European Journal of Chemistry

Synthesis, characterization and thermal decomposition kinetics of poly(2-imidazolidinthione-formaldehyde)



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Naushad Ahmad
Rizwan Wahab
Suliman Yousef Al Oma

Abstract

A polymeric ligand, 2-imidazolidinthione-formaldehyde (poly-IF), bearing nitrogen and sulfur donor group was synthesized by the polycondensation of 2-imidazolidinthione and formaldehyde in alkaline medium. The synthetic ligand was characterized with micro-analytical and spectral studies. The thermal degradation is investigated by means of dynamic thermogravimetry (TG/DTG) in helium and air atmosphere at various heating rate. The non-isothermal degradation of poly-IF compound was occurred in an inert and air atmosphere. Degradation activation energies were calculated using model free multiple heating rate methods i.e. Flynn-Wall-Ozawa (FWO), Friedman and Kissinger. The compound poly-IF was also tested against strain (Escherichia coli) and it inhibits the proliferation of bacterial growth.


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Ahmad, N.; Wahab, R.; Al Oma, S. Y. Synthesis, Characterization and Thermal Decomposition Kinetics of poly(2-Imidazolidinthione-Formaldehyde). Eur. J. Chem. 2014, 5, 155-161.

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King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
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