Z.; Chen, X. L.; Kurmoo, M.; Zeng, M. H. Inorg. Chem. 2017, 56, 15178-15186.
https://doi.org/10.1021/acs.inorgchem.7b02530

[42]. Chen, X. L.; Xu, H. B.; Shi, X. X.; Zhang, Y. X.; Yang, T.; Kurmoo, M.; Zeng, M. H. Inorg. Chem. 2017, 56, 14069-14076.
https://doi.org/10.1021/acs.inorgchem.7b02210

Supporting Agencies

The Analytical & Testing Center of China Three Gorges University, Yichang, China and The Institute of Nuclear Science and Technology, Sichuan University, Chengdu, China.
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).