European Journal of Chemistry 2019, 10(3), 267-272 | doi: https://doi.org/10.5155/eurjchem.10.3.267-272.1914 | Get rights and content






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Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide


Bridget Ndoye Ndosiri (1,*) orcid , Katia Nchimi Nono (2) orcid , Paboudam Gbambie Awawou (3) orcid , Emmanuel Ngwang Nfor (4) orcid , Aminou Mohamadou (5) orcid , Jerome Marrot (6) orcid , Peter Ndifon Teke (7) orcid

(1) Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
(2) Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
(3) Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
(4) Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon
(5) Université de Reims Champagne-Ardenne, Institut de Chimie Moléculaire de Reims (ICMR), CNRS UMR 7312, UFR des Sciences Exactes et Naturelles, Bâtiment 18 Europol ’Agro, BP 1039, F-51687 Reims Cedex 2, France
(6) Institut Lavoisier de Versailles (ILV)-UMR 8180 (CNRS/UVSQ,)45 avenue des États-Unis Bâtiment Lavoisier 78035 Versailles, Cedex, France
(7) Inorganic Chemistry Department, Faculty of Science, University of Yaounde 1, Yaounde, Cameroon
(*) Corresponding Author

Received: 05 Jul 2019 | Revised: 29 Jul 2019 | Accepted: 31 Jul 2019 | Published: 30 Sep 2019 | Issue Date: September 2019

Abstract


The dinuclear compound, [Mn2(Pyala)2(Dca)2(H2O)]n·2H2O (1) (Pyala = N-(2-pyridylmethyl)-L-alanine and Dca = dicyanamide anion) has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction techniques. The crystal data for C22H26Mn2N10O6: orthorhombic, space group P212121 (no. 19), a = 10.3728(8) Å, b = 15.9780(12) Å, c = 16.3585(13) Å, = 2711.2(4) Å3, Z = 4, T = 198(2) K, μ(MoKα) = 0.989 mm-1, Dcalc = 1.559 g/cm3, 129607 reflections measured (3.564° ≤ 2Θ ≤ 60.046°), 7923 unique (Rint = 0.0324, Rsigma = 0.0155) which were used in all calculations. The final R1 was 0.0169 (I > 2σ(I)) and wR2 was 0.0458 (all data). The obtained non-centrosymmetric dinuclear Mn(II) complex contains two unique Mn(II) cations with similar octahedral coordination environment. Photoluminescent measurements on the complex in the solid state show that it displays strong photoluminescence at 442 nm.


Keywords


Manganese; Dicyanamide; Photoluminescent; Non-centrosymmetric; Single crystal structure; N-(2-Pyridylmethyl)-(L)-alanine)

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DOI: 10.5155/eurjchem.10.3.267-272.1914

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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Ndosiri, B.; Nono, K.; Awawou, P.; Nfor, E.; Mohamadou, A.; Marrot, J.; Teke, P. Eur. J. Chem. 2019, 10(3), 267-272. doi:10.5155/eurjchem.10.3.267-272.1914
Ndosiri, B.; Nono, K.; Awawou, P.; Nfor, E.; Mohamadou, A.; Marrot, J.; Teke, P. Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide. Eur. J. Chem. 2019, 10(3), 267-272. doi:10.5155/eurjchem.10.3.267-272.1914
Ndosiri, B., Nono, K., Awawou, P., Nfor, E., Mohamadou, A., Marrot, J., & Teke, P. (2019). Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide. European Journal of Chemistry, 10(3), 267-272. doi:10.5155/eurjchem.10.3.267-272.1914
Ndosiri, Bridget, Katia Nchimi Nono, Paboudam Gbambie Awawou, Emmanuel Ngwang Nfor, Aminou Mohamadou, Jerome Marrot, & Peter Ndifon Teke. "Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide." European Journal of Chemistry [Online], 10.3 (2019): 267-272. Web. 21 Feb. 2020
Ndosiri, Bridget, Nono, Katia, Awawou, Paboudam, Nfor, Emmanuel, Mohamadou, Aminou, Marrot, Jerome, AND Teke, Peter. "Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide" European Journal of Chemistry [Online], Volume 10 Number 3 (30 September 2019)

DOI Link: https://doi.org/10.5155/eurjchem.10.3.267-272.1914

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