European Journal of Chemistry

A highly sensitive and selective spectrophotometric method for the determination of vanadium at nanotrace levels in some environmental, biological, soil, food, and pharmaceutical samples using salicylaldehyde-benzoylhydrazone

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Published: Dec 31, 2020
DOI: https://doi.org/10.5155/eurjchem.11.4.385-395.2030
Keywords:
Food samples, Spectrophotometry, Environmental samples, Pharmaceutical samples, Vanadium determination, Salicylaldehyde-benzoylhydrazone
Section
Research Article
Issue
Vol. 11 No. 4 (2020): December 2020
Dates
Received 2020-08-18
Accepted 2020-11-22
Published 2020-12-31
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Shaifa Abrarin
Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
http://orcid.org/0000-0001-5938-393X
Mohammed Jamaluddin Ahmed
Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
http://orcid.org/0000-0002-3765-066X

Abstract

A very simple, non-extractive and new spectrophotometric method for the swift determination of trace amount of vanadium using salicylaldehyde-benzoylhydrazone (Sal-BH) has been developed. Sal-BH undergoes a reaction in a slightly acidic solution (0.0016-0.0032 M H2S04) with vanadium to give a light greenish-yellow chelate, which has an absorption maximum at 392 nm. The reaction is instantaneous and absorbance remains stable for over 24 hrs. The average molar absorption co-efficient and Sandell’s sensitivity were found to be 2.5039×105 L/mol.cm and 1.0 ng/cm2 V, respectively. Beer’s law was obeyed for 0.001-30 mg/L of V, providing a detection limit of 0.1 µg/L of V and RSD 0-2 %. The stoichiometric composition of the chelate is 1:1 (V:Sal-BH). Interference study shows that a large excess of over 60 cations, anions, and some common complexing agents (such as chloride, azide, tartrate, EDTA and SCN‑, etc.) satisfy the tolerance limit. The developed method was successfully used in the determination of vanadium in several standard reference materials as well as in some environmental waters, biological fluids, soil, food and pharmaceutical samples and solutions containing both vanadium (IV) and vanadium (V). The results of the proposed method for assessing biological, food and vegetable samples were comparable with ICP-OES and AAS were found to be in excellent agreement. The method has high precision and accuracy (s = ±0.01 for 0.5 mg/L).


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Abrarin, S.; Ahmed, M. J. A Highly Sensitive and Selective Spectrophotometric Method for the Determination of Vanadium at Nanotrace Levels in Some Environmental, Biological, Soil, Food, and Pharmaceutical Samples Using Salicylaldehyde-Benzoylhydrazone. Eur. J. Chem. 2020, 11, 385-395.

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References

[1]. Baroch, E. F.; Updated by Staff., Vanadium and Vanadium Alloys. Kirk-Othmer Encyclopedia of Chemical Technology, 2013.
https://doi.org/10.1002/0471238961.22011401.a01.pub3

[2]. Crans, D. C.; Gottlieb, M. S.; Tawara, J.; Bunch, R. L.; Theisen, L. A. Anal. Biochem. 1990, 188(1), 53-64.
https://doi.org/10.1016/0003-2697(90)90527-G

[3]. Clayton, G. D.; Clayton, F. E. (Eds)., Patty's Industrial Hygiene and Toxicology, 3rd Edition, Vol. 2A, Wiley, New York, 1981, pp. 2013-2036.

[4]. Bratter, P.; Schramel, P., Trace Element Analytical Chemistry in Medicine and Biology, De Gruyter, Berlin, 1984, pp. 375-383.

[5]. Mracova, M.; Jirova, D.; Janci, H.; Lener, J. Sci. Total Environ. 1993, 16, 633-633.

[6]. Venugopal, B.; Luckey, T. D., Metal Toxicity in Mammals, Vol: 2, Plenum Press, New York, 1979, pp. 220-223.

[7]. Nordberg, G. F.; Fowler, B. A.; Nordberg, M.; Friberg, L. T. Handbook on the Toxicology of Metals, Academic Press, Amsterdam. 1986.

[8]. Key, M. M.; Henschel, A. F.; Butter, J.; Ligo, R. N.; Tabershad, I. R. Occupational Diseases-A Guide to Their Recognition, US Department of Health, Education and Welfare, US Government Printing, Washington, DC., June 1977.

[9]. Pyrzynska, K. Microchim. Acta 2005, 149(3-4), 159-164.
https://doi.org/10.1007/s00604-004-0304-5

[10]. Crumb, R. Vanadium and Its Role in Life Metal Ions in Biological Systems, Volume 31, Biochemical Education, 1995, 23(3), 180.
https://doi.org/10.1016/0307-4412(95)90238-4

[11]. Liao, Z. J. Pollution, hazard, migrate and transform of micro amounts heavy metal elements in environment, Science Press, Beijing, 1989, pp. 28-30.

[12]. Patel, B.; Henderson, G. E.; Haswell, S. J.; Grzeskowiak, R. Analyst 1990, 115(8), 1063-1066.
https://doi.org/10.1039/an9901501063

[13]. Lenntech B.V., Vanadium - V, Retrieved Oct 01, 2020, from https://www.lenntech.com/periodic/elements/v.htm

[14]. Ahmed, M. J.; Zannat, T. Pak. J. Anal. Environ. Chem. 2012, 13(1), 22-35.

[15]. Ahmed, M. J.; Afrin, A.; Uddin, M. O. Eur. J. Chem. 2020, 11(1), 37-49.
https://doi.org/10.5155/eurjchem.11.1.37-49.1923

[16]. Ahmed, M. J.; Banoo, S. Talanta 1999, 48(5), 1085-1094.
https://doi.org/10.1016/S0039-9140(98)00329-4

[17]. Zucchi, C.; Forneris, M.; Martinez, L.; Olsina, R.; Marchevsky, E. Fresen. J. Anal. Chem. 1998, 360(1), 128-130.
https://doi.org/10.1007/s002160050658

[18]. Narayana, S. L.; Reddy, K. J.; Narayana Reddy, S. A.; Sarala, Y.; Reddy, A. V. Environ. Monit. Assess. 2007, 144(1-3), 341-349.
https://doi.org/10.1007/s10661-007-9997-3

[19]. Verdizade, N. A.; Magerramov, A. M.; Kuliev, K. A. J. Anal. Chem. 2011, 66(12), 1159-1164.
https://doi.org/10.1134/S1061934811090188

[20]. Zalov A. Z.; Verdizade, N. A. Chem. J. 2015, 5(4), 54-62.

[21]. Narang, K. K.; Rao, T. R.; Shrestha, S.; Shrestha, S. Synt. React. Inorg. Metal-Org. Chem. 2000, 30(5), 931-954.
https://doi.org/10.1080/00945710009351810

[22]. Jeffery, G. H.; Bassett, J.; Mendham, J.; Denney, R. C. (Eds.). Vogel's Textbook of Quantitative Chemical Analysis, ELBS, 5th Edition, Bath Press Ltd., London, 1994.

[23]. Mukherji, A. K. Analytical Chemistry of Zirconium and Hafnium, 1st Edition, Pergamon Press, Oxford, 1970.
https://doi.org/10.1016/B978-0-08-006886-2.50006-0

[24]. Pal, B. K.; Chaudhury, B. Mikrochim. Acta 1985, 85(5-6), 437-446.
https://doi.org/10.1007/BF01201540

[25]. Busev, A. I.; Tiptsova, V. G.; Ivanov, V. M. Analytical Chemistry of Rare Elements, Mir Publishers, Moscow, 1981, pp. 385-392.

[26]. Al-Kharafi, F. M.; Badawy, W. A. Electrochim. Acta 1997, 42(4), 579-586.
https://doi.org/10.1016/S0013-4686(96)00202-2

[27]. Sandell's, E. B. Colorimetric Determination of Traces of Metals, 3rd Edition, Interscience, New York, 1965, pp. 269-275.

[28]. Ostampour, L.; Taher, M. Talanta 2008, 75(5), 1279-1283.
https://doi.org/10.1016/j.talanta.2008.01.045

[29]. Job, P. Ann. Chim. Paris, 1928, 9, 113-203.
https://doi.org/10.3406/bmsap.1928.9218

[30]. Yoe, J. H.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16(2), 111-115.
https://doi.org/10.1021/i560126a015

[31]. Gao, J.; Zhang, X.; Yang, W.; Kang, J. Anal. Chim. Acta 2002, 455(1), 159-165.
https://doi.org/10.1016/S0003-2670(01)01583-5

[32]. Mitra, S., Sample Preparation Techniques in Analytical Chemistry, John Wiley & Sons, Inc., 2003, pp. 125-140.
https://doi.org/10.1002/0471457817

[33]. Melwanki, M. B.; Seetharamappa, J.; Masti, S. P. Anal. Sci. 2001, 17(8), 979-982.
https://doi.org/10.2116/analsci.17.979

[34]. Greenberg, E. A.; Clesceri, S. L.; Eaton, D. A. (Eds.). Standard Methods for the Examination of Water and Wastewater, 18th edn, American Public Health Association, Washington D. C., 1992, 3-253-260.

[35]. Chambon, P.; Lound, U.; Ohanian, E. WHO Guidelines for Drinking Water Quality, Recommendations, WHO, Geneva, 2nd Edition, 1993.

[36]. Miura, J. Anal. Chem. 1990, 62(14), 1424-1428.
https://doi.org/10.1021/ac00213a015

[37]. Khayatian, G.; Hassanpoor, S.; Azar, A. R. J.; Mohebbi, S. J. Braz. Chem. Soc. 2013, 24(11), 1808-1812.

[38]. Stahr, H. M. Analytical Methods in Toxicology, 3rd Edition, John Wiley and Sons, New York, 1991, pp. 85-96.

[39]. Rondini, E. A.; Walters, D. M.; Bauer, A. K. Part. Fibre Toxicol. 2010, 7(1), 9, 1-13.
https://doi.org/10.1186/1743-8977-7-9

[40]. Jackson, M. L. Soil Chemical Analysis, Prentice Hall, Englewood Cliffs, 1965, pp. 326-345.

[41]. Ahmed, M. J.; Afrin, A.; Akhtar, Y. Am. J. Anal. Chem. 2019, 10(11), 528-561.
https://doi.org/10.4236/ajac.2019.1011038

[42]. Zannat, T.; Ahmed, M. J. Eur. J. Chem. 2015, 6(2), 141-150.
https://doi.org/10.5155/eurjchem.6.2.141-150.1193

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University of Chittagong, Chittagong-4331, Bangladesh.
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