European Journal of Chemistry

Cation binding by some pyranopyridothiazole derivatives

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Published: Jun 30, 2014
DOI: https://doi.org/10.5155/eurjchem.5.2.339-342.1003
Keywords:
Thiazole, Extraction, Stoichiometry, Complexation, Stability constants, Inclusion properties
Section
Research Article
Issue
Vol. 5 No. 2 (2014): June 2014
Dates
Received 2013-12-15
Accepted 2014-02-24
Published 2014-06-30


Main Article Content

Olfa Naouali
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences at Bizerte, Carthage University, Zarzouna-Bizerta, 7021, Tunisia
Hussain Soleiman
Chemistry Department, Sciences and Arts College, Al-Qassim University, Al-Rass, 53200, Kingdom Saudi Arabia
Lassaad Baklouti
Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences at Bizerte, Carthage University, Zarzouna-Bizerta, 7021, Tunisia

Abstract

The binding properties of a cyanopyranopyridothiazole (L1), aminothiazole (L2), iminothiazole (L3) and phenyliminothiazole (L4) derivatives toward some transition metal and heavy metal cations, have been investigated in methanol, followed by UV spectrophotometry absorption and conductivity determination. The stoichiometries of the formed complexes and their stability constants were determined by a digital data processing. The study of extraction properties from water into dichloromethane shows a lower extraction affinity for the metal picrates with L1, unlike L2-L4 which are better extracted and specially Fe(III) with L4.


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Naouali, O.; Soleiman, H.; Baklouti, L. Cation Binding by Some Pyranopyridothiazole Derivatives. Eur. J. Chem. 2014, 5, 339-342.

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Carthage University, Zarzouna-Bizerta, 7021, Tunisia
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