European Journal of Chemistry 2020, 11(1), 37-49 | doi: https://doi.org/10.5155/eurjchem.11.1.37-49.1923 | Get rights and content

Issue cover




Crossmark

  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

A highly sensitive and rapid spectrophotometric method for the determination of molybdenum at nano-trace levels in some real, environmental, biological, food and soil samples using salicylaldehyde-benzoylhydrazone


Mohammed Jamaluddin Ahmed (1,*) orcid , Ayesha Afrin (2) orcid , Mohammad Ohi Uddin (3) orcid

(1) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
(2) Department of Applied Chemistry and Chemical Engineering, University of Chittagong, Chittagong-4331, Bangladesh
(3) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
(*) Corresponding Author

Received: 14 Sep 2019 | Revised: 21 Nov 2019 | Accepted: 02 Dec 2019 | Published: 31 Mar 2020 | Issue Date: March 2020

Abstract


A very simple, sensitive and highly selective non-extractive new spectrophotometric method has been developed for the determination of molybdenum at nano-trace levels using salicylaldehyde-benzoylhydrazone (Sal-BH). The method is based on the reaction of non-absorbent Sal-BH in a slightly acidic solution (0.0025-0.0075 M H2S04) with molybdenum (VI) to give a light yellowish chelate, which has an absorption maximum at 440 nm. The reaction is instantaneous and absorbance remains stable for over 24 h. The average molar absorption coefficient and Sandell’s sensitivity were found to be 4.32×105 L/mol.cm and 5 ng/cm2 of molybdenum, respectively. Linear calibration graphs were obtained for 0.01-60.00 mg/L of molybdenum having detection limit of 1 µg/L and RSD 0.0-2.0 %. The stoichiometric composition of the chelate is 1:1 (Mo:Sal-BH). A large excess of over 60 cations, anions and some common complexing agents (such as chloride, azide, tartrate, EDTA, SCN- etc.) do not interfere in the determination. The method was successfully used in the determination of molybdenum in several Certified Reference Materials (Alloys, steels, water, hair and bovine liver) as well as in some environmental waters (Potable and polluted), biological samples (Human blood, urine, nails, hair, food and vegetables), soil samples, and solutions containing both molybdenum(VI) and molybdenum(V) as well as complex synthetic mixtures. The results of the proposed method for assessing biological, food and vegetables samples were found to be in excellent agreement with those obtained by ICP-OES and AAS. The method has high precision and accuracy (s = ±0.01 for 0.5 mg/L).


Announcements


One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).

Editor-in-Chief
European Journal of Chemistry

Keywords


Molybdenum; Food samples; Biological samples; Environmental samples; Spectrophotometry; Salicylaldehyde-benzoylhydrazone

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.11.1.37-49.1923

Links for Article


| | | | | | |

| | | | | | |

| | | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 1929 times | icon graph PDF Article downloaded 416 times

Funding information


University of Chittagong, Chittagong-4331, Bangladesh.

Citations

/


[1]. Muhammad Jamaluddin Ahmed, Muhammad Jihan Uddin, Muhammad Emdadul Hoque
Development of a new highly sensitive and selective spectrophotometric method for the determination of selenium at nano-trace levels in various complex matrices using salicylaldehyde-orthoaminophenol
European Journal of Chemistry  12(4), 469, 2021
DOI: 10.5155/eurjchem.12.4.469-481.2137
/


[2]. Shaifa Abrarin, Mohammed Jamaluddin Ahmed
A highly sensitive and selective spectrophotometric method for the determination of vanadium at nanotrace levels in some environmental, biological, soil, food, and pharmaceutical samples using salicylaldehyde-benzoylhydrazone
European Journal of Chemistry  11(4), 385, 2020
DOI: 10.5155/eurjchem.11.4.385-395.2030
/


[3]. Mohammed Jamaluddin Ahmed, Faisal Hossain, Esham Mahmood
A Highly Selective and Simple Spectrophotometric Method for the Determination of Zinc at Nano-trace Levels in Some Environmental, Biological, Food, and Pharmaceutical Samples Using 2-hydroxynaphthaldehydebenzoylhydrazone
European Journal of Chemistry  11(2), 160, 2020
DOI: 10.5155/eurjchem.11.2.160-167.1987
/


References


[1]. Hurliy, L. S.; Bratter, P.; Schramel, P. Trace Element Analytical Chemistry in Medicine and Biology, 6th edition, John Wiley & Sons, 1994.

[2]. Langard, S.; Friberg, L.; Nordberg, G. F.; Vouk, V. B.; Norseth, T. Handbook on the Toxicology of Metals, Elsevier, Amsterdam, 1986, pp. 185-210.

[3]. Kabata-Pendias, A.; Pendias, H., Biochemistry of Trace Elements, Wydawnictwa Geologiczne, Warsaw, Poland, 1993.

[4]. Hay, R. W. Bioinorganic Chemistry, Ellis Horwood Ltd., Chichester, UK, 1990.

[5]. Dojlido, J. Chemistry of Water, Arkady, Warsaw, Poland, 1987.

[6]. Ahmed, M. J.; Tasnima, Z. Pak. J. Anal. Environ. Chem. 2012, 13(2), 22-35.

[7]. Ahmed, M. J.; Haque, E. M. Anal. Sci. 2002, 18(4), 433-439.
https://doi.org/10.2116/analsci.18.433

[8]. Ahmed, M. J.; Uddin, N. M.; Tasnima, Z.; Salma, S. Anal. Methods 2014, 6(7), 2282-2293.
https://doi.org/10.1039/C3AY42113A

[9]. Vogel, A. I. , Vogel's Quantitative Chemical Analysis, 5th Edition, Longman Group, ELBS, UK, 1989.

[10]. Kousaburo, O.; Makoto, I.; Kenji, N.; Katsumi, Y. Anal. Sci. 1986, 2, 339-350.

[11]. Tarek, M.; Zaki, M.; EI-Zawawy, F. M.; Abdel-Kader, A. K.; Abdalla, M. M. Anal. Sci. 1990, 6, 61-65.
https://doi.org/10.2116/analsci.6.61

[12]. Durust, Y.; Karakus, H.; Yavuz, M. Y.; Gepdiremen, A. A. Turk. J. Chem. 2014, 38, 739-755.
https://doi.org/10.3906/kim-1309-59

[13]. Pelit, L.; Suleyman, K.; Pelit, F.; Hayati, T.; Ertas, F. N. Anal. Methods 2013, 5, 5792-5798.
https://doi.org/10.1039/c3ay40772a

[14]. Rameshwar, D.; Kapoor, J. K.; Gambhir, S. J. Chem. Sci. 2013, 2013, 1-6.

[15]. Sailaja, S.; Reedy, M. R.; Raju, K. M.; Reddy, K. H. Indian J. Chem. A 1999, 38, 156-160.

[16]. Praveenkumar, A.; Reddy, V. K. J. Chilean Chem. Soc. 2007, 52, 1309-1313.
https://doi.org/10.4067/S0717-97072007000400009

[17]. Reddy, S. A.; Reddy, K. J.; Narayana, S. L.; Rao, Y. S.; Ramachandraiah, C.; Reddy, A. V. Food Anal. Methods 2009, 2, 141-148.
https://doi.org/10.1007/s12161-008-9050-3

[18]. Savariar, C. P.; Arunachalam, M. K.; HariharanT. R.Anal. Chim. Acta 1974, 69(2), 305-311.
https://doi.org/10.1016/S0003-2670(01)80896-5

[19]. Pytlakowska, K.; Feist, B. J. Anal. Chem. 2013, 68, 39-44.
https://doi.org/10.1134/S1061934813010115

[20]. Srilalitha, V.; Raghavendra, G. P. A.; Kumar, K. R.; Seshagiri, V.; Ravindranath, L. K. Chem. Bull. 2010, 55(69), 32-60.

[21]. Dasarathgau, H.; Nawardhananad, N.; Rnando, A. J. Chem. 1987, 65, 1124-1132.

[22]. Tarek, M.; Zaki, M.; Abdel-Kader, A. K.; Abdalla, M. M. Talanta 1990, 37, 1091-1095.
https://doi.org/10.1016/0039-9140(90)80160-H

[23]. Martinez-Vidal, J. L.; Pino, J. L.; Dlaz, C.; Salinas, F. Analyst 1990, 115, 329-331.
https://doi.org/10.1039/an9901500329

[24]. Bermejo-Barrera, M. P.; Vazquez-Gonzalez, J. F.; Bermejo-Martinez, F. Analyst 1987, 112, 473-475.
https://doi.org/10.1039/an9871200473

[25]. Wakamatsu, Y. Inter. Nuclear Inform. Sys. 1977, 9(1), 470-478.

[26]. Fernandez, J. M. L.; Perez-Bendito, D.; Valcarcel, M. Analyst 1978,103, 1210-1214.
https://doi.org/10.1039/an9780301210

[27]. Zaijun, L.;Jiaomai, P.; Tang, J.; Zaijun, P. L.; Tang, J. J. Anal. Bioanal. Chem. 2002, 374, 1125-1131.
https://doi.org/10.1007/s00216-002-1574-6

[28]. Keshavan, B.; Nagaraja, P.; Keshavan, B.; Nagaraja, P. Microchim. Acta1 985, 86, 379-387.
https://doi.org/10.1007/BF01206908

[29]. Patel, K. S.; Mishra, R. K. Chemischer Informationsdienst 1983, 14, 24.
https://doi.org/10.1002/chin.198324359

[30]. Wakamatsu, Y. Inter. Nuclear Inform. Sys. 1980, 29(7), 472-476.
https://doi.org/10.2116/bunsekikagaku.29.7_472

[31]. Perez-Bendito, D.; Pino-Perez, F.; Perez-Bendito, D.; Pino-Perez, F. Mikrochim. Acta 1976, 65, 613-622.
https://doi.org/10.1007/BF01218237

[32]. Zhang, Z. H.; Lu, H.Y.; Yang, S. H.; Gao, J. W. J. Comb. Chem. 2010, 12(5), 643-646.
https://doi.org/10.1021/cc100047j

[33]. Abbasi, S. A. Separation Sci. 1976, 11(3), 293-300.
https://doi.org/10.1080/01496397608085321

[34]. Chandrakar, L.; Singh, R. Analyst 1987, 112, 1511-1513.
https://doi.org/10.1039/AN9871201511

[35]. Martinez-Vidal, J. L; Fernandez-Alba, A. R. Analyst 1990, 115, 329-331.
https://doi.org/10.1039/an9901500329

[36]. Rodriguez, M. T.Analyst 1982, 107, 41-46.
https://doi.org/10.1039/an9820700041

[37]. Zhang-Fa, H.; Xi-Man, L. Talanta 1988, 35(12), 1007-1009.
https://doi.org/10.1016/0039-9140(88)80238-8

[38]. Sacconi, L. J. Am. Chem. Soc. 1953, 75(21), 5434-5435.
https://doi.org/10.1021/ja01117a519

[39]. Salam, M. A.; Chowdhury, D. A.; Hossain, S. M. A. Bull. Pure Appl. Sci. 1995, 14, 129-135.

[40]. Mukherji, A. K., Analytical Chemistry of Zirconium and Hafnium, International Series of Monographs in Analytical Chemistry, 1stEdition, Pergamon Press, New York, 1970.
https://doi.org/10.1016/B978-0-08-006886-2.50006-0

[41]. Pal, B. K.; Chowdhury, B. Mikrochim. Acta 1984, 83, 121-131.
https://doi.org/10.1007/BF01237266

[42]. Sandell's, E. B., Colorimetric Determination of Traces of Metals, 3rd Edition, Interscience, New York, 1965.

[43]. Ojeda, C. B.; Torres, A. G.; Rojas, F. S.; Pavon, J. M. C. Analyst 1987, 112, 1499-1501.
https://doi.org/10.1039/AN9871201499

[44]. Job, P. Ann. Chim. Paris 1928, 9, 113-203.
https://doi.org/10.3406/bmsap.1928.9218

[45]. Yoe, J. N.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16(2), 111-115.
https://doi.org/10.1021/i560126a015

[46]. Parker, G. A.; Analytical Chemistry of Molybdenum, Springer-Verlag, 1983.
https://doi.org/10.1007/978-3-642-68992-5

[47]. Sun, Y. C.; Yang, J. Y.; Tzeng, S. R. Analyst 1999, 124, 421-424.
https://doi.org/10.1039/a809596e

[48]. Greenberg, E. A.; Clesceri, S. L.; Eaton, D. A., American Public Health Association, 18th Edition, Washington D. C., 1992, pp. 253-268

[49]. Khayatian, G.; Hassanpoor, S.; Azar, A. R. J.; Mohebbi, S. J. Braz. Chem. Soc. 2013, 24(11), 1808-1817.

[50]. Stahr, H. M. Analytical Methods in Toxicology. 3rd Edition, John Wiley & Sons, 1991.

[51]. Hesse, P. R. A Text Book of Soil Chemical Analysis, Chemical Publishing Co. Inc., New York, 1972.

[52]. Radja, N.; Charles-Holmes, R. Clin. Exp. Dermatol. 2002, 27(1), 62-63.
https://doi.org/10.1046/j.0307-6938.2001.00940.x

[53]. Sebenik, R. F. Molybdenum and Molybdenum Compounds, Ullman's Encyclopedia of Chemical Technology. Wiley-VCH, Wenham, 2005, 655.

[54]. Ahmed, M. J.; Islam, M. T.; Hossain, F. RSC Advances 2018, 8, 5509-5522.
https://doi.org/10.1039/C7RA12762F


How to cite


Ahmed, M.; Afrin, A.; Uddin, M. Eur. J. Chem. 2020, 11(1), 37-49. doi:10.5155/eurjchem.11.1.37-49.1923
Ahmed, M.; Afrin, A.; Uddin, M. A highly sensitive and rapid spectrophotometric method for the determination of molybdenum at nano-trace levels in some real, environmental, biological, food and soil samples using salicylaldehyde-benzoylhydrazone. Eur. J. Chem. 2020, 11(1), 37-49. doi:10.5155/eurjchem.11.1.37-49.1923
Ahmed, M., Afrin, A., & Uddin, M. (2020). A highly sensitive and rapid spectrophotometric method for the determination of molybdenum at nano-trace levels in some real, environmental, biological, food and soil samples using salicylaldehyde-benzoylhydrazone. European Journal of Chemistry, 11(1), 37-49. doi:10.5155/eurjchem.11.1.37-49.1923
Ahmed, Mohammed, Ayesha Afrin, & Mohammad Ohi Uddin. "A highly sensitive and rapid spectrophotometric method for the determination of molybdenum at nano-trace levels in some real, environmental, biological, food and soil samples using salicylaldehyde-benzoylhydrazone." European Journal of Chemistry [Online], 11.1 (2020): 37-49. Web. 3 Jun. 2023
Ahmed, Mohammed, Afrin, Ayesha, AND Uddin, Mohammad. "A highly sensitive and rapid spectrophotometric method for the determination of molybdenum at nano-trace levels in some real, environmental, biological, food and soil samples using salicylaldehyde-benzoylhydrazone" European Journal of Chemistry [Online], Volume 11 Number 1 (31 March 2020)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.11.1.37-49.1923


CrossRef | Scilit | GrowKudos | Researchgate | Publons | ScienceGate | Scite | Lens | OUCI

WorldCat Paperbuzz | LibKey Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2020, 11(1), 37-49 | doi: https://doi.org/10.5155/eurjchem.11.1.37-49.1923 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c) 2020 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).



© Copyright 2010 - 2023  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.