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Binding properties of coumarin phthalonitrile derivatives in methanol
Olfa Naouali (1)
, Besma Mellah (2) , Rawdha Medyouni (3) , Naceur Hamdi (4) , Lassaad Baklouti (5,*) (1) Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna-Bizerta, 7021, Tunisia
(2) Centre National de Recherches en Sciences des Matériaux Technopôle Borj-Cédria, Soliman, BP73 8020, Tunisie
(3) Heterocyclic and Organometallic Chemistry Laboratory, Higher Institute of Environmental Sciences and Technology, University of Carthage, Hammam-Lif, 2050, Tunisia
(4) Chemistry Department, College of Science and Arts, Qassim University, Al-Rass, 58883, Kingdom of Saudi Arabia
(5) Laboratory of Applied Chemistry and Natural Substances Resources and Environment, Faculty of Sciences, University of Carthage, Zarzouna-Bizerta, 7021, Tunisia
(*) Corresponding Author
Received: 13 May 2015 | Revised: 17 Jun 2015 | Accepted: 20 Jun 2015 | Published: 30 Sep 2015 | Issue Date: September 2015
Abstract
The complexation properties of coumarin phthalonitrile derivatives 1-3, towards some transition, heavy and lanthanide metal cations have been investigated in methanol by means of UV spectrophotometry and conductivity experiments. The stoichiometries of the complexes formed and their stability constants were resolved by digital processing of data. A binuclear M2L (M = Metal, L = Ligand) species were formed and the profiles of affinity of ligands 1-3 towards transition metal cations illustrate their selectivity towards Cu2+.
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DOI: 10.5155/eurjchem.6.3.337-341.1271
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DOI Link: https://doi.org/10.5155/eurjchem.6.3.337-341.1271
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European Journal of Chemistry 2015, 6(3), 337-341 | doi: https://doi.org/10.5155/eurjchem.6.3.337-341.1271 | Get rights and content
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