Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Thermal decomposition kinetics of sodium carboxymethyl cellulose: Model-free methods
Naushad Ahmad (1)
, Rizwan Wahab (2,*) , Suliman Yusuf Al-Omar (3) (1) Department of Chemistry, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(2) Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(3) Department of Zoology, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia
(*) Corresponding Author
Received: 15 Nov 2013 | Revised: 27 Dec 2013 | Accepted: 27 Dec 2013 | Published: 30 Jun 2014 | Issue Date: June 2014
Abstract
Thermal analysis techniques such as thermogravimetric analysis (TGA) have been widely used because they provide rapid quantitative determination of various processes under isothermal or non-isothermal conditions. It allows the estimation of effective kinetic and thermodynamic parameters for various decomposition and thermal reactions. In this article, thermal degradation of sodium carboxymethyl cellulose (SMC) is investigated by means of dynamic thermogravimetric/derivative thermogravimetry (TG/DTG) in helium atmosphere with the flow rate 100 mL/min at the heating rate of 10-30 °C/min until the furnace wall temperature reached 700 °C. The non-isothermal degradation of SMC found to be taking place occurred major one step and minor two steps. Using a non-isothermal kinetic method based on a TGA data, kinetic parameters (Eand ln A) are calculated by Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO) and Friedman methods. The results of studied polymer demonstrated that E and ln A is varied with function of conversion (α), which is in good agreement with literature data.
Announcements
Our editors have decided to support scientists to publish their manuscripts in European Journal of Chemistry without any financial constraints.
1- The article processing fee will not be charged from the articles containing the single-crystal structure characterization or a DFT study between September 15, 2023 and October 31, 2023 (Voucher code: FALL2023).
2. A 50% discount will be applied to the article processing fee for submissions made between September 15, 2023 and October 31, 2023 by authors who have at least one publication in the European Journal of Chemistry (Voucher code: AUTHOR-3-2023).
3. Young writers will not be charged for the article processing fee between September 15, 2023 and October 31, 2023 (Voucher code: YOUNG2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.5.2.247-251.971
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 4001 times |
PDF Article downloaded 1105 times
Funding information
Deanship of Scientific Research, College of Science Research Center, King Saud University, Riyadh, Kingdom of Saudi Arabia
Citations
[1]. Ravi S. Baghel, C.R.K. Reddy, Ravindra Pal Singh
Seaweed-based cellulose: Applications, and future perspectives
Carbohydrate Polymers 267, 118241, 2021
DOI: 10.1016/j.carbpol.2021.118241
[2]. Candida Nissola, Marcelo Luis Kuhn Marchioro, Eneri Vieira de Souza Leite Mello, Ana Carolina Guidi, Daniela Cristina de Medeiros, Camila Girotto da Silva, João Carlos Palazzo de Mello, Edimir Andrade Pereira, Aneli M. Barbosa-Dekker, Robert F.H. Dekker, Mário A.A. Cunha
Hydrogel containing (1 → 6)-β-D-glucan (lasiodiplodan) effectively promotes dermal wound healing
International Journal of Biological Macromolecules 183, 316, 2021
DOI: 10.1016/j.ijbiomac.2021.04.169
[3]. G. Priya, U. Narendrakumar, I. Manjubala
Thermal behavior of carboxymethyl cellulose in the presence of polycarboxylic acid crosslinkers
Journal of Thermal Analysis and Calorimetry 138(1), 89, 2019
DOI: 10.1007/s10973-019-08171-2
[4]. Faouzia Khili, Amel Dakhlaoui Omrani
Synthesis of nanocellulose/cobalt oxide composite for efficient degradation of Rhodamine B by activation of peroxymonosulfate
European Journal of Chemistry 10(1), 19, 2019
DOI: 10.5155/eurjchem.10.1.19-25.1789
[5]. Kaman Singh, Ashok Kumar
Physiochemical aspects for the adsorption behavior of sodium carboxymethyl cellulose onto mesoporous granular fine quartz surface from its aqueous solutions
Separation Science and Technology 56(18), 3033, 2021
DOI: 10.1080/01496395.2021.1878373
[6]. Matthew R. Burton, Shahin Mehraban, James McGettrick, Trystan Watson, Nicholas P. Lavery, Matthew J. Carnie
Earth abundant, non-toxic, 3D printed Cu2−xS with high thermoelectric figure of merit
Journal of Materials Chemistry A 7(44), 25586, 2019
DOI: 10.1039/C9TA10064D
[7]. Patricio J. Robles Barros, Diego Palmiro Ramirez Ascheri, Mikaele Lorrany Siqueira Santos, Cleiber Cintra Morais, José L. Ramirez Ascheri, Roberta Signini, Danilo Martins dos Santos, André José de Campos, Ivano Alessandro Devilla
Soybean hulls: Optimization of the pulping and bleaching processes and carboxymethyl cellulose synthesis
International Journal of Biological Macromolecules 144, 208, 2020
DOI: 10.1016/j.ijbiomac.2019.12.074
[8]. Sara Kaabi Falahieh Asl, Sandor Nemeth, Ming Jen Tan
Novel biodegradable calcium phosphate/polymer composite coating with adjustable mechanical properties formed by hydrothermal process for corrosion protection of magnesium substrate
Journal of Biomedical Materials Research Part B: Applied Biomaterials 104(8), 1643, 2016
DOI: 10.1002/jbm.b.33505
[9]. Duraikkannu Shanthana Lakshmi, Nitin Trivedi, C.R.K. Reddy
Synthesis and characterization of seaweed cellulose derived carboxymethyl cellulose
Carbohydrate Polymers 157, 1604, 2017
DOI: 10.1016/j.carbpol.2016.11.042
[10]. Juliana Paes Leme de Mello Sousa, Renata Nunes Oliveira, Antonia Monica Neres Santos, Ormindo Domingues Gamallo, Leonardo Sales Araújo, Antonieta Middea, Yara Peluso Cid, Rosane Nora Castro
Superabsorbent biodegradable CMC membranes loaded with propolis: Peppas-Sahlin kinetics release
Polímeros 33(2), , 2023
DOI: 10.1590/0104-1428.20230010
[11]. Ł. Szymański, E. Olejnik, T. Tokarski, P. Kurtyka, D. Drożyński, S. Żymankowska-Kumon
Reactive casting coatings for obtaining in situ composite layers based on Fe alloys
Surface and Coatings Technology 350, 346, 2018
DOI: 10.1016/j.surfcoat.2018.06.085
References
[1]. Saddawi, A.; Jones, J. M.; Williams, A.; Wojtowicz, M. A. Energ. Fuel. 2010, 24, 1274-1282.
http://dx.doi.org/10.1021/ef900933k
[2]. Souza, D.; Castillo, T. E.; Rodriguez, R. J. S. J. Therm. Anal. Calorim. 2012, 109(3), 1353-1364.
http://dx.doi.org/10.1007/s10973-011-2152-y
[3]. Mohan, D.; Pittman, C. U.; Steele, P. H. Energ. Fuel. 2006, 20, 848-889.
http://dx.doi.org/10.1021/ef0502397
[4]. Antal, M. J. J.; Varhegyi, G. Ind. Eng. Chem. Res. 1995, 34, 703-717.
http://dx.doi.org/10.1021/ie00042a001
[5]. Abidi, N.; Hequet, E.; Cabrales, L.; Gannaway, J.; Wilkins, T.; Wells, L. W. J. App. Polym. Sci. 2008, 107, 476-486.
http://dx.doi.org/10.1002/app.27100
[6]. Abidi, N.; Hequet, E.; Ethridge, D. J. App. Polym. Sci. 2007, 103, 3476-3482.
http://dx.doi.org/10.1002/app.24465
[7]. Stamm, A. J. Ind. Eng. Chem. 1956, 48, 413-417.
http://dx.doi.org/10.1021/ie51398a022
[8]. Dahiya, J. B.; Kumar, K.; Hagedorn, M. M.; Bockhorn, H. Polym. Int. 2008, 57, 722-729.
http://dx.doi.org/10.1002/pi.2398
[9]. Majewicz, T. G.; Podlas, T. J. Cellulose ether. In Encyclopedia of chemicaltechnology, 4th Ed., New York: Wiley, 1966, Vol. 5, pp. 545-547.
[10]. Majewicz, T. G.; Podlas, T. J.; Kroschwitz, J. I. Kirk-Othmer. Cellulose Ethers, Kroschwitz, J. I. (Editor), Kirk-Othmer Concise Encyclopedia of Chemical Technology, Wiley-Interscience, 2005.
[11]. Hui, L. O.; Kumar, R. N.; Rozman, H. D.; Noor, M.; Azemi, M. Polymers 2005, 59, 57-69.
[12]. Muzzarelli, R. A. A. Carbohydr. Polym. 1966, 29, 309-316.
http://dx.doi.org/10.1016/S0144-8617(96)00033-1
[13]. Vander, P.; Varum, K. M.; Domard, A.; El-Geddari, N. E.; Moerschbacher, B. Plant Physiol. 1998, 118, 1353-1359.
http://dx.doi.org/10.1104/pp.118.4.1353
[14]. Peluso, G.; Petillo, O.; Ranieri, M.; Santin, M.; Ambrosio, L.; Calabro, D.; Avallone, B.; Balsamo, G. Biomaterials 1994, 15, 1215-1220.
http://dx.doi.org/10.1016/0142-9612(94)90272-0
[15]. Gerentes, P.; Vachoud, L.; Doury, J.; Domard, A. Biomaterials 2002, 23, 1295-1302.
http://dx.doi.org/10.1016/S0142-9612(01)00247-2
[16]. Despond, S.; Espuche, E.; Domard, A. J. Polym. Sci. Part B 2001, 39, 3114-3127.
http://dx.doi.org/10.1002/polb.10064
[17]. Kumar, G.; Bristow, J. F.; Smith, P. J.; Payne, G. F. Polymer. 2000, 41, 2157-2168.
http://dx.doi.org/10.1016/S0032-3861(99)00360-2
[18]. Holme, H. K.; Foros, H.; Pettersen, H.; Dornish, M.; Smidsrod, O. Carbohydr. Polym. 2001, 46, 287-294.
http://dx.doi.org/10.1016/S0144-8617(00)00332-5
[19]. Piotr, U.; Von Clemens, S. J. Chem. Soc. Perkin Trans. 2000, 2, 2022-2028.
[20]. Shao, J.; Yang, Y.; Zhong, Q. Polym. Degrad. Stab. 2003, 82, 395-398.
http://dx.doi.org/10.1016/S0141-3910(03)00177-0
[21]. Kissinger, H. E. Anal. Chem. 1957, 29, 1702-1706.
http://dx.doi.org/10.1021/ac60131a045
[22]. Akahira, T.; Sunose, T. Chiba Inst. Technol. 1971, 16, 22-31.
[23]. Flynn, J. H.; Wall, L. A. J. Polym. Sci. Part C-Polym. Lett. 1966, 4, 323-328.
[24]. Ozawa, T. Bull. Chem. Soc. Japan 1965, 38, 1881-1882.
http://dx.doi.org/10.1246/bcsj.38.1881
[25]. Doyle, C. D. Nature 1965, 207, 290-291.
http://dx.doi.org/10.1038/207290a0
[26]. Friedman, H. L. J. Polym. Sci. C 1964, 6, 183-195.
[27]. Volker, S.; Rieckmann, Th. J. Anal. Appl. Pyrol. 2002, 62, 165-177.
http://dx.doi.org/10.1016/S0165-2370(01)00113-9
[28]. Lede, J. Ind. Eng. Chem. Res. 2002, 39, 893-898.
[29]. Gallagher, P. K. Thermogravimetry and Thermomagnetometry, in Handbook of Thermal Analysis and Calorimetry, Ed. Brown, M. E. Elsevier Science B. V., Amsterdam, 1998, 1, pp. 225-278.
[30]. Gongwer, P. E.; Arisawa, H.; Brill, T. B. Combust Flame. 1997, 109, 370-381.
http://dx.doi.org/10.1016/S0010-2180(96)00188-5
[31]. Brown, M. E.; Maciejewski, M.; Vyazovkin, S.; Nomen, R.; Sempere, J.; Burnham, A.; Opfermann, J.; Strey, R.; Anderson, H. L.; Kemmler, A. R.; Keuleers, J.; Desseyn, H. O.; Chao-Rui, L.; Tang, T. B.; Roduit, B.; Malek, J.; Mitsuhashi, T. Thermochim. Acta 2000, 355(1-2), 125-143.
http://dx.doi.org/10.1016/S0040-6031(00)00443-3
[32]. Maciejewski, M. Thermochim. Acta 2000, 355, 145-154.
http://dx.doi.org/10.1016/S0040-6031(00)00444-5
[33]. Vyazovkin, S.; Wight, A. C. Annu. Rev. Phys. Chem. 1997, 48, 125-149.
http://dx.doi.org/10.1146/annurev.physchem.48.1.125
[34]. Lomakin, S. M.; Rogovina, S. Z.; Grachev, A. V.; Prut, E. V.; Alexanyan, Ch. V. Thermochim. Acta 2011, 521, 66-73.
http://dx.doi.org/10.1016/j.tca.2011.04.005
[35]. Chrissafis, K.; Paraskevopoulos, K. M.; Bikiaris, D. N. Polym. Degrad. Stab. 2006, 91, 60-68.
http://dx.doi.org/10.1016/j.polymdegradstab.2005.04.028
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.5.2.247-251.971
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2014, 5(2), 247-251 | doi: https://doi.org/10.5155/eurjchem.5.2.247-251.971 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.