European Journal of Chemistry 2014, 5(3), 402-409. doi:10.5155/eurjchem.5.3.402-409.977

Synthesis, spectroscopic and thermal characterization of Fe(III)-mixed ligand complexes and spectrophotometric determination of Fe(III) in various samples


Gehad Genidy Mohamed (1,*) , Ahmed Mahmoud Mohamed Hindy (2) , Mahmoud Sabry Rizk (3) , Mai El-Sayed Sadek (4)

(1) Chemistry Department, Faculty of Science, Cairo University, 12613, Giza, Egypt
(2) Department of Requirements of Labs, El-Fostat Plant, Cairo Water Company, 11511, Cairo, Egypt
(3) Chemistry Department, Faculty of Science, Cairo University, 12613, Giza, Egypt
(4) Department of Requirements of Labs, El-Fostat Plant, Cairo Water Company, 11511, Cairo, Egypt
(*) Corresponding Author

Received: 18 Nov 2013, Accepted: 12 Jan 2014, Published: 30 Sep 2014

Abstract


The aim of the present study is to find a non time consuming, economical and reliable spectrophotometric procedures using commercially available spectrophotometric reagents for the determination of Fe(III) ions. The methods are based on the formation of colored ternary complexes using, 1,10-phenanthroline and eriochrome black T or tartrazine mixed reagents and improved using a cationic surfactant, cetyltrimethyl ammonium bromide. This surfactant interacts with the complex to build up true ternary complex. The most suitable conditions for determination of Fe(III) ions and the parameters affecting the reactions including pH, time, temperature, stoichiometric ratios and reagents concentrations are optimized. The effect of different interfering ions is studied together with the suitable masking agents. The developed methods are used for the determination of Fe(III) ions in the presence of cetyltrimethyl ammonium bromide in different types of water (polluted industrial waste, ground, river Nile and drinking water). The synthesis and spectroscopy studies of two Fe complexes were reported. Thermal analysis was carried out in order to give an idea about the thermal stability of the complexes.


Keywords


Tartrazine; Fe(III) complexes; Eriochrome black T; 1,10-Phenanthroline; Polluted waste water; Cetyltrimethyl ammonium bromide

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DOI: 10.5155/eurjchem.5.3.402-409.977

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References

[1]. Davydova, S. L. Crit. Rev. Anal. Chem. 1999, 28, 377-381.
http://dx.doi.org/10.1080/10408349891199239

[2]. Burns, D. T.; Dangolle, C. D. F. Anal. Chim. Acta 1997, 356, 145-148.
http://dx.doi.org/10.1016/S0003-2670(97)00456-X

[3]. Frenzel, W. Fresenius J. Anal. Chem. 1998, 361, 936-940.
http://dx.doi.org/10.1007/s002160051014

[4]. Nielsen, S.; Hansen, E. H. Anal. Chim. Acta 1998, 366, 163-176.
http://dx.doi.org/10.1016/S0003-2670(98)00101-9

[5]. Byrdy, F. A.; Olson, L. K.; Vela, N. P.; Caruso, J. A. J. Chromatogr. A 1995, 712, 311-320.
http://dx.doi.org/10.1016/0021-9673(95)00528-U

[6]. Korolczuk, M. Anal. Chim. Acta 2000, 414, 165-171.
http://dx.doi.org/10.1016/S0003-2670(00)00793-5

[7]. Pehkunen, S. Analyst 1995, 120, 2655-2663.
http://dx.doi.org/10.1039/an9952002655

[8]. Teshima, N.; Ayukawa, K.; Kawashima, T. Talanta 1996, 43, 1755-1760.
http://dx.doi.org/10.1016/0039-9140(96)01966-2

[9]. Kutsumata, H.; Teshima, N.; Kawashima, T. Bull. Chem. Soc. (Jpn.) 1997, 70, 2151-2154.
http://dx.doi.org/10.1246/bcsj.70.2151

[10]. Safavi, A.; Abdollahi, H. Microchem. J. 1999, 632, 211-217.
http://dx.doi.org/10.1006/mchj.1999.1796

[11]. Safavi, A.; Abdollahi, H. Talanta 2001, 54, 727-734.
http://dx.doi.org/10.1016/S0039-9140(01)00321-6

[12]. Abdollahi, H. Anal. Chim. Acta 2001, 442, 327-336.
http://dx.doi.org/10.1016/S0003-2670(01)01174-6

[13]. Pranab, K.; Thakur, R. Microchem. J. 2005, 80, 39-43.
http://dx.doi.org/10.1016/j.microc.2004.09.004

[14]. Yamini, Y.; Leyla; Mohammadi, D. E. Microchim. Acta 2003, 142, 21-25.
http://dx.doi.org/10.1007/s00604-002-0957-x

[15]. Zang, Z. X.; Xie, Y. Y.; Shi, Y.; Guangpuxue, Y. Fenxi Huaxue 1999, 19, 241-243.

[16]. Aki, M. A. Microchem. J. 2003, 75, 199-209.
http://dx.doi.org/10.1016/S0026-265X(03)00097-3

[17]. Ma, H. M.; Huang, Y. X.; Liang, S. C. Microchim. Acta 1998, 128, 181-185.
http://dx.doi.org/10.1007/BF01243047

[18]. Asgedom; Chandravanshi, G. Annali. Di Chimica (Rome) 1996, 86, 485-494.

[19]. Khuhawar, M. Y.; Lanjwani, S. N. Chem. Soc. (Pakistan) 2001, 23, 157-162.

[20]. King, D. W.; Line, J.; Kester, D. R. Anal. Chim. Acta 1991, 247, 125-132.
http://dx.doi.org/10.1016/S0003-2670(00)83061-5

[21]. Singh, H. B.; Agnihotri, N. K.; Singh, V. K. Talanta 1999, 48, 623-631.
http://dx.doi.org/10.1016/S0039-9140(98)00286-0

[22]. Hernandez, H. F.; Escriche, J. M.; Saez, R. M.; Barreda, M. C. R. Analyst 1986, 111, 1045-1049.
http://dx.doi.org/10.1039/an9861101045

[23]. Feng, J. L. Y.; Xuebao, H. Anal. Chem. 1988, 9, 407-413.

[24]. Qiu, C.; Zhu, Y. Anal. Chem. 1986, 26, 19-22.

[25]. Maireang, V.; Chotikkai, J.; Duangduan, P. Annual Book of ASTM Standards. American Society Resting and Materials. Philadelphia, 1982, 31, 438: 448.

[26]. Likussar, W.; Wawchinek, O.; Beyer, W. Anal. Chim. Acta. 1968, 40, 538-539.
http://dx.doi.org/10.1016/S0003-2670(00)86775-6

[27]. Nagahiro, T.; Uesugi, K.; Satake, M. Analyst 1986, 111, 1389-1391.
http://dx.doi.org/10.1039/an9861101389

[28]. Eaton, A. D.; Rice, E. W.; Baird, R. B. Standard Methods for the determination of Water and Wastewater". 19th Ed., APHA, AWWA, WEF, 1995.

[29]. Odashima, T.; Ishii, H. Anal. Chim. Acta. 1975, 74, 61-65.
http://dx.doi.org/10.1016/S0003-2670(01)82779-3

[30]. Yoe, J. H.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16, 111-115.
http://dx.doi.org/10.1021/i560126a015

[31]. Job, P. Ann. Chim. 1928, 9, 113-203.

[32]. Sandell, E. B. Colorimetric determination of traces of Metals. 3rd Ed., InterScience, New York, 1959.

[33]. Mohamed, G. G.; El-Gamel, N. E. A.; Teixidor, F. Polyhedron 2001, 20, 2689-2696.
http://dx.doi.org/10.1016/S0277-5387(01)00867-1

[34]. Jarvis, A. J. J. Acta Crystallogr. 1961, 14, 14-20.
http://dx.doi.org/10.1107/S0365110X61002795

[35]. Alcock, N. W.; Spencer, R. C.; Prince, R. H.; Kennard, O. J. Chem. Soc. A 1968, 2383-2388.
http://dx.doi.org/10.1039/j19680002383

[36]. Mohamed, G. G.; El-Gamel, N. E. A.; El-Dien, N. F. A. Synth. React. Inorg. Met. Org. Chem. 2001, 31, 347-358.
http://dx.doi.org/10.1081/SIM-100002053

[37]. El-Sonbati, A. Z.; Diab, M. A.; El-Bindary, A. A.; Nozha, S. G. Spectrochim. Acta A 2011, 83, 490-498.
http://dx.doi.org/10.1016/j.saa.2011.08.070

[38]. Abdallah, S. M.; Mohamed, G. G.; Zayed, M. A.; Abu-Elela, M. Spectrochim. Acta A 2009, 73, 833-840.
http://dx.doi.org/10.1016/j.saa.2009.04.005

[39]. Aljahdali, M. S.; El-Sherif, A. A.; Hilal, R. H.; Abdel-Karim, A. T. Eur. J. Chem. 2013, 4, 370-378.
http://dx.doi.org/10.5155/eurjchem.4.4.370-378.803

[40]. Abd El-Halim, H. F.; Omar, M. M.; Mohamed, G. G.; Sayed, M. A. Eur. J. Chem. 2011, 2, 178-188.
http://dx.doi.org/10.5155/eurjchem.2.2.178-188.240

[41]. Hassan, Walid M. I., Zayed, E. M.; Elkholy, A. K.; Moustafa, H.; Mohamed, G. G. Spectrochim. Acta A 2013, 103, 378-387.
http://dx.doi.org/10.1016/j.saa.2012.10.058

[42]. Emara, A. A. A.; Abu-Hussein, A. A. A.; Taha, A. A.; Mahmoud, N. H. Spectrochim. Acta A 2010, 77, 594-604.
http://dx.doi.org/10.1016/j.saa.2010.06.012

[43]. Mohamed, G. G.; Zayed, M. A.; Abdallah, S. M. J. Mol. Struct. 2010, 979, 62-71.
http://dx.doi.org/10.1016/j.molstruc.2010.06.002

[44]. Mohamed, G. G.; Badawy, M. A.; Omar, M. M.; Nassar, M. M.; Kamel, A. B. Eur. J. Chem. 2010, 1, 282-288.
http://dx.doi.org/10.5155/eurjchem.1.4.282-288.113

[45]. Abd El-Halim, H. F.; Mohamed, G. G.; El-Dessouky, M. M. I.; Mahmoud, W. A. Spectrochim. Acta A 2011, 82, 8-19.
http://dx.doi.org/10.1016/j.saa.2011.05.089

[46]. Soliman, M. H.; Mohamed, G. G. Spectrochim. Acta A 2012, 91, 11-17.
http://dx.doi.org/10.1016/j.saa.2012.01.021

[47]. Mahmoud, W. H.; Mohamed, G. G.; El-Dessouky, M. M. I. Spectrochim. Acta A 2014, 122, 598-608.
http://dx.doi.org/10.1016/j.saa.2013.11.069

[48]. Abd El-Halim, H. F.; Nour El-Dien, F. A.; Mohamed, G. G; Mohamed, N. A. J. Therm. Anal. Calorim. 2013, 111, 173-181.
http://dx.doi.org/10.1007/s10973-012-2333-3


How to cite


Mohamed, G.; Hindy, A.; Rizk, M.; Sadek, M. Eur. J. Chem. 2014, 5(3), 402-409. doi:10.5155/eurjchem.5.3.402-409.977
Mohamed, G.; Hindy, A.; Rizk, M.; Sadek, M. Synthesis, spectroscopic and thermal characterization of Fe(III)-mixed ligand complexes and spectrophotometric determination of Fe(III) in various samples. Eur. J. Chem. 2014, 5(3), 402-409. doi:10.5155/eurjchem.5.3.402-409.977
Mohamed, G., Hindy, A., Rizk, M., & Sadek, M. (2014). Synthesis, spectroscopic and thermal characterization of Fe(III)-mixed ligand complexes and spectrophotometric determination of Fe(III) in various samples. European Journal of Chemistry, 5(3), 402-409. doi:10.5155/eurjchem.5.3.402-409.977
Mohamed, Gehad, Ahmed Mahmoud Mohamed Hindy, Mahmoud Sabry Rizk, & Mai El-Sayed Sadek. "Synthesis, spectroscopic and thermal characterization of Fe(III)-mixed ligand complexes and spectrophotometric determination of Fe(III) in various samples." European Journal of Chemistry [Online], 5.3 (2014): 402-409. Web. 20 Jan. 2019
Mohamed, Gehad, Hindy, Ahmed, Rizk, Mahmoud, AND Sadek, Mai. "Synthesis, spectroscopic and thermal characterization of Fe(III)-mixed ligand complexes and spectrophotometric determination of Fe(III) in various samples" European Journal of Chemistry [Online], Volume 5 Number 3 (30 September 2014)

DOI Link: https://doi.org/10.5155/eurjchem.5.3.402-409.977

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