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Cation binding by some pyranopyridothiazole derivatives
Olfa Naouali (1)
, Hussain Soleiman (2) , Lassaad Baklouti (3,*) (1) Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences at Bizerte, Carthage University, Zarzouna-Bizerta, 7021, Tunisia
(2) Chemistry Department, Sciences and Arts College, Al-Qassim University, Al-Rass, 53200, Kingdom Saudi Arabia
(3) Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences at Bizerte, Carthage University, Zarzouna-Bizerta, 7021, Tunisia
(*) Corresponding Author
Received: 15 Dec 2013 | Revised: 23 Feb 2014 | Accepted: 24 Feb 2014 | Published: 30 Jun 2014 | Issue Date: June 2014
Abstract
The binding properties of a cyanopyranopyridothiazole (L1), aminothiazole (L2), iminothiazole (L3) and phenyliminothiazole (L4) derivatives toward some transition metal and heavy metal cations, have been investigated in methanol, followed by UV spectrophotometry absorption and conductivity determination. The stoichiometries of the formed complexes and their stability constants were determined by a digital data processing. The study of extraction properties from water into dichloromethane shows a lower extraction affinity for the metal picrates with L1, unlike L2-L4 which are better extracted and specially Fe(III) with L4.
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European Journal of Chemistry
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DOI: 10.5155/eurjchem.5.2.339-342.1003
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Carthage University, Zarzouna-Bizerta, 7021, Tunisia
Citations
[1]. Olfa Naouali, Besma Mellah, Rawdha Medyouni, Naceur Hamdi, Lassaad Baklouti
Binding properties of coumarin phthalonitrile derivatives in methanol
European Journal of Chemistry 6(3), 337, 2015
DOI: 10.5155/eurjchem.6.3.337-341.1271
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DOI Link: https://doi.org/10.5155/eurjchem.5.2.339-342.1003
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European Journal of Chemistry 2014, 5(2), 339-342 | doi: https://doi.org/10.5155/eurjchem.5.2.339-342.1003 | Get rights and content
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