Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
A highly sensitive and selective spectrophotometric method for the determination of vanadium at nanotrace levels in some environmental, biological, soil, food, and pharmaceutical samples using salicylaldehyde-benzoylhydrazone
Shaifa Abrarin (1)
, Mohammed Jamaluddin Ahmed (2,*) (1) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
(2) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
(*) Corresponding Author
Received: 18 Aug 2020 | Revised: 14 Nov 2020 | Accepted: 22 Nov 2020 | Published: 31 Dec 2020 | Issue Date: December 2020
Abstract
A very simple, non-extractive and new spectrophotometric method for the swift determination of trace amount of vanadium using salicylaldehyde-benzoylhydrazone (Sal-BH) has been developed. Sal-BH undergoes a reaction in a slightly acidic solution (0.0016-0.0032 M H2S04) with vanadium to give a light greenish-yellow chelate, which has an absorption maximum at 392 nm. The reaction is instantaneous and absorbance remains stable for over 24 hrs. The average molar absorption co-efficient and Sandell’s sensitivity were found to be 2.5039×105 L/mol.cm and 1.0 ng/cm2 V, respectively. Beer’s law was obeyed for 0.001-30 mg/L of V, providing a detection limit of 0.1 µg/L of V and RSD 0-2 %. The stoichiometric composition of the chelate is 1:1 (V:Sal-BH). Interference study shows that a large excess of over 60 cations, anions, and some common complexing agents (such as chloride, azide, tartrate, EDTA and SCN‑, etc.) satisfy the tolerance limit. The developed method was successfully used in the determination of vanadium in several standard reference materials as well as in some environmental waters, biological fluids, soil, food and pharmaceutical samples and solutions containing both vanadium (IV) and vanadium (V). The results of the proposed method for assessing biological, food and vegetable samples were comparable with ICP-OES and AAS were found to be in excellent agreement. The method has high precision and accuracy (s = ±0.01 for 0.5 mg/L).
Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.11.4.385-395.2030
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 741 times |
PDF Article downloaded 360 times
Funding information
University of Chittagong, Chittagong-4331, Bangladesh.
Citations
[1]. Muhammad Jamaluddin Ahmed, Muhammad Jihan Uddin, Muhammad Emdadul Hoque
Development of a new highly sensitive and selective spectrophotometric method for the determination of selenium at nano-trace levels in various complex matrices using salicylaldehyde-orthoaminophenol
European Journal of Chemistry 12(4), 469, 2021
DOI: 10.5155/eurjchem.12.4.469-481.2137
[2]. Asha WADY, Mohammed KHALİD, Mohammed ALOTAİBİ, Yusuf AHMED
Synthesis, characterization, DFT calculations, and catalytic epoxidation of two oxovanadium(IV) Schiff base complexes
Journal of the Turkish Chemical Society Section A: Chemistry 9(1), 163, 2022
DOI: 10.18596/jotcsa.1008578
[3]. Muhammad Jamaluddin Ahmed, Tahmina Happy
Development of a new highly sensitive and selective spectrophotometric method for the determination of cobalt at nanotrace levels in various complex matrices using N,N’-bis(salicylidene)-ethylenediamine
European Journal of Chemistry 13(1), 20, 2022
DOI: 10.5155/eurjchem.13.1.20-32.2139
References
[1]. Baroch, E. F.; Updated by Staff., Vanadium and Vanadium Alloys. Kirk-Othmer Encyclopedia of Chemical Technology, 2013.
https://doi.org/10.1002/0471238961.22011401.a01.pub3
[2]. Crans, D. C.; Gottlieb, M. S.; Tawara, J.; Bunch, R. L.; Theisen, L. A. Anal. Biochem. 1990, 188(1), 53-64.
https://doi.org/10.1016/0003-2697(90)90527-G
[3]. Clayton, G. D.; Clayton, F. E. (Eds)., Patty's Industrial Hygiene and Toxicology, 3rd Edition, Vol. 2A, Wiley, New York, 1981, pp. 2013-2036.
[4]. Bratter, P.; Schramel, P., Trace Element Analytical Chemistry in Medicine and Biology, De Gruyter, Berlin, 1984, pp. 375-383.
[5]. Mracova, M.; Jirova, D.; Janci, H.; Lener, J. Sci. Total Environ. 1993, 16, 633-633.
[6]. Venugopal, B.; Luckey, T. D., Metal Toxicity in Mammals, Vol: 2, Plenum Press, New York, 1979, pp. 220-223.
[7]. Nordberg, G. F.; Fowler, B. A.; Nordberg, M.; Friberg, L. T. Handbook on the Toxicology of Metals, Academic Press, Amsterdam. 1986.
[8]. Key, M. M.; Henschel, A. F.; Butter, J.; Ligo, R. N.; Tabershad, I. R. Occupational Diseases-A Guide to Their Recognition, US Department of Health, Education and Welfare, US Government Printing, Washington, DC., June 1977.
[9]. Pyrzynska, K. Microchim. Acta 2005, 149(3-4), 159-164.
https://doi.org/10.1007/s00604-004-0304-5
[10]. Crumb, R. Vanadium and Its Role in Life Metal Ions in Biological Systems, Volume 31, Biochemical Education, 1995, 23(3), 180.
https://doi.org/10.1016/0307-4412(95)90238-4
[11]. Liao, Z. J. Pollution, hazard, migrate and transform of micro amounts heavy metal elements in environment, Science Press, Beijing, 1989, pp. 28-30.
[12]. Patel, B.; Henderson, G. E.; Haswell, S. J.; Grzeskowiak, R. Analyst 1990, 115(8), 1063-1066.
https://doi.org/10.1039/an9901501063
[13]. Lenntech B.V., Vanadium - V, Retrieved Oct 01, 2020, from https://www.lenntech.com/periodic/elements/v.htm
[14]. Ahmed, M. J.; Zannat, T. Pak. J. Anal. Environ. Chem. 2012, 13(1), 22-35.
[15]. Ahmed, M. J.; Afrin, A.; Uddin, M. O. Eur. J. Chem. 2020, 11(1), 37-49.
https://doi.org/10.5155/eurjchem.11.1.37-49.1923
[16]. Ahmed, M. J.; Banoo, S. Talanta 1999, 48(5), 1085-1094.
https://doi.org/10.1016/S0039-9140(98)00329-4
[17]. Zucchi, C.; Forneris, M.; Martinez, L.; Olsina, R.; Marchevsky, E. Fresen. J. Anal. Chem. 1998, 360(1), 128-130.
https://doi.org/10.1007/s002160050658
[18]. Narayana, S. L.; Reddy, K. J.; Narayana Reddy, S. A.; Sarala, Y.; Reddy, A. V. Environ. Monit. Assess. 2007, 144(1-3), 341-349.
https://doi.org/10.1007/s10661-007-9997-3
[19]. Verdizade, N. A.; Magerramov, A. M.; Kuliev, K. A. J. Anal. Chem. 2011, 66(12), 1159-1164.
https://doi.org/10.1134/S1061934811090188
[20]. Zalov A. Z.; Verdizade, N. A. Chem. J. 2015, 5(4), 54-62.
[21]. Narang, K. K.; Rao, T. R.; Shrestha, S.; Shrestha, S. Synt. React. Inorg. Metal-Org. Chem. 2000, 30(5), 931-954.
https://doi.org/10.1080/00945710009351810
[22]. Jeffery, G. H.; Bassett, J.; Mendham, J.; Denney, R. C. (Eds.). Vogel's Textbook of Quantitative Chemical Analysis, ELBS, 5th Edition, Bath Press Ltd., London, 1994.
[23]. Mukherji, A. K. Analytical Chemistry of Zirconium and Hafnium, 1st Edition, Pergamon Press, Oxford, 1970.
https://doi.org/10.1016/B978-0-08-006886-2.50006-0
[24]. Pal, B. K.; Chaudhury, B. Mikrochim. Acta 1985, 85(5-6), 437-446.
https://doi.org/10.1007/BF01201540
[25]. Busev, A. I.; Tiptsova, V. G.; Ivanov, V. M. Analytical Chemistry of Rare Elements, Mir Publishers, Moscow, 1981, pp. 385-392.
[26]. Al-Kharafi, F. M.; Badawy, W. A. Electrochim. Acta 1997, 42(4), 579-586.
https://doi.org/10.1016/S0013-4686(96)00202-2
[27]. Sandell's, E. B. Colorimetric Determination of Traces of Metals, 3rd Edition, Interscience, New York, 1965, pp. 269-275.
[28]. Ostampour, L.; Taher, M. Talanta 2008, 75(5), 1279-1283.
https://doi.org/10.1016/j.talanta.2008.01.045
[29]. Job, P. Ann. Chim. Paris, 1928, 9, 113-203.
https://doi.org/10.3406/bmsap.1928.9218
[30]. Yoe, J. H.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16(2), 111-115.
https://doi.org/10.1021/i560126a015
[31]. Gao, J.; Zhang, X.; Yang, W.; Kang, J. Anal. Chim. Acta 2002, 455(1), 159-165.
https://doi.org/10.1016/S0003-2670(01)01583-5
[32]. Mitra, S., Sample Preparation Techniques in Analytical Chemistry, John Wiley & Sons, Inc., 2003, pp. 125-140.
https://doi.org/10.1002/0471457817
[33]. Melwanki, M. B.; Seetharamappa, J.; Masti, S. P. Anal. Sci. 2001, 17(8), 979-982.
https://doi.org/10.2116/analsci.17.979
[34]. Greenberg, E. A.; Clesceri, S. L.; Eaton, D. A. (Eds.). Standard Methods for the Examination of Water and Wastewater, 18th edn, American Public Health Association, Washington D. C., 1992, 3-253-260.
[35]. Chambon, P.; Lound, U.; Ohanian, E. WHO Guidelines for Drinking Water Quality, Recommendations, WHO, Geneva, 2nd Edition, 1993.
[36]. Miura, J. Anal. Chem. 1990, 62(14), 1424-1428.
https://doi.org/10.1021/ac00213a015
[37]. Khayatian, G.; Hassanpoor, S.; Azar, A. R. J.; Mohebbi, S. J. Braz. Chem. Soc. 2013, 24(11), 1808-1812.
[38]. Stahr, H. M. Analytical Methods in Toxicology, 3rd Edition, John Wiley and Sons, New York, 1991, pp. 85-96.
[39]. Rondini, E. A.; Walters, D. M.; Bauer, A. K. Part. Fibre Toxicol. 2010, 7(1), 9, 1-13.
https://doi.org/10.1186/1743-8977-7-9
[40]. Jackson, M. L. Soil Chemical Analysis, Prentice Hall, Englewood Cliffs, 1965, pp. 326-345.
[41]. Ahmed, M. J.; Afrin, A.; Akhtar, Y. Am. J. Anal. Chem. 2019, 10(11), 528-561.
https://doi.org/10.4236/ajac.2019.1011038
[42]. Zannat, T.; Ahmed, M. J. Eur. J. Chem. 2015, 6(2), 141-150.
https://doi.org/10.5155/eurjchem.6.2.141-150.1193
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.11.4.385-395.2030
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2020, 11(4), 385-395 | doi: https://doi.org/10.5155/eurjchem.11.4.385-395.2030 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c) 2020 Authors
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.